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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Ethylamine, 2,2'-dithiobis-, calcium salt 101418-33-1 C4H12CaN2S2+2
    Ethylamine, 2,2'-dithiobis-, calcium salt
    —— 1-Chloroallyl isothiocyanate 101670-64-8 C4H4ClNS
    1-Chloroallyl isothiocyanate
    —— 2-Methyl-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline 100280-15-7 C9H9F4NS
    2-Methyl-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline
    —— Propyl 2-(ethoxycarbonylamino)ethylsulfanylformate 101491-87-6 C9H17NO4S
    Propyl 2-(ethoxycarbonylamino)ethylsulfanylformate
    —— N,N-Diethyl-N-methyl-2-(((1-(phenylthio)cyclobutyl)carbonyl)oxy)ethanaminium iodide 101361-01-7 C18H28INO2S
    N,N-Diethyl-N-methyl-2-(((1-(phenylthio)cyclobutyl)carbonyl)oxy)ethanaminium iodide
    —— 3-Chloro-1,2-butanedithiol 101258-18-8 C4H9ClS2
    3-Chloro-1,2-butanedithiol
    —— 3-((2,3,5,6-Tetramethylphenyl)thio)butyric acid ethyl ester 100700-36-5 C16H24O2S
    3-((2,3,5,6-Tetramethylphenyl)thio)butyric acid ethyl ester
    —— 13,13-dimethyl-1,8-dioxa-4,11-dithia-dispiro[4.1.4.3]tetradecane 101198-14-5 C12H20O2S2
    13,13-dimethyl-1,8-dioxa-4,11-dithia-dispiro[4.1.4.3]tetradecane
    —— Ammonium, sulfonylbis(hexamethylene)bis(triethyl-, diiodide 101295-91-4 C24H54I2N2O2S
    Ammonium, sulfonylbis(hexamethylene)bis(triethyl-, diiodide
    —— 2-Chloro-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline 100280-14-6 C8H6ClF4NS
    2-Chloro-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline
    —— Ethyl 4-[(dimethylamino)methyl]-5-hydroxy-2-[(4-methylphenyl)sulfanyl]-1-benzofuran-3-carboxylate--hydrogen chloride (1/1) 100347-60-2 C21H24ClNO4S
    Ethyl 4-[(dimethylamino)methyl]-5-hydroxy-2-[(4-methylphenyl)sulfanyl]-1-benzofuran-3-carboxylate--hydrogen chloride (1/1)
    —— N,N'-[Pyrimidine-2,4-diylbis(sulfanediylethane-2,1-diyl)]bis(N-ethylethan-1-amine)--hydrogen chloride (1/2) 94565-18-1 C16H32Cl2N4S2
    N,N'-[Pyrimidine-2,4-diylbis(sulfanediylethane-2,1-diyl)]bis(N-ethylethan-1-amine)--hydrogen chloride (1/2)
    —— (Thiobis(p-phenylenethio))diacetic acid 2,2',2''-nitrilotriethanol salt (1:2) 87299-01-2 C28H44N2O10S3
    (Thiobis(p-phenylenethio))diacetic acid 2,2',2''-nitrilotriethanol salt (1:2)
    —— (m-Phenylenedithio)diacetic acid 2,2',2''-nitrilotriethanol salt (1:2) 87299-02-3 C22H40N2O10S2
    (m-Phenylenedithio)diacetic acid 2,2',2''-nitrilotriethanol salt (1:2)
    —— N-[4-({2-[Di(propan-2-yl)amino]ethyl}sulfanyl)phenyl]-N'-phenylbenzenecarboximidamide--hydrogen bromide (1/2) 80784-95-8 C27H35Br2N3S
    N-[4-({2-[Di(propan-2-yl)amino]ethyl}sulfanyl)phenyl]-N'-phenylbenzenecarboximidamide--hydrogen bromide (1/2)
    —— 2-[bis(2-hydroxyethyl)amino]ethanol;2-(4-bromophenyl)sulfanylacetic acid 87298-90-6 C6H15NO3*C8H7BrO2S
    2-[bis(2-hydroxyethyl)amino]ethanol;2-(4-bromophenyl)sulfanylacetic acid
    —— 11-ethyl-12-phenyl-3-prop-2-enoxy-6H-benzo[c][1]benzothiocine 85850-84-6 C26H24OS
    11-ethyl-12-phenyl-3-prop-2-enoxy-6H-benzo[c][1]benzothiocine
    —— 2-[(11-ethyl-12-phenyl-6H-benzo[c][1]benzothiocin-3-yl)oxy]-N,N-dimethylethanamine 85850-79-9 C27H29NOS
    2-[(11-ethyl-12-phenyl-6H-benzo[c][1]benzothiocin-3-yl)oxy]-N,N-dimethylethanamine
    —— 2-Chloro-5-methylsulfanylpyrimidine-4,6-diamine;6-chloro-5-methylsulfanylpyrimidine-2,4-diamine 83623-05-6 C10H14Cl2N8S2
    2-Chloro-5-methylsulfanylpyrimidine-4,6-diamine;6-chloro-5-methylsulfanylpyrimidine-2,4-diamine
    —— 2-(Diethylamino)ethyl 1-phenylsulfanylcyclopropane-1-carboxylate;hydrochloride 84245-04-5 C16H24ClNO2S
    2-(Diethylamino)ethyl 1-phenylsulfanylcyclopropane-1-carboxylate;hydrochloride
    —— Ethanimidothioate;methylmercury(1+) —— C3H7HgNS
    Ethanimidothioate;methylmercury(1+)
    —— Thiraldin 37262-63-8 C18H20Cl6N2O2S2
    Thiraldin
    —— 2,2-Dimethyl-4-((pentachlorophenylthio)methyl)-1,3-dioxolane 73987-11-8 C12H11Cl5O2S
    2,2-Dimethyl-4-((pentachlorophenylthio)methyl)-1,3-dioxolane
    —— 2-Chloro-5-(methylthio)-4,6-pyrimidinediamine 70958-50-8 C5H7ClN4S
    2-Chloro-5-(methylthio)-4,6-pyrimidinediamine
    —— 1-Phenylmercapto-2-hydrazino-propan 69781-99-3 C9H14N2S
    1-Phenylmercapto-2-hydrazino-propan
    —— 2,6-Diaminohexane-1-thiol--hydrogen chloride (1/2) 70548-53-7 C6H18Cl2N2S
    2,6-Diaminohexane-1-thiol--hydrogen chloride (1/2)
    —— 2-[(2-Methylpentan-2-yl)disulfanyl]ethan-1-amine--hydrogen chloride (1/1) 69311-57-5 C8H20ClNS2
    2-[(2-Methylpentan-2-yl)disulfanyl]ethan-1-amine--hydrogen chloride (1/1)
    —— 2-phenylsulfanylethylhydrazine;sulfuric acid —— C16H26N4O4S3
    2-phenylsulfanylethylhydrazine;sulfuric acid
    —— (3-Mercaptophenyl)trimethylammonium iodide dimethylcarbamate (ester) 66968-02-3 C12H19IN2OS
    (3-Mercaptophenyl)trimethylammonium iodide dimethylcarbamate (ester)
    —— 2-Fluoroethyl xanthate 64057-80-3 C5H9FOS2
    2-Fluoroethyl xanthate
    —— Carbamic acid, dimethyldithio-, p-(trimethylammonio)phenyl ester, iodide 63977-50-4 C12H19IN2S2
    Carbamic acid, dimethyldithio-, p-(trimethylammonio)phenyl ester, iodide
    —— N,N-diethyl-2-[(4-methylphenyl)thio]ethanamine hydrochloride 63918-10-5 C13H22ClNS
    N,N-diethyl-2-[(4-methylphenyl)thio]ethanamine hydrochloride
    —— 3,6,9,12,15,18,21,24,27-Nonathianonacosane-1-thiol, 29-(2,2-dimethylhydrazino)- 63917-39-5 C22H48N2S10
    3,6,9,12,15,18,21,24,27-Nonathianonacosane-1-thiol, 29-(2,2-dimethylhydrazino)-
    —— 2-Propanone, 1,1,1-trifluoro-3-(2-pyridinylthio)- 127183-36-2 C8H6F3NOS
    2-Propanone, 1,1,1-trifluoro-3-(2-pyridinylthio)-
    —— 2-Chloro-N-{2-[(2-methylphenyl)sulfanyl]ethyl}ethan-1-amine--hydrogen chloride (1/1) 63918-03-6 C11H17Cl2NS
    2-Chloro-N-{2-[(2-methylphenyl)sulfanyl]ethyl}ethan-1-amine--hydrogen chloride (1/1)
    —— 2-[(5-Imino-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]ethan-1-amine--hydrogen chloride (1/1) 63503-53-7 C4H9ClN4S2
    2-[(5-Imino-4,5-dihydro-1,3,4-thiadiazol-2-yl)sulfanyl]ethan-1-amine--hydrogen chloride (1/1)
    —— 2-Propanone, 1,1,1-trifluoro-3-(4-pyridinylthio)- 127183-37-3 C8H6F3NOS
    2-Propanone, 1,1,1-trifluoro-3-(4-pyridinylthio)-
    —— 2-Propanone, 1,1,1-trifluoro-3-((1-methyl-1H-imidazol-2-yl)thio)- 127183-51-1 C7H7F3N2OS
    2-Propanone, 1,1,1-trifluoro-3-((1-methyl-1H-imidazol-2-yl)thio)-
    —— (4-Chloromethanesulfonyl-2-nitro-phenyl)-[4-(4-nitro-phenylsulfanyl)-phenyl]-amine 56947-96-7 C19H14ClN3O6S2
    (4-Chloromethanesulfonyl-2-nitro-phenyl)-[4-(4-nitro-phenylsulfanyl)-phenyl]-amine
    —— 1,1,1-Trifluoro-3-(4-methylpyrimidin-2-yl)sulfanylpropan-2-one 127183-45-3 C8H7F3N2OS
    1,1,1-Trifluoro-3-(4-methylpyrimidin-2-yl)sulfanylpropan-2-one
    —— trans-(2-((tert-butoxycarbonyl)amino)cyclobutyl)methyl methanesulfonate 55217-61-3 C5H11NS*ClH
    trans-(2-((tert-butoxycarbonyl)amino)cyclobutyl)methyl methanesulfonate
    —— 2,6,7-Trioxabicyclo(2.2.2)octane, 4-(1,1-dimethylethyl)-1-(4-methylthiophenyl)- 130523-86-3 C16H22O3S
    2,6,7-Trioxabicyclo(2.2.2)octane, 4-(1,1-dimethylethyl)-1-(4-methylthiophenyl)-
    —— [2-(Ethyl-isobutylsulfanylcarbonyl-amino)-ethyl]-thiocarbamic acid S-isobutyl ester 51122-73-7 C14H28N2O2S2
    [2-(Ethyl-isobutylsulfanylcarbonyl-amino)-ethyl]-thiocarbamic acid S-isobutyl ester
    —— 1,2-bis(hexadecylthio)ethane 5543-81-7 C34H70S2
    1,2-bis(hexadecylthio)ethane
    —— Acetamide, N-(5-(9H-purin-6-ylthio)-1,3,4-thiadiazol-2-YL)- 53051-75-5 C9H7N7OS2
    Acetamide, N-(5-(9H-purin-6-ylthio)-1,3,4-thiadiazol-2-YL)-
    —— S-ethyl dipropylthiocarbamate S,S-dioxide 51892-58-1 C9H19NO3S
    S-ethyl dipropylthiocarbamate S,S-dioxide
    —— (cis)-2-Mercaptocyclobutylmethylamine hydrochloride 41696-77-9 C5H12ClNS
    (cis)-2-Mercaptocyclobutylmethylamine hydrochloride
    —— O-t-Butyl-S-(1-methylthioethyl)thiocarbonat 36852-51-4 C8H16O2S2
    O-t-Butyl-S-(1-methylthioethyl)thiocarbonat
    —— 2,2'-Disulfanediylbis[N-(cycloheptylmethyl)ethanimidamide]--hydrogen chloride (1/2) 40493-24-1 C20H40Cl2N4S2
    2,2'-Disulfanediylbis[N-(cycloheptylmethyl)ethanimidamide]--hydrogen chloride (1/2)
    —— 2,2'-Disulfanediylbis[N-(3-cyclohexylpropyl)ethanimidamide]--hydrogen chloride (1/2) 40284-18-2 C22H44Cl2N4S2
    2,2'-Disulfanediylbis[N-(3-cyclohexylpropyl)ethanimidamide]--hydrogen chloride (1/2)