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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,9-dioxa-6-thiacyclodecan-1-ol-6,6-dioxide 1067244-39-6 C7H14O5S
    3,9-dioxa-6-thiacyclodecan-1-ol-6,6-dioxide
    —— 2,6-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-36-9 C10H10N2OS2
    2,6-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(methylthio)pyridin-2-amine hydrochloride 936245-10-2 C17H17N3OS2*ClH
    3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(methylthio)pyridin-2-amine hydrochloride
    —— 1-methyl-2-azathiabenzene 1-oxide 88628-88-0 C5H7NOS
    1-methyl-2-azathiabenzene 1-oxide
    —— 4-fluoro-α-[[(2-fluorophenyl)thio]methyl]-benzeneacetic acid 131210-55-4 C15H12F2O2S
    4-fluoro-α-[[(2-fluorophenyl)thio]methyl]-benzeneacetic acid
    —— 2-(2-carbamimidoylsulfanylethoxy)ethyl carbamimidothioate;hydron;dichloride —— C6H16Cl2N4OS2
    2-(2-carbamimidoylsulfanylethoxy)ethyl carbamimidothioate;hydron;dichloride
    —— 2,2,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 126636-79-1 C11H12N2OS2
    2,2,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 4-carboxy-1-methyl-2-azathiabenzene 1-oxide 88628-87-9 C6H7NO3S
    4-carboxy-1-methyl-2-azathiabenzene 1-oxide
    —— 3-(4-methylsulfanyl-1H-pyrazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine 1073551-34-4 C10H15N3S
    3-(4-methylsulfanyl-1H-pyrazol-3-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— 2,6,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-37-0 C11H12N2OS2
    2,6,8-Trimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— (4-Cyclohexyl-pentyl)-{2-[2-(4-cyclohexyl-pentylamino)-ethyldisulfanyl]-ethyl}-amine 90378-83-9 C26H52N2S2
    (4-Cyclohexyl-pentyl)-{2-[2-(4-cyclohexyl-pentylamino)-ethyldisulfanyl]-ethyl}-amine
    —— (Methylcarbonylthio)(methylsulfonyl)methane 89986-83-4 C4H8O3S2
    (Methylcarbonylthio)(methylsulfonyl)methane
    —— 5-methylthio-2-furonitrile 106240-49-7 C6H5NOS
    5-methylthio-2-furonitrile
    —— 8-Ethyl-2-methyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-38-1 C11H12N2OS2
    8-Ethyl-2-methyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— 2,8-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one 120079-35-8 C10H10N2OS2
    2,8-Dimethyl-2,3-dihydro-thiazolo[3,2-a]thieno[3,4-d]pyrimidin-5-one
    —— <i>N</i>-allyl-<i>N</i>'-isobutyl-thiourea 23328-50-9 C8H16N2S
    <i>N</i>-allyl-<i>N</i>'-isobutyl-thiourea
    —— 3,3'-bis(phenylthio)<2>staffane 115092-69-8 C22H22S2
    3,3'-bis(phenylthio)<2>staffane
    —— 5-(methylmercapto)-2-pyrimidinone 75670-14-3 C5H6N2OS
    5-(methylmercapto)-2-pyrimidinone
    —— (3,3-Dimethyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine 160976-82-9 C19H21NS
    (3,3-Dimethyl-2-phenylsulfanyl-but-1-enylidene)-p-tolyl-amine
    —— (2-fluoro-4-(methylsulfanyl)benzyl)carbamic acid tert-butyl ester 1570084-49-9 C13H18FNO2S
    (2-fluoro-4-(methylsulfanyl)benzyl)carbamic acid tert-butyl ester
    —— <i>N</i>-allyl-<i>N</i>'-octadecyl-thiourea 7460-25-5 C22H44N2S
    <i>N</i>-allyl-<i>N</i>'-octadecyl-thiourea
    —— 5-(6-chloro-pyridin-3-ylmethyl)-2-methylsulfanyl-1H-pyrimidin-4-one 1380430-99-8 C11H10ClN3OS
    5-(6-chloro-pyridin-3-ylmethyl)-2-methylsulfanyl-1H-pyrimidin-4-one
    —— 1,10-Di-(ethylsulphinyl)-decan 28242-23-1 C14H30O2S2
    1,10-Di-(ethylsulphinyl)-decan
    —— [4-chloro-6-(4-chloro-benzylamino)-5-methyl-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-46-1 C16H17Cl2N3O2S
    [4-chloro-6-(4-chloro-benzylamino)-5-methyl-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-25-6 C15H15Cl2N3O2S
    [4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— [4-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-43-8 C15H16ClN3O2S
    [4-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— 2-carbethoxymethylthio-4-chloropyrimidine 50892-52-9 C8H9ClN2O2S
    2-carbethoxymethylthio-4-chloropyrimidine
    —— (4,6-dichloro-5-methyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester 50892-45-0 C9H10Cl2N2O2S
    (4,6-dichloro-5-methyl-pyrimidin-2-ylsulfanyl)-acetic acid ethyl ester
    —— 2-[4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-propionic acid 50892-40-5 C14H13Cl2N3O2S
    2-[4-chloro-6-(4-chloro-benzylamino)-pyrimidin-2-ylsulfanyl]-propionic acid
    —— S-(1-Thiomethoxyaethyl)-thioacetat 38634-60-5 C5H10OS2
    S-(1-Thiomethoxyaethyl)-thioacetat
    —— 2-methylthio-1,3-propanediol 58620-10-3 C4H10O2S
    2-methylthio-1,3-propanediol
    —— 8-methylthiopyrido<2,3-d>pyridazine 21170-68-3 C8H7N3S
    8-methylthiopyrido<2,3-d>pyridazine
    —— 1-(Diethylamino)-7-methyl-5-phenyl-3,4-(6-chlorobenzo)-2,6-thiazabicyclo<3.2.0>hepta-3,6-diene 84538-81-8 C20H21ClN2S
    1-(Diethylamino)-7-methyl-5-phenyl-3,4-(6-chlorobenzo)-2,6-thiazabicyclo<3.2.0>hepta-3,6-diene
    —— 3-(4-methylbenzenesulfenyl)-2-pyridone 107383-65-3 C12H11NOS
    3-(4-methylbenzenesulfenyl)-2-pyridone
    —— 2-Methyl-3-phenyl-3-(phenylthio)-2-propensaeure-diethylthioamid 80438-75-1 C20H23NS2
    2-Methyl-3-phenyl-3-(phenylthio)-2-propensaeure-diethylthioamid
    —— 22276-34-2 C22H24S4
    —— 2-amino-5-(4-aminopyrimidin-2-ylthio)thiazole 133691-91-5 C7H7N5S2
    2-amino-5-(4-aminopyrimidin-2-ylthio)thiazole
    —— N-Cycloheptyl-2-(N-cycloheptylcarbamimidoylmethyldisulfanyl)-acetamidine 90379-61-6 C18H34N4S2
    N-Cycloheptyl-2-(N-cycloheptylcarbamimidoylmethyldisulfanyl)-acetamidine
    —— Ethyl 5-Amino-3-phenyl-2H-pyrido[4,3-b][1,4]-thiazin-7-ylcarbamate 86970-55-0 C16H16N4O2S
    Ethyl 5-Amino-3-phenyl-2H-pyrido[4,3-b][1,4]-thiazin-7-ylcarbamate
    —— (5-fluoro-2-(2-(hydroxymethyl)-4-(methylsulfonyl)phenylthio)phenyl)methanol 1062599-88-5 C15H15FO4S2
    (5-fluoro-2-(2-(hydroxymethyl)-4-(methylsulfonyl)phenylthio)phenyl)methanol
    —— 1-bromo-10-isothiocyanato-decane 31520-36-2 C11H20BrNS
    1-bromo-10-isothiocyanato-decane
    —— ethyl (5-amino-2-methyl-3-phenyl-2H-pyrido<4,3-b><1,4>thiazin-7-yl)carbamate 86970-56-1 C17H18N4O2S
    ethyl (5-amino-2-methyl-3-phenyl-2H-pyrido<4,3-b><1,4>thiazin-7-yl)carbamate
    —— 5-aminospiro[benzo[b]thiophene-2(3H),1'-cyclopropan]-3-one 79003-01-3 C10H9NOS
    5-aminospiro[benzo[b]thiophene-2(3H),1'-cyclopropan]-3-one
    —— 5-methylthiospiro[benzo[b]furan-2(3H), 1'-cyclopropane]-3-one 79003-13-7 C11H10OS
    5-methylthiospiro[benzo[b]furan-2(3H), 1'-cyclopropane]-3-one
    —— 5-amino-4',5'-dihydrospiro<benzo<b>thiophene-2(3H),3'(2'H)-furan>-3,2'-dione 79003-19-3 C11H9NO3S
    5-amino-4',5'-dihydrospiro<benzo<b>thiophene-2(3H),3'(2'H)-furan>-3,2'-dione
    —— 5-nitro-4',5'-dihydrospiro[benzo[b]thiophene-2(3H),3'(2'H)-furan]-3,2'-dione 79003-35-3 C11H7NO5S
    5-nitro-4',5'-dihydrospiro[benzo[b]thiophene-2(3H),3'(2'H)-furan]-3,2'-dione
    —— 2-[(2-amino-2-cycloheptyliminoethyl)disulfanyl]-N'-cycloheptylethanimidamide;hydron;dichloride —— C18H36Cl2N4S2
    2-[(2-amino-2-cycloheptyliminoethyl)disulfanyl]-N'-cycloheptylethanimidamide;hydron;dichloride
    —— 1-Benzenesulfonyl-2-morpholin-4-ylmethyl-3-phenylsulfanyl-1H-indole 85678-46-2 C25H24N2O3S2
    1-Benzenesulfonyl-2-morpholin-4-ylmethyl-3-phenylsulfanyl-1H-indole
    —— p-(2-phenylthio-1-chloroethyl)benzyltrimethylstannane 112122-84-6 C18H23ClSSn
    p-(2-phenylthio-1-chloroethyl)benzyltrimethylstannane
    —— 2-[(4-bromo-3,5-dimethylphenyl)thio]ethyl ethyl ether 865138-55-2 C12H17BrOS
    2-[(4-bromo-3,5-dimethylphenyl)thio]ethyl ethyl ether