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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine 151358-52-0 C20H24FNO3S
    N-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine
    —— 4-((4-chlorophenyl)thio)-4-(thiophen-2-yl)butan-2-one 1420293-51-1 C14H13ClOS2
    4-((4-chlorophenyl)thio)-4-(thiophen-2-yl)butan-2-one
    —— 6-tert-butyl-2,2-dimethyl-2,3-dihydropyran-4-thione 245068-79-5 C11H18OS
    6-tert-butyl-2,2-dimethyl-2,3-dihydropyran-4-thione
    —— 2-Fluoro-4-(3-trifluoromethylphenylthio)benzaldehyde 1006727-27-0 C14H8F4OS
    2-Fluoro-4-(3-trifluoromethylphenylthio)benzaldehyde
    —— 2-Amino-4-(5-fluoromethyl-furan-2-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 357289-75-9 C11H9FN4OS
    2-Amino-4-(5-fluoromethyl-furan-2-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— Dinitro-bis(phenylthio)methan 58174-58-6 C13H10N2O4S2
    Dinitro-bis(phenylthio)methan
    —— (Z)-2-Methyl-3,4-bis-phenylsulfanyl-but-3-en-2-ol 89005-26-5 C17H18OS2
    (Z)-2-Methyl-3,4-bis-phenylsulfanyl-but-3-en-2-ol
    —— ((Z)-2-Ethoxy-3-methyl-but-1-enylsulfanyl)-benzene 89005-24-3 C13H18OS
    ((Z)-2-Ethoxy-3-methyl-but-1-enylsulfanyl)-benzene
    —— 6-phenylsulfanyl-(5S)-2-hexyne-1,5-diol 577749-31-6 C12H14O2S
    6-phenylsulfanyl-(5S)-2-hexyne-1,5-diol
    —— 6-bromo-3,3-dimethyl-2,3-dihydrobenzo[b]thiophene 153561-56-9 C10H11BrS
    6-bromo-3,3-dimethyl-2,3-dihydrobenzo[b]thiophene
    —— 1-t-butylthio-3-methyl-1,3-butadiene 87745-46-8 C9H16S
    1-t-butylthio-3-methyl-1,3-butadiene
    —— 1,1,2,2-Tetrakis(methyldisulfanyl)ethane 5418-92-8 C6H14S8
    1,1,2,2-Tetrakis(methyldisulfanyl)ethane
    —— 3-Amino-propyl-mercapto-essigsaeure-sulfon 66740-36-1 C5H11NO4S
    3-Amino-propyl-mercapto-essigsaeure-sulfon
    —— N-(N,N'-Diethylcarbamimidoyl)-N,N'-diethylthiourea 61479-68-3 C10H22N4S
    N-(N,N'-Diethylcarbamimidoyl)-N,N'-diethylthiourea
    —— 5-isothiocyanatopent-1-yne 152417-98-6 C6H7NS
    5-isothiocyanatopent-1-yne
    —— 1-[2,6-di-t-butyldiphenylsilyloxy-(2S,4E)-4-hexenylsulfanyl]benzene 577749-33-8 C44H52O2SSi2
    1-[2,6-di-t-butyldiphenylsilyloxy-(2S,4E)-4-hexenylsulfanyl]benzene
    —— 6-phenylsulfanyl-(E,2S)-2-hexene-1,5-diol 577749-32-7 C12H16O2S
    6-phenylsulfanyl-(E,2S)-2-hexene-1,5-diol
    —— 3-(2-methylphenyl)-2-(2-methylphenyl)amino-5-cyano-6-thiomethylpyrimidin-4(H)-one 260389-05-7 C20H18N4OS
    3-(2-methylphenyl)-2-(2-methylphenyl)amino-5-cyano-6-thiomethylpyrimidin-4(H)-one
    —— 2-(4-chlorophenyl)-6-methylthiothiazolo<4,5-d><3,1>oxazin-4-one 147235-60-7 C12H7ClN2O2S2
    2-(4-chlorophenyl)-6-methylthiothiazolo<4,5-d><3,1>oxazin-4-one
    —— 4-n-Octylthiopyrrole 120884-80-2 C12H21NS
    4-n-Octylthiopyrrole
    —— 4-{[4-({[3-(2,6-dichlorophenyl)-5-(1-methylethyl)-4-isoxazolyl]methyl}oxy)phenyl]thio}-1-benzothiophene-2-carboxylic acid 1093631-60-7 C28H21Cl2NO4S2
    4-{[4-({[3-(2,6-dichlorophenyl)-5-(1-methylethyl)-4-isoxazolyl]methyl}oxy)phenyl]thio}-1-benzothiophene-2-carboxylic acid
    —— 4-Ethylthiopyrrole 120884-76-6 C6H9NS
    4-Ethylthiopyrrole
    —— p-tolyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-1-thio-2-deoxy-β-D-ribofuranoside 1402737-65-8 C24H42O4SSi2
    p-tolyl-3,5-O-(tetraisopropylsiloxane-1,3-diyl)-1-thio-2-deoxy-β-D-ribofuranoside
    —— 2-Amino-4-isoxazol-5-yl-6-methylsulfanyl-pyrimidine-5-carbonitrile 357284-47-0 C9H7N5OS
    2-Amino-4-isoxazol-5-yl-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— N-(4-(4-(5-methyl-1H-pyrazol-3-ylamino)-6-morpholinopyrimidin-2-ylthio)phenyl)propionamide —— C21H25N7O2S
    N-(4-(4-(5-methyl-1H-pyrazol-3-ylamino)-6-morpholinopyrimidin-2-ylthio)phenyl)propionamide
    —— N-[4-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-piperidin-1-ylpyrimidin-2-yl]sulfanylphenyl]propanamide —— C22H27N7OS
    N-[4-[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-piperidin-1-ylpyrimidin-2-yl]sulfanylphenyl]propanamide
    —— (1,1-difluoro-2-phenyl-1-phenylsulfanylpropan-2-oxy)trimethylsilane 899820-55-4 C18H22F2OSSi
    (1,1-difluoro-2-phenyl-1-phenylsulfanylpropan-2-oxy)trimethylsilane
    —— 2,2-difluoro-1-(4-bromophenyl)-2-phenylsulfanyl-1-trimethoxysiloxyethane 899820-47-4 C17H19BrF2OSSi
    2,2-difluoro-1-(4-bromophenyl)-2-phenylsulfanyl-1-trimethoxysiloxyethane
    —— 2-((5-((2-(Dimethylamino)-1-methylethyl)thio)-1,3,4-thiadiazol-2-yl)thio)-N,N-dimethyl-1-propanamine 6292-05-3 C12H24N4S3
    2-((5-((2-(Dimethylamino)-1-methylethyl)thio)-1,3,4-thiadiazol-2-yl)thio)-N,N-dimethyl-1-propanamine
    —— 4-({4-[(2-amino-6-ethyl-4-pyrimidinyl)amino]phenyl}sulfanyl)phenol 569658-12-4 C18H18N4OS
    4-({4-[(2-amino-6-ethyl-4-pyrimidinyl)amino]phenyl}sulfanyl)phenol
    —— 6-ethyl-N4-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]-2,4-pyrimidinediamine 570415-02-0 C17H16FN5S
    6-ethyl-N4-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]-2,4-pyrimidinediamine
    —— 2-Chlor-3-methylsulfonyl-propionamid 10568-98-6 C4H8ClNO3S
    2-Chlor-3-methylsulfonyl-propionamid
    —— 2,5-bis[2'-(5'-chlorothienyl)sulfanyl]thiophene 1211374-98-9 C12H6Cl2S5
    2,5-bis[2'-(5'-chlorothienyl)sulfanyl]thiophene
    —— 3-acetamidothiopropionamide 76275-89-3 C5H10N2OS
    3-acetamidothiopropionamide
    —— [3-(1-Phenylsulfanylethyl)phenyl]boronic acid 1332344-51-0 C14H15BO2S
    [3-(1-Phenylsulfanylethyl)phenyl]boronic acid
    —— 1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314034-04-2 C26H34ClN3S
    1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314034-03-1 C14H14ClN3S
    1-[4-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine
    —— 4-<(3,6-Dichlor-2-pyridinyl)-methylthio>-benzolamin 58803-97-7 C12H10Cl2N2S
    4-<(3,6-Dichlor-2-pyridinyl)-methylthio>-benzolamin
    —— N-(4-(4-chloro-6-(3-methyl-1H-pyrazol-5-ylamino)pyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide 1061682-24-3 C17H14ClF3N6OS
    N-(4-(4-chloro-6-(3-methyl-1H-pyrazol-5-ylamino)pyrimidin-2-ylthio)phenyl)-3,3,3-trifluoropropanamide
    —— 2-(4-aminophenylthio)-6-methoxyquinoline 190331-35-2 C16H14N2OS
    2-(4-aminophenylthio)-6-methoxyquinoline
    —— 1-[4-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-12-2 C14H13Br2N3S
    1-[4-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— S-dimethylcarbamoyl-p-aminothiophenol 112308-01-7 C9H12N2OS
    S-dimethylcarbamoyl-p-aminothiophenol
    —— 4-Carboxymethylthio-5H-pyrimido <4.5-b>-thiazin-6(7H)-on 65247-65-6 C8H7N3O3S2
    4-Carboxymethylthio-5H-pyrimido <4.5-b>-thiazin-6(7H)-on
    —— methanesulfonic acid 3-{4-[4-(3-methanesulfonyloxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl}-propyl ester 719294-09-4 C22H24F6O6S3
    methanesulfonic acid 3-{4-[4-(3-methanesulfonyloxy-propyl)-2-trifluoromethyl-phenylsulfanyl]-3-trifluoromethyl-phenyl}-propyl ester
    —— 2,5-bis{2'-[5'-(4''-aminophenyl)sulfanyl]thienyl}thiophene 1211374-99-0 C24H18N2S7
    2,5-bis{2'-[5'-(4''-aminophenyl)sulfanyl]thienyl}thiophene
    —— 2-(2'-propyl)-5,6-dihydro-1,4-dithiin-1,1,4,4-tetroxide 68090-31-3 C7H12O4S2
    2-(2'-propyl)-5,6-dihydro-1,4-dithiin-1,1,4,4-tetroxide
    —— 5-(4-Dimethylsulfamoyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide 63032-35-9 C12H14N2O4S4
    5-(4-Dimethylsulfamoyl-phenylsulfanyl)-thiophene-2-sulfonic acid amide
    —— 6-(4-aminophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine 1076691-21-8 C23H23N3S2
    6-(4-aminophenylthio)-8-methyl-3-phenethylthiomethylimidazo[1,2-a]pyridine
    —— 2-(4-Aminophenyl)sulfanyl-2-phenylethanol 1260243-59-1 C14H15NOS
    2-(4-Aminophenyl)sulfanyl-2-phenylethanol
    —— 4-((2-(2-chlorophenyl)thiazol-4-yl)methylthio)aniline 1048364-13-1 C16H13ClN2S2
    4-((2-(2-chlorophenyl)thiazol-4-yl)methylthio)aniline