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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-Morpholinyl)ethyl (phenylthio)acetate hydrochloride 35859-26-8 C14H20ClNO3S
    2-(4-Morpholinyl)ethyl (phenylthio)acetate hydrochloride
    —— 6-Cyano-5-oxothiazolidino<3,2-a>pyrimidin 32084-54-1 C7H5N3OS
    6-Cyano-5-oxothiazolidino<3,2-a>pyrimidin
    —— (2-Aminoaethyl)-octyl-disulfid 105532-69-2 C10H23NS2
    (2-Aminoaethyl)-octyl-disulfid
    —— 4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetonitrile 54413-88-6 C16H15NOS2
    4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetonitrile
    —— 4-methoxy-6-{[4'-(methylthio)-phenyl]-thio}-benzyl chloride 54413-87-5 C15H15ClOS2
    4-methoxy-6-{[4'-(methylthio)-phenyl]-thio}-benzyl chloride
    —— (2-Aminoaethyl)-butyl-disulfid 95056-38-5 C6H15NS2
    (2-Aminoaethyl)-butyl-disulfid
    —— 4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetic acid 54413-89-7 C16H16O3S2
    4-methoxy-6-[(4'-methylthio-phenyl)-thio]-phenylacetic acid
    —— 3-Cyclohexylsulfonyl-propylbromid 5755-73-7 C9H17BrO2S
    3-Cyclohexylsulfonyl-propylbromid
    —— 2-p-Tolyl-6,7-dihydro-thiazolo[3,2-a][1,3,5]triazin-4-one 82256-17-5 C12H11N3OS
    2-p-Tolyl-6,7-dihydro-thiazolo[3,2-a][1,3,5]triazin-4-one
    —— 6-(2-hydroxy-ethyl)-5-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-7-one 53750-92-8 C9H12N2O2S
    6-(2-hydroxy-ethyl)-5-methyl-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-7-one
    —— N-(2-Mercaptoaethyl)-thioharnstoff 15267-06-8 C3H8N2S2
    N-(2-Mercaptoaethyl)-thioharnstoff
    —— 2-(Cyclopropyl)-2-thiazolin 55089-25-3 C6H9NS
    2-(Cyclopropyl)-2-thiazolin
    —— 2-(dimethylamino)ethyl 2-phenylsulfanylacetate;hydron;chloride —— C12H18ClNO2S
    2-(dimethylamino)ethyl 2-phenylsulfanylacetate;hydron;chloride
    —— 1-bromo-4-[1,2,2,2-tetradeuterio-1-(trideuteriomethyl)ethyl]sulfanyl-benzene 1428935-50-5 C9H11BrS
    1-bromo-4-[1,2,2,2-tetradeuterio-1-(trideuteriomethyl)ethyl]sulfanyl-benzene
    —— 2-(4-Morpholinyl)ethyl ((4-methylphenyl)thio)acetate hydrochloride 35859-40-6 C15H22ClNO3S
    2-(4-Morpholinyl)ethyl ((4-methylphenyl)thio)acetate hydrochloride
    —— Carbamic acid 2,2-dimethyl-[1,3]dithiolan-4-ylmethyl ester 35801-62-8 C7H13NO2S2
    Carbamic acid 2,2-dimethyl-[1,3]dithiolan-4-ylmethyl ester
    —— 2-(Dimethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride 35859-32-6 C13H20ClNO2S
    2-(Dimethylamino)ethyl ((4-methylphenyl)thio)acetate hydrochloride
    —— hydron;2-piperidin-1-ylethyl 2-(4-methylphenyl)sulfanylacetate;chloride —— C16H24ClNO2S
    hydron;2-piperidin-1-ylethyl 2-(4-methylphenyl)sulfanylacetate;chloride
    —— 2-carbamoyloxymethyl-1,4-dithia-spiro[4.5]decane 35877-41-9 C10H17NO2S2
    2-carbamoyloxymethyl-1,4-dithia-spiro[4.5]decane
    —— 1-(phenylsulfonyl)-3-(phenylthio)-1H-indole-2-carbaldehyde 643001-32-5 C21H15NO3S2
    1-(phenylsulfonyl)-3-(phenylthio)-1H-indole-2-carbaldehyde
    —— Dimethyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 85678-47-3 C17H18N2S
    Dimethyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine
    —— 2-(β-hydroxyethylthio)-5-aminophenol 146310-38-5 C8H11NO2S
    2-(β-hydroxyethylthio)-5-aminophenol
    —— 2-(4-Morpholinyl)ethyl ((4-chlorophenyl)thio)acetate hydrochloride 35859-48-4 C14H19Cl2NO3S
    2-(4-Morpholinyl)ethyl ((4-chlorophenyl)thio)acetate hydrochloride
    —— (Z)-4-ethyl-5-(phenylthio)-1,4-nonadiene 217803-24-2 C17H24S
    (Z)-4-ethyl-5-(phenylthio)-1,4-nonadiene
    —— phenyl tris(trimethylsilyl)tetrahedranyl sulfide 1313728-12-9 C19H32SSi3
    phenyl tris(trimethylsilyl)tetrahedranyl sulfide
    —— dicyclopropyl sulfide 45468-25-5 C6H10S
    dicyclopropyl sulfide
    —— 4-(4-Chloro-phenylsulfanyl)-4-(2,4,6-trimethyl-phenyl)-butyric acid 37014-91-8 C19H21ClO2S
    4-(4-Chloro-phenylsulfanyl)-4-(2,4,6-trimethyl-phenyl)-butyric acid
    —— 4,7-Bis-(methylthio)-1,2,5-thiadiazolo<3,4,-d>pyridazin 33097-33-5 C6H6N4S3
    4,7-Bis-(methylthio)-1,2,5-thiadiazolo<3,4,-d>pyridazin
    —— N-methyl-N-[2-(1-methyl-cyclopropoxy)-ethyl]-thioacetamide 786686-63-3 C9H17NOS
    N-methyl-N-[2-(1-methyl-cyclopropoxy)-ethyl]-thioacetamide
    —— (2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran 477200-80-9 C38H56O3SSi2
    (2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-4-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran
    —— [Amino(ethylsulfanyl)methylidene]azanium;[ethoxy(oxido)phosphoryl] ethyl phosphate —— C10H28N4O7P2S2
    [Amino(ethylsulfanyl)methylidene]azanium;[ethoxy(oxido)phosphoryl] ethyl phosphate
    —— {(2R,4S,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-acetic acid methyl ester 477200-78-5 C23H38O4SSi
    {(2R,4S,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-acetic acid methyl ester
    —— 2,4,6,7,9,11-Hexathiadecane 2,2,11,11-tetraoxide 155994-72-2 C6H14O4S6
    2,4,6,7,9,11-Hexathiadecane 2,2,11,11-tetraoxide
    —— 2-{(2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-ethanol 477200-79-6 C22H38O3SSi
    2-{(2R,4R,6S)-2-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-4-yl}-ethanol
    —— (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienal 477200-85-4 C37H46O3SSi
    (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dienal
    —— (R)-2-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-propan-1-ol 477200-81-0 C32H42O3SSi
    (R)-2-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-propan-1-ol
    —— (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dien-1-ol 477200-84-3 C37H48O3SSi
    (2E,4E)-(R)-6-{(2R,4R,6S)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-phenylsulfanyl-tetrahydro-pyran-2-yl}-2-methyl-hepta-2,4-dien-1-ol
    —— 1,2-Bis(n-butylthio)hexan 54796-92-8 C14H30S2
    1,2-Bis(n-butylthio)hexan
    —— 3-Methylsulfanyl-selenophene-2-carbaldehyde 113123-68-5 C6H6OSSe
    3-Methylsulfanyl-selenophene-2-carbaldehyde
    —— 2-[3-carboxymethyl-4-(2-carboxyphenylthio)phenyl]propionic acid 203519-15-7 C18H16O6S
    2-[3-carboxymethyl-4-(2-carboxyphenylthio)phenyl]propionic acid
    —— 5.5'-Dimethyl-2.2'-bi-2-thiazolin 41601-93-8 C8H12N2S2
    5.5'-Dimethyl-2.2'-bi-2-thiazolin
    —— 3-Bromo-4-(methylthio) selenophene 82451-15-8 C5H5BrSSe
    3-Bromo-4-(methylthio) selenophene
    —— 7,7-(1,2-Benzenediyldithio)-6-methylbicyclo<3.2.1>octan-2-one 115436-05-0 C15H16OS2
    7,7-(1,2-Benzenediyldithio)-6-methylbicyclo<3.2.1>octan-2-one
    —— 2-amino-3,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-4,6-dione 37489-43-3 C6H6N4O2S
    2-amino-3,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-4,6-dione
    —— bis(2,4-di-tert-butyl-6-methylphenyl)sulfane 1202870-60-7 C30H46S
    bis(2,4-di-tert-butyl-6-methylphenyl)sulfane
    —— N-Carbethoxy-thiomethylurethan 51291-77-1 C5H9NO3S
    N-Carbethoxy-thiomethylurethan
    —— (2,4-di-tert-butyl-6-bromophenyl)-(2,4-di-tert-butyl-6-methylphenyl)sulfane 1190974-83-4 C29H43BrS
    (2,4-di-tert-butyl-6-bromophenyl)-(2,4-di-tert-butyl-6-methylphenyl)sulfane
    —— 2-thioxo-2,3,6,7-tetrahydro-thiazolo[3,2-<i>a</i>][1,3,5]triazin-4-one 34683-33-5 C5H5N3OS2
    2-thioxo-2,3,6,7-tetrahydro-thiazolo[3,2-<i>a</i>][1,3,5]triazin-4-one
    —— 2,6-bis[[(2,3-difluorophenyl)methyl]thio]-4,5-pyrimidinediamine 354582-93-7 C18H14F4N4S2
    2,6-bis[[(2,3-difluorophenyl)methyl]thio]-4,5-pyrimidinediamine
    —— 4-methylsulfanyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-ylamine 37489-30-8 C7H8N4S2
    4-methylsulfanyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-ylamine