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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-<(cyclopropylmethyl)thio>-2-methylpropanal 135937-99-4 C8H14OS
    2-<(cyclopropylmethyl)thio>-2-methylpropanal
    —— 1-(4-nitrophenylthio)phenylthio-4-(4-bromophenylthio)phenylthio-benzene 865179-31-3 C30H20BrNO2S4
    1-(4-nitrophenylthio)phenylthio-4-(4-bromophenylthio)phenylthio-benzene
    —— 4-(2,5-dichlorophenylthio)-3-(4-(dimethylamino)piperidin-1-ylsulfonyl)benzonitrile 1252681-82-5 C20H21Cl2N3O2S2
    4-(2,5-dichlorophenylthio)-3-(4-(dimethylamino)piperidin-1-ylsulfonyl)benzonitrile
    —— 4-Pyridyl-n-cetylthioether 10351-16-3 C21H37NS
    4-Pyridyl-n-cetylthioether
    —— 2-(3-butenylthio)-2-methylpropanal 135937-88-1 C8H14OS
    2-(3-butenylthio)-2-methylpropanal
    —— 5-cyano-2-(2,5-dimethylphenylthio)benzene-1-sulfonyl chloride 1252681-56-3 C15H12ClNO2S2
    5-cyano-2-(2,5-dimethylphenylthio)benzene-1-sulfonyl chloride
    —— 4-Allylmercapto-pyridin 10351-14-1 C8H9NS
    4-Allylmercapto-pyridin
    —— α-methylmercaptopropionamidine 13382-53-1 C4H8OS
    α-methylmercaptopropionamidine
    —— 4-bromophenyl thien-2-yl sulphide 140619-03-0 C10H7BrS2
    4-bromophenyl thien-2-yl sulphide
    —— 3-(4-Bromo-phenylsulfanyl)-butyraldehyde 81513-83-9 C10H11BrOS
    3-(4-Bromo-phenylsulfanyl)-butyraldehyde
    —— 2-Amino-4-ethylsulfanyl-6-methylsulfanyl-pyrimidine-5-carbonitrile 114460-78-5 C8H10N4S2
    2-Amino-4-ethylsulfanyl-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 4-(4-bromo-phenylsulfanyl)-pyridine-3-sulfonic acid amide 851708-90-2 C11H9BrN2O2S2
    4-(4-bromo-phenylsulfanyl)-pyridine-3-sulfonic acid amide
    —— 2-amino-4,6-bis-methylsulfanyl-pyrimidine-5-carbonitrile 114460-77-4 C7H8N4S2
    2-amino-4,6-bis-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 4-allylthio-2-amino-6-methylthio-5-cyanopyrimidine 111971-59-6 C9H10N4S2
    4-allylthio-2-amino-6-methylthio-5-cyanopyrimidine
    —— (4-bromophenyl)((1-(methoxymethyl)cyclopropyl)methyl)sulfane 1580441-37-7 C12H15BrOS
    (4-bromophenyl)((1-(methoxymethyl)cyclopropyl)methyl)sulfane
    —— 1-(4-methoxyphenylthio)-4-(4-bromophenylthio)benzene 865179-24-4 C19H15BrOS2
    1-(4-methoxyphenylthio)-4-(4-bromophenylthio)benzene
    —— 1-(4-bromo-phenylsulfanyl)-2,4-difluoro-benzene 1451093-03-0 C12H7BrF2S
    1-(4-bromo-phenylsulfanyl)-2,4-difluoro-benzene
    —— 1-(4-bromo-phenylsulfanyl)-3,5-dichloro-benzene 1451093-06-3 C12H7BrCl2S
    1-(4-bromo-phenylsulfanyl)-3,5-dichloro-benzene
    —— (4-bromophenyl)(3,3-dimethylbutyl)sulfane 1580441-32-2 C12H17BrS
    (4-bromophenyl)(3,3-dimethylbutyl)sulfane
    —— 1-bromo-4-(2-(trifluoromethyl)phenylsulfanyl)-benzene 1451092-98-0 C13H8BrF3S
    1-bromo-4-(2-(trifluoromethyl)phenylsulfanyl)-benzene
    —— {3-[(4-Bromophenyl)sulfanyl]propoxy}(tert-butyl)dimethylsilane 1310948-07-2 C15H25BrOSSi
    {3-[(4-Bromophenyl)sulfanyl]propoxy}(tert-butyl)dimethylsilane
    —— (2-Amino-5-cyano-6-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid ethyl ester 114473-48-2 C10H12N4O2S2
    (2-Amino-5-cyano-6-methylsulfanyl-pyrimidin-4-ylsulfanyl)-acetic acid ethyl ester
    —— 1-[(4-bromophenyl)sulphanyl]-3,3,-dimethyl-2-(1,3-thiazol-5-yl)butan-2-ol 1350754-61-8 C15H18BrNOS2
    1-[(4-bromophenyl)sulphanyl]-3,3,-dimethyl-2-(1,3-thiazol-5-yl)butan-2-ol
    —— 1-[2-(4-bromo-phenylsulfanyl)-ethyl]-pyrrolidine 7037-39-0 C12H16BrNS
    1-[2-(4-bromo-phenylsulfanyl)-ethyl]-pyrrolidine
    —— 3-((4-bromophenyl)thio)quinoline 1299398-55-2 C15H10BrNS
    3-((4-bromophenyl)thio)quinoline
    —— 3-(4-Bromophenylthio)-4-chloro-9H-thioxanthen-9-one 1372152-39-0 C19H10BrClOS2
    3-(4-Bromophenylthio)-4-chloro-9H-thioxanthen-9-one
    —— 2-(4-bromophenylthio)-5-(tert-butylsulfonyl)pyrazine 1428549-06-7 C14H15BrN2O2S2
    2-(4-bromophenylthio)-5-(tert-butylsulfonyl)pyrazine
    —— 2-[(4-bromophenyl)thio]-N,N-diethylacetamide 927869-02-1 C12H16BrNOS
    2-[(4-bromophenyl)thio]-N,N-diethylacetamide
    —— (4-bromo-phenylsulfanyl)-pyruvic acid 104186-14-3 C9H7BrO3S
    (4-bromo-phenylsulfanyl)-pyruvic acid
    —— {2-[(4-bromophenyl)thio]ethoxy}(t-butyl)dimethylsilane 879488-02-5 C14H23BrOSSi
    {2-[(4-bromophenyl)thio]ethoxy}(t-butyl)dimethylsilane
    —— 2-((4-bromophenyl)thio)quinoline-3-carbaldehyde 1309388-91-7 C16H10BrNOS
    2-((4-bromophenyl)thio)quinoline-3-carbaldehyde
    —— 4-((4-bromophenyl)thio)-4-phenylbutan-2-one 1224876-31-6 C16H15BrOS
    4-((4-bromophenyl)thio)-4-phenylbutan-2-one
    —— ((4-nitrophenylthio)phenyl)((4-bromophenylthio)phenyl)thioether 865179-29-9 C24H16BrNO2S3
    ((4-nitrophenylthio)phenyl)((4-bromophenylthio)phenyl)thioether
    —— 1-(4-nitrophenylthio)-4-(4-bromophenylthio)benzene 865179-25-5 C18H12BrNO2S2
    1-(4-nitrophenylthio)-4-(4-bromophenylthio)benzene
    —— 2-methanesulfinyl-2-methyl-propan-1-ol 25841-37-6 C5H12O2S
    2-methanesulfinyl-2-methyl-propan-1-ol
    —— N-Methallyl-N-methylthiocarbamidsaeure-O-ethylester 62371-13-5 C8H15NOS
    N-Methallyl-N-methylthiocarbamidsaeure-O-ethylester
    —— 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid m-(phenylthio)benzyl ester 26003-02-1 C23H26O2S
    2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid m-(phenylthio)benzyl ester
    —— 2-Methylmercapto-5-(4-chlor-phenylmercapto)-pyrimidin-4-carbonsaeure 25818-46-6 C12H9ClN2O2S2
    2-Methylmercapto-5-(4-chlor-phenylmercapto)-pyrimidin-4-carbonsaeure
    —— 2-methylsulfinyl isobutyramide 25841-41-2 C5H11NO2S
    2-methylsulfinyl isobutyramide
    —— 4-Nitro-4'-carbomethoxydiphenylsulfid 33174-25-3 C14H11NO4S
    4-Nitro-4'-carbomethoxydiphenylsulfid
    —— 1-Methoxymethyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-55-5 C15H15N3O4S
    1-Methoxymethyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— 1-(Z-2-butenyloxy)-1-(phenylthio)propane 132816-07-0 C13H18OS
    1-(Z-2-butenyloxy)-1-(phenylthio)propane
    —— 2-Methylmercapto-5-(4-methyl-phenylmercapto)-pyrimido-4-carbonsaeure 26032-74-6 C13H12N2O2S2
    2-Methylmercapto-5-(4-methyl-phenylmercapto)-pyrimido-4-carbonsaeure
    —— (2S,3S,4S,6R)-2-Methyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 141805-54-1 C12H16O3S
    (2S,3S,4S,6R)-2-Methyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol
    —— E-S-Phenyl Acetothiohydroximate 132637-62-8 C8H9NOS
    E-S-Phenyl Acetothiohydroximate
    —— 1-Ethyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54458-17-2 C15H15N3O3S
    1-Ethyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— 2-[4-(4-nitro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione 38571-22-1 C15H10N4O4S
    2-[4-(4-nitro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione
    —— 1-Isopropyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-52-2 C16H17N3O3S
    1-Isopropyl-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— N<sup>1</sup>-<4-(4-Nitrophenylthio)phenyl>-N<sup>3</sup>-phenylthiourea 78924-18-2 C19H15N3O2S2
    N<sup>1</sup>-<4-(4-Nitrophenylthio)phenyl>-N<sup>3</sup>-phenylthiourea
    —— N'-[2,4-bis(methylthio)-6-methyl-pyridin-3-yl]-N-heptyl-N-[2-[4-(3-hydroxypropyl)piperazin-1-yl]ethyl]urea 664340-40-3 C25H45N5O2S2
    N'-[2,4-bis(methylthio)-6-methyl-pyridin-3-yl]-N-heptyl-N-[2-[4-(3-hydroxypropyl)piperazin-1-yl]ethyl]urea