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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one 1613669-09-2 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613668-93-1 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-33-2 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one 1613669-12-7 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one 1613668-97-5 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-06-9 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-butylthiopyrimidin-4(3H)-one 1613668-94-2 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-butylthiopyrimidin-4(3H)-one
    —— 6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-38-7 C17H20ClFN2OS
    6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-11-6 C17H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613668-96-4 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— (S,S)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-39-8 C17H20ClFN2OS
    (S,S)-6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one 1613669-07-0 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-propylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-32-1 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one 1613669-34-3 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one 1613669-40-1 C17H20ClFN2OS
    6-[1-(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-sec-butylthio-pyrimidin-4(3H)-one
    —— (R)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one 1613669-35-4 C16H18ClFN2OS
    (R)-6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one 1613668-99-7 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-15-0 C19H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-isopropylthiopyrimidin-4(3H)-one 1613669-01-4 C15H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-isopropylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-cyclopentylthiopyrimidin-4(3H)-one 1613668-95-3 C16H16ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one 1613669-13-8 C18H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-sec-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one 1613669-14-9 C18H22ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-ethyl-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-cyclopentylpyrimidin-4(3H)-one 1613669-00-3 C17H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-5-methyl-2-cyclopentylpyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-2-butylthiopyrimidin-4(3H)-one 1613669-04-7 C16H18ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-2-butylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-cyclopentylthiopyrimidin-4(3H)-one 1613669-10-5 C18H20ClFN2OS
    6-[(2-chloro-6-fluorophenyl)ethyl]-5-methyl-2-cyclopentylthiopyrimidin-4(3H)-one
    —— 6-[(2-chloro-6-fluorophenyl)methyl]-2-isopropylthiopyrimidin-4(3H)-one 1613668-91-9 C14H14ClFN2OS
    6-[(2-chloro-6-fluorophenyl)methyl]-2-isopropylthiopyrimidin-4(3H)-one
    —— 4-(4-amino-benzylsulfanyl)-aniline 42497-98-3 C13H14N2S
    4-(4-amino-benzylsulfanyl)-aniline
    —— (2S)-2-amino-5-thiahexylamine 68013-51-4 C5H14N2S
    (2S)-2-amino-5-thiahexylamine
    —— 2-Chloro-4-(3-ethylphenylthio)benzaldehyde 1006727-30-5 C15H13ClOS
    2-Chloro-4-(3-ethylphenylthio)benzaldehyde
    —— Methoxymethyl-methyl-sulfon 39213-24-6 C3H8O3S
    Methoxymethyl-methyl-sulfon
    —— <<2-(methylthio)-1,3,4-thiadiazol-5-yl>thio><(4-methyl-5-thioxo-1,3,4-thiadiazolin-2-yl)thio>methane 105785-05-5 C7H8N4S6
    <<2-(methylthio)-1,3,4-thiadiazol-5-yl>thio><(4-methyl-5-thioxo-1,3,4-thiadiazolin-2-yl)thio>methane
    —— (5-Methyl-2-p-tolylsulfanyl-benzoyl)-phosphonic acid dimethyl ester 176509-36-7 C17H19O4PS
    (5-Methyl-2-p-tolylsulfanyl-benzoyl)-phosphonic acid dimethyl ester
    —— (Z)-methyl 3-(phenylthio)-4-(3-oxocyclopentyl)but-2-enoate 105090-06-0 C16H18O3S
    (Z)-methyl 3-(phenylthio)-4-(3-oxocyclopentyl)but-2-enoate
    —— 11-ethoxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline 144918-85-4 C14H12N4OS
    11-ethoxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline
    —— 11-(2-hydroxyethyl)oxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline 144918-90-1 C14H12N4O2S
    11-(2-hydroxyethyl)oxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline
    —— 11-hydroxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline 144918-74-1 C12H8N4OS
    11-hydroxy<1,2,4>triazolo<5',1': 2,3><1,3>thiazino<6,5-b>quinoline
    —— (E)-methyl 3-(phenylthio)-4-(3-oxocyclopentyl)but-2-enoate 105090-05-9 C16H18O3S
    (E)-methyl 3-(phenylthio)-4-(3-oxocyclopentyl)but-2-enoate
    —— 2-Ethyl-4H-11-thia-1,3,3a,10-tetraaza-cyclopenta[b]anthracen-4-ol 144918-76-3 C14H12N4OS
    2-Ethyl-4H-11-thia-1,3,3a,10-tetraaza-cyclopenta[b]anthracen-4-ol
    —— 2-Methyl-4H-11-thia-1,3,3a,10-tetraaza-cyclopenta[b]anthracen-4-ol 144918-75-2 C13H10N4OS
    2-Methyl-4H-11-thia-1,3,3a,10-tetraaza-cyclopenta[b]anthracen-4-ol
    —— 5-isopropyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one 1075181-63-3 C22H20N2OS2
    5-isopropyl-6-(1-naphthylmethyl)-2-[(thiophen-2-yl)thio]pyrimidin-4(3H)-one
    —— 3-Amino-4-cyano-5-methylsulfanyl-1H-pyrrole-2-carboxylic acid methyl ester 124476-08-0 C8H9N3O2S
    3-Amino-4-cyano-5-methylsulfanyl-1H-pyrrole-2-carboxylic acid methyl ester
    —— 5-cyano-6-methylthio-2-phenyl-4-thioxo-3,4-dihydropyrimidine 109228-96-8 C12H9N3S2
    5-cyano-6-methylthio-2-phenyl-4-thioxo-3,4-dihydropyrimidine
    —— 5-Amino-3-methylmercapto-4-cyan-isoxazol 68571-72-2 C5H5N3OS
    5-Amino-3-methylmercapto-4-cyan-isoxazol
    —— 5-Amino-1-methyl-3-(methylthio)-1λ<sup>4</sup>,2thiazin-4-carbonitril-1-oxid 112623-09-3 C7H9N3OS2
    5-Amino-1-methyl-3-(methylthio)-1λ<sup>4</sup>,2thiazin-4-carbonitril-1-oxid
    —— 5-cyano-2-methyl-6-methylthio-4-thioxo-3,4-dihydropyrimidine 144584-43-0 C7H7N3S2
    5-cyano-2-methyl-6-methylthio-4-thioxo-3,4-dihydropyrimidine
    —— 2-amino-5-[2-(2-chlorophenylthio)phenyl]-1,3,4-oxadiazole 1226870-88-7 C14H10ClN3OS
    2-amino-5-[2-(2-chlorophenylthio)phenyl]-1,3,4-oxadiazole
    —— fluhexafon 1097630-26-6 C12H17F3N2O3S
    fluhexafon
    —— 6-Amino-3-methylsulfanyl-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ol 87452-28-6 C12H17NOS
    6-Amino-3-methylsulfanyl-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-ol
    —— thioacetic acid <i>S</i>-(2-methanesulfonyl-ethyl ester) 96864-33-4 C5H10O3S2
    thioacetic acid <i>S</i>-(2-methanesulfonyl-ethyl ester)
    —— 2-methylsulfanyl-propene-1,1,3,3-tetracarbonitrile 98556-74-2 C8H4N4S
    2-methylsulfanyl-propene-1,1,3,3-tetracarbonitrile