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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4-Methylsulfanyl-phenylsulfanyl)-acetonitrile 79506-68-6 C9H9NS2
    (4-Methylsulfanyl-phenylsulfanyl)-acetonitrile
    —— N-Hydroxy-2-(4-methylsulfanyl-phenylsulfanyl)-acetamidine 79506-77-7 C9H12N2OS2
    N-Hydroxy-2-(4-methylsulfanyl-phenylsulfanyl)-acetamidine
    —— tert-Butyl-[4-(4-fluoro-phenylsulfanyl)-butoxy]-diphenyl-silane 300706-49-4 C26H31FOSSi
    tert-Butyl-[4-(4-fluoro-phenylsulfanyl)-butoxy]-diphenyl-silane
    —— 4-(methylsulfinyl)diphenyl sulfide 33689-38-2 C13H12OS2
    4-(methylsulfinyl)diphenyl sulfide
    —— 5-Fluoro-4-prop-2-ynylsulfanyl-1H-pyrimidin-2-one 105245-96-3 C7H5FN2OS
    5-Fluoro-4-prop-2-ynylsulfanyl-1H-pyrimidin-2-one
    —— tert-butyl (1R,3S)-1,2,2-trimethyl-3-((4-(methylthio)phenylthio)methyl)cyclopentylcarbamate 1300078-80-1 C21H33NO2S2
    tert-butyl (1R,3S)-1,2,2-trimethyl-3-((4-(methylthio)phenylthio)methyl)cyclopentylcarbamate
    —— [1,3]Dithiane-2,2-dicarboxylic acid diethyl ester 90956-47-1 C10H16O4S2
    [1,3]Dithiane-2,2-dicarboxylic acid diethyl ester
    —— [({[2-(Phenylsulfanyl)phenyl]methylidene}amino)oxy]acetic acid 352427-04-4 C15H13NO3S
    [({[2-(Phenylsulfanyl)phenyl]methylidene}amino)oxy]acetic acid
    —— 2-[2'-(phenylthio)benzyl]pyridine 359015-70-6 C18H15NS
    2-[2'-(phenylthio)benzyl]pyridine
    —— 2-(Phenylsulfanyl)benzaldehyde oxime 352427-00-0 C13H11NOS
    2-(Phenylsulfanyl)benzaldehyde oxime
    —— ethyl 2-diazo-3-oxo-3-(2-phenylthio)phenylpropanoate 131327-54-3 C17H14N2O3S
    ethyl 2-diazo-3-oxo-3-(2-phenylthio)phenylpropanoate
    —— 3-[(2-bromo-5-octylphenyl)thio]benzo[b]thiophene-2-carboxylic acid 1618666-16-2 C23H25BrO2S2
    3-[(2-bromo-5-octylphenyl)thio]benzo[b]thiophene-2-carboxylic acid
    —— 2-(4-chlorophenyl)-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile 303997-39-9 C18H12ClN3S
    2-(4-chlorophenyl)-2-[6-(phenylthio)pyridazin-3-yl]acetonitrile
    —— 4-chloro-2-(ethylthio)aniline 107254-78-4 C8H10ClNS
    4-chloro-2-(ethylthio)aniline
    —— α-phenyl-α-[(4,5,6,7-tetrahydrobenzothiazol-2-yl)thio]acetic acid 85592-39-8 C15H15NO2S2
    α-phenyl-α-[(4,5,6,7-tetrahydrobenzothiazol-2-yl)thio]acetic acid
    —— (3,4-Dimethoxy-2-thienylthio)-acetic Acid 58386-18-8 C8H10O4S2
    (3,4-Dimethoxy-2-thienylthio)-acetic Acid
    —— (2-amino-5-chloro-phenylsulfanyl)-acetic acid 418783-16-1 C8H8ClNO2S
    (2-amino-5-chloro-phenylsulfanyl)-acetic acid
    —— 4-Aza-phenothiazin-10-carbonsaeure-1-methyl-4-amino-piperidid 99002-75-2 C18H20N4OS
    4-Aza-phenothiazin-10-carbonsaeure-1-methyl-4-amino-piperidid
    —— (+/-)-4-oxo-5-phenyl-4,5-dihydro-11H-pyrrolo[2,1-d][1,5]benzothiazocine 189883-86-1 C19H15NOS
    (+/-)-4-oxo-5-phenyl-4,5-dihydro-11H-pyrrolo[2,1-d][1,5]benzothiazocine
    —— α-(2-{[(1H-pyrrol-1-yl)methyl]phenyl}thio)phenylacetic acid 189883-85-0 C19H17NO2S
    α-(2-{[(1H-pyrrol-1-yl)methyl]phenyl}thio)phenylacetic acid
    —— trans-2-(phenylthio)-4-phenylbutyrolactone 62675-52-9 C16H14O2S
    trans-2-(phenylthio)-4-phenylbutyrolactone
    —— α-[(5-Chlorothiazolo[5,4-b]pyridin-2-yl)thio]α-phenyl acetic acid 85615-12-9 C14H9ClN2O2S2
    α-[(5-Chlorothiazolo[5,4-b]pyridin-2-yl)thio]α-phenyl acetic acid
    —— 1,1-bis(phenylthio)-2-cyclohexyl-2-ethanone 111731-05-6 C20H22OS2
    1,1-bis(phenylthio)-2-cyclohexyl-2-ethanone
    —— 4-Phenyl-4-phenylsulfanyl-butyric acid 2-dimethylamino-ethyl ester 47366-25-6 C20H25NO2S
    4-Phenyl-4-phenylsulfanyl-butyric acid 2-dimethylamino-ethyl ester
    —— 2,2-Dimethyl-2,3-dihydro-pyrido[3,2-e][1,3]thiazin-4-one 118966-07-7 C9H10N2OS
    2,2-Dimethyl-2,3-dihydro-pyrido[3,2-e][1,3]thiazin-4-one
    —— 2,4-dimethoxy-6-methylsulfanyl-pyrimidine 89943-44-2 C7H10N2O2S
    2,4-dimethoxy-6-methylsulfanyl-pyrimidine
    —— 2-(7-iodo-2,3-dihydrobenzo[b][1,4]dioxin-6-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-67-3 C19H17IN4O2S
    2-(7-iodo-2,3-dihydrobenzo[b][1,4]dioxin-6-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-chloro-4-fluoro-1-methylsulfanylbenzene 917761-33-2 C7H6ClFS
    2-chloro-4-fluoro-1-methylsulfanylbenzene
    —— 6-Phenylsulfanyl-1,4,4a,8a-tetrahydro-1,4-methano-naphthalene-5,8-dione 95333-41-8 C17H14O2S
    6-Phenylsulfanyl-1,4,4a,8a-tetrahydro-1,4-methano-naphthalene-5,8-dione
    —— N,N,N',N'-Tetrakis-[2-(4-chloro-phenylsulfanyl)-ethyl]-succinamide 61455-09-2 C36H36Cl4N2O2S4
    N,N,N',N'-Tetrakis-[2-(4-chloro-phenylsulfanyl)-ethyl]-succinamide
    —— 2H,3H-benzo<1,2-b:4,3:b'>bisthiete 220398-60-7 C8H6S2
    2H,3H-benzo<1,2-b:4,3:b'>bisthiete
    —— 5-bromo-3-methyl-6-phenylthiouracil 81077-92-1 C11H9BrN2O2S
    5-bromo-3-methyl-6-phenylthiouracil
    —— (3,3-Dimethyl-2-phenylsulfanylmethyl-cyclohex-1-enyl)-methanol 81054-02-6 C16H22OS
    (3,3-Dimethyl-2-phenylsulfanylmethyl-cyclohex-1-enyl)-methanol
    —— 1,5-dithia-spiro[5.5]undecan-8-ol 68972-10-1 C9H16OS2
    1,5-dithia-spiro[5.5]undecan-8-ol
    —— cobalt(2+);tetrathiocyanate —— C4CoN4S4-2
    cobalt(2+);tetrathiocyanate
    —— 3-(5-methyl-1,3,4-thiadiazol-2-mercapto)-propionitrile 132432-21-4 C6H7N3S2
    3-(5-methyl-1,3,4-thiadiazol-2-mercapto)-propionitrile
    —— 1-(methylthio)oct-2-ene 91944-69-3 C9H18S
    1-(methylthio)oct-2-ene
    —— 6,6-dimethyl-2-phenylthiomethyl-1-cyclohexencarboxaldehyde 126087-75-0 C16H20OS
    6,6-dimethyl-2-phenylthiomethyl-1-cyclohexencarboxaldehyde
    —— 1-methoxy-1-(phenylthio)-1,3-pentadiene 93500-44-8 C12H14OS
    1-methoxy-1-(phenylthio)-1,3-pentadiene
    —— 1-Methyl-3-methylmercapto-1,2,4-triazolon (5) 53065-41-1 C4H7N3OS
    1-Methyl-3-methylmercapto-1,2,4-triazolon (5)
    —— 5-Mercaptomethyldihydro-1,2,4-triazolon-3 53065-40-0 C3H5N3OS
    5-Mercaptomethyldihydro-1,2,4-triazolon-3
    —— <i>N</i>-ethyl-4-(4-nitro-phenylsulfanyl)-aniline 5786-51-6 C14H14N2O2S
    <i>N</i>-ethyl-4-(4-nitro-phenylsulfanyl)-aniline
    —— (1R,2R)-1-(R)-1,4-Dioxa-spiro[4.5]dec-2-yl-2-methoxy-2-phenylsulfanyl-ethanol 134678-19-6 C17H24O4S
    (1R,2R)-1-(R)-1,4-Dioxa-spiro[4.5]dec-2-yl-2-methoxy-2-phenylsulfanyl-ethanol
    —— tert-Butyl-{(Z)-1-tert-butyl-3-[1-(methoxy-phenylsulfanyl-methyl)-heptyloxy]-propenyloxy}-dimethyl-silane 200347-28-0 C28H50O3SSi
    tert-Butyl-{(Z)-1-tert-butyl-3-[1-(methoxy-phenylsulfanyl-methyl)-heptyloxy]-propenyloxy}-dimethyl-silane
    —— (E)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene 93500-48-2 C12H16OS
    (E)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene
    —— (1-Methoxy-heptylsulfanyl)-benzene 89423-38-1 C14H22OS
    (1-Methoxy-heptylsulfanyl)-benzene
    —— (1-Methoxy-4-methyl-pent-3-enylsulfanyl)-benzene 116204-90-1 C13H18OS
    (1-Methoxy-4-methyl-pent-3-enylsulfanyl)-benzene
    —— 5H,7H-Dibenzo<b,g><1,5>dithiocin 6-oxide 103896-92-0 C14H12OS2
    5H,7H-Dibenzo<b,g><1,5>dithiocin 6-oxide
    —— (2R,4aR,5S,7R,8aR,9aS,10aR)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-3,3-bis-ethylsulfanyl-10a-methyl-decahydro-1,8,10-trioxa-anthracene-2-carbaldehyde 807616-67-7 C43H66O6S2Si2
    (2R,4aR,5S,7R,8aR,9aS,10aR)-5-(tert-Butyl-dimethyl-silanyloxy)-7-[2-(tert-butyl-diphenyl-silanyloxymethyl)-allyl]-3,3-bis-ethylsulfanyl-10a-methyl-decahydro-1,8,10-trioxa-anthracene-2-carbaldehyde
    —— Cyclohexyl-phenylsulfanyl-acetaldehyde 115205-38-4 C14H18OS
    Cyclohexyl-phenylsulfanyl-acetaldehyde