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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(2-Amino-ethyl)-(2-{2-[(2-amino-ethyl)-(3-hydroxy-propyl)-amino]-ethylsulfanylmethylsulfanyl}-ethyl)-amino]-propan-1-ol 677717-48-5 C15H36N4O2S2
    3-[(2-Amino-ethyl)-(2-{2-[(2-amino-ethyl)-(3-hydroxy-propyl)-amino]-ethylsulfanylmethylsulfanyl}-ethyl)-amino]-propan-1-ol
    —— 4-Chloro-2,5-bis(methylsulfanyl)pyrimidine 6944-12-3 C6H7ClN2S2
    4-Chloro-2,5-bis(methylsulfanyl)pyrimidine
    —— <i>N</i>-<i>tert</i>-butyl-<i>N</i>'-(3-dimethylamino-propyl)-thiourea 103502-79-0 C10H23N3S
    <i>N</i>-<i>tert</i>-butyl-<i>N</i>'-(3-dimethylamino-propyl)-thiourea
    —— 5-Phenyl-4-(phenylthio)-1,2,3-thiadiazole 114393-63-4 C14H10N2S2
    5-Phenyl-4-(phenylthio)-1,2,3-thiadiazole
    —— 2-Amino-6-benzylamino-4-methylmercapto-pyrimidin 91769-84-5 C12H14N4S
    2-Amino-6-benzylamino-4-methylmercapto-pyrimidin
    —— methyl 2-[6-(3-chloropropylthio)imidazo[1,2-b]pyridazin-2-yl]-2-methylpropionate 1027033-22-2 C14H18ClN3O2S
    methyl 2-[6-(3-chloropropylthio)imidazo[1,2-b]pyridazin-2-yl]-2-methylpropionate
    —— 2-ethyl-4-chloromethyl-2-methyl-[1,3]dithiolane-1,1,3,3-tetraoxide 6623-95-6 C7H13ClO4S2
    2-ethyl-4-chloromethyl-2-methyl-[1,3]dithiolane-1,1,3,3-tetraoxide
    —— isopropyl β-dichloromethylsulfonylpropionate 119451-37-5 C7H12Cl2O4S
    isopropyl β-dichloromethylsulfonylpropionate
    —— methyl 3-((4-aminopyridin-2-yl)thio)propanoate 1250012-73-7 C9H12N2O2S
    methyl 3-((4-aminopyridin-2-yl)thio)propanoate
    —— 1-Ethyl-3-hexadecyl-thiourea 94381-36-9 C19H40N2S
    1-Ethyl-3-hexadecyl-thiourea
    —— 2-(4'-nitropyridin-2'-ylsulfanyl)-ethanamine 1265869-52-0 C7H9N3O2S
    2-(4'-nitropyridin-2'-ylsulfanyl)-ethanamine
    —— 1-Allyl-3-hexadecyl-thiourea 6313-22-0 C20H40N2S
    1-Allyl-3-hexadecyl-thiourea
    —— 2-(3-methoxy-3-oxopropylthio)-4-nitropyridine N-oxide 1314876-27-1 C9H10N2O5S
    2-(3-methoxy-3-oxopropylthio)-4-nitropyridine N-oxide
    —— hexadecyl-thiourea 86533-71-3 C17H36N2S
    hexadecyl-thiourea
    —— (3-Dimethylamino-propyl)-thiocarbamic acid S-methyl ester 6944-44-1 C7H16N2OS
    (3-Dimethylamino-propyl)-thiocarbamic acid S-methyl ester
    —— 1-(2-hydroxyethyl)-3-hexadecylthiourea 1398599-74-0 C19H40N2OS
    1-(2-hydroxyethyl)-3-hexadecylthiourea
    —— 6-Amino-5-(methylsulfanyl)pyrimidin-2(1h)-one 6623-80-9 C5H7N3OS
    6-Amino-5-(methylsulfanyl)pyrimidin-2(1h)-one
    —— (cyano-3 pyridyl-2)(hydroxy-2 ethyl) sulfure 89407-35-2 C8H8N2OS
    (cyano-3 pyridyl-2)(hydroxy-2 ethyl) sulfure
    —— 5-phenylthio-3,6-dichloro-1,2,4-triazine 132434-85-6 C9H5Cl2N3S
    5-phenylthio-3,6-dichloro-1,2,4-triazine
    —— 6-Methyl-3-(prop-2-en-1-yl)-4-[(prop-2-en-1-yl)sulfanyl]-2H-pyran-2-one 923602-36-2 C12H14O2S
    6-Methyl-3-(prop-2-en-1-yl)-4-[(prop-2-en-1-yl)sulfanyl]-2H-pyran-2-one
    —— ethyl 2-(phenylthio)but-3-enoate 109542-07-6 C12H14O2S
    ethyl 2-(phenylthio)but-3-enoate
    —— dimethyl phenylthio(trimethylsilylmethyl)malonate 83182-22-3 C15H22O4SSi
    dimethyl phenylthio(trimethylsilylmethyl)malonate
    —— 5-(4-Chlor-anilino)-4,6-dihydroxy-2-methylmercapto-pyrimidin 6630-69-9 C11H10ClN3O2S
    5-(4-Chlor-anilino)-4,6-dihydroxy-2-methylmercapto-pyrimidin
    —— N-hydroxy-2-(phenylthio)acetamide 4707-65-7 C8H9NO2S
    N-hydroxy-2-(phenylthio)acetamide
    —— 3-methyl-5-phenylsulfanylmethyl-[1,2,4]oxadiazole 865706-92-9 C10H10N2OS
    3-methyl-5-phenylsulfanylmethyl-[1,2,4]oxadiazole
    —— ethyl 2-[(3-ethynyl-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate 1011458-42-6 C21H20O4S
    ethyl 2-[(3-ethynyl-2-methoxycarbonylmethyl)phenyl]-2-(phenylthio)acetate
    —— 3-methyl-4-phenylthio-2-pyrazolin-5-one 127788-15-2 C10H10N2OS
    3-methyl-4-phenylthio-2-pyrazolin-5-one
    —— 5-ethyl-2-(4-fluorophenyl)-4-phenylsulfanyl-4H-pyrazol-3-one 1308248-25-0 C17H15FN2OS
    5-ethyl-2-(4-fluorophenyl)-4-phenylsulfanyl-4H-pyrazol-3-one
    —— O-ethyl (phenylthio)thioacetate 162999-94-2 C10H12OS2
    O-ethyl (phenylthio)thioacetate
    —— dimethyl-(5-phenylsulfanylmethyl-[1,2,4]oxadiazol-3-yl)-amine 865707-08-0 C11H13N3OS
    dimethyl-(5-phenylsulfanylmethyl-[1,2,4]oxadiazol-3-yl)-amine
    —— 1-(4-fluorophenyl)-3-methyl-4-(phenylthio)-1H-pyrazol-5(4H)-one 1308248-21-6 C16H13FN2OS
    1-(4-fluorophenyl)-3-methyl-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— ethyl 3-(3-azido-2-thienyl)-2-(phenylthio)propenoate 106183-75-9 C15H13N3O2S2
    ethyl 3-(3-azido-2-thienyl)-2-(phenylthio)propenoate
    —— 1,3-dimethyl-4-(phenylthio)-1H-pyrazol-5(4H)-one 82051-46-5 C11H12N2OS
    1,3-dimethyl-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— 3-isopropyl-4-(phenylthio)-1H-pyrazol-5(4H)-one 1188445-13-7 C12H14N2OS
    3-isopropyl-4-(phenylthio)-1H-pyrazol-5(4H)-one
    —— (4-Hydroxy-phenylsulfanyl)-acetic acid 2-morpholin-4-yl-2-oxo-ethyl ester 851478-84-7 C14H17NO5S
    (4-Hydroxy-phenylsulfanyl)-acetic acid 2-morpholin-4-yl-2-oxo-ethyl ester
    —— O2-(2-methylthioethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate 1404220-31-0 C6H15N3O2S
    O2-(2-methylthioethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate
    —— 5-((5-Bromo-2-(methylthio)-4-pyrimidinyl)amino)-2,4-pyrimidinediol 6951-53-7 C9H8BrN5O2S
    5-((5-Bromo-2-(methylthio)-4-pyrimidinyl)amino)-2,4-pyrimidinediol
    —— Ethyl α-fluoro-α-(p-tolylthio)acetate 130612-81-6 C11H13FO2S
    Ethyl α-fluoro-α-(p-tolylthio)acetate
    —— ethyl 2-ethoxalyl-p-tolylthioacetate 87378-99-2 C15H18O5S
    ethyl 2-ethoxalyl-p-tolylthioacetate
    —— 1-[[4-amino-3-[2-(4-hydroxyphenyl)ethyl]-4H-1,2,4-triazol-5-yl]thioacetyl]-3-(2-thienyl)-5-(4-dimethylaminophenyl)-2-pyrazoline 1246567-70-3 C27H29N7O2S2
    1-[[4-amino-3-[2-(4-hydroxyphenyl)ethyl]-4H-1,2,4-triazol-5-yl]thioacetyl]-3-(2-thienyl)-5-(4-dimethylaminophenyl)-2-pyrazoline
    —— 5-{[5-Bromo-6-methyl-2-(methylsulfanyl)pyrimidin-4-yl]amino}pyrimidine-2,4(1h,3h)-dione 6951-54-8 C10H10BrN5O2S
    5-{[5-Bromo-6-methyl-2-(methylsulfanyl)pyrimidin-4-yl]amino}pyrimidine-2,4(1h,3h)-dione
    —— <N,N-Bis-(2-hydroxy-ethyl)-4-amino-phenylmercapto>-essigsaeure-methylester 92198-63-5 C13H19NO4S
    <N,N-Bis-(2-hydroxy-ethyl)-4-amino-phenylmercapto>-essigsaeure-methylester
    —— methyl 3,5-diamino-6-phenylthiopyrazinoate 70296-94-5 C12H12N4O2S
    methyl 3,5-diamino-6-phenylthiopyrazinoate
    —— 2-(3-butynyl)-2-<2-(phenylthio)ethyl>-1,3-dioxolane 91798-93-5 C15H18O2S
    2-(3-butynyl)-2-<2-(phenylthio)ethyl>-1,3-dioxolane
    —— 2-(Methylsulfonyl)-1-cyclopentanon 89729-97-5 C6H10O3S
    2-(Methylsulfonyl)-1-cyclopentanon
    —— N1-benzyl-1,2-dihydro-4-[[4-methylthiophenyl]methyl]-5-trifluoromethyl-3H-pyrazol-3-one 501033-13-2 C19H17F3N2OS
    N1-benzyl-1,2-dihydro-4-[[4-methylthiophenyl]methyl]-5-trifluoromethyl-3H-pyrazol-3-one
    —— (E)-2-(4-(methylthio)benzylidene)-N-phenylhydrazinecarbothioamide 1319729-48-0 C15H15N3S2
    (E)-2-(4-(methylthio)benzylidene)-N-phenylhydrazinecarbothioamide
    —— 5-((5-Bromo-6-chloro-2-(methylthio)pyrimidin-4-yl)amino)pyrimidine-2,4(1H,3H)-dione 7356-33-4 C9H7BrClN5O2S
    5-((5-Bromo-6-chloro-2-(methylthio)pyrimidin-4-yl)amino)pyrimidine-2,4(1H,3H)-dione
    —— 7-(4-Chloro-phenyl)-3-phenyl-5-[(E)-phenylimino]-3,7-dihydro-[1,3]dithiino[4,5-d]thiazole-2-thione 908589-69-5 C23H15ClN2S4
    7-(4-Chloro-phenyl)-3-phenyl-5-[(E)-phenylimino]-3,7-dihydro-[1,3]dithiino[4,5-d]thiazole-2-thione
    —— (4R,6R)-4-Methyl-6-phenylsulfanylmethyl-tetrahydro-pyran-2-ol 216865-94-0 C13H18O2S
    (4R,6R)-4-Methyl-6-phenylsulfanylmethyl-tetrahydro-pyran-2-ol