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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-Furan-2-yl-6-methylsulfanyl-2-thiophen-2-yl-pyrimidine 87568-79-4 C13H10N2OS2
    4-Furan-2-yl-6-methylsulfanyl-2-thiophen-2-yl-pyrimidine
    —— 5,6-dihydro-1H-thieno[3,2-c]pyrazole 1447827-71-5 C5H6N2S
    5,6-dihydro-1H-thieno[3,2-c]pyrazole
    —— 2-(6-Bromobenzo[d][1,3]dioxol-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-56-0 C18H15BrN4O2S
    2-(6-Bromobenzo[d][1,3]dioxol-5-ylthio)-1-(pent-4-ynyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-(methylthio)-3-(benzyloxymethyl)pyrimidin-4-one 146202-39-3 C13H14N2O2S
    2-(methylthio)-3-(benzyloxymethyl)pyrimidin-4-one
    —— 1,2-bis-(2-methylthio-4-oxopyrimidin-3-yl)ethane 89185-12-6 C12H14N4O2S2
    1,2-bis-(2-methylthio-4-oxopyrimidin-3-yl)ethane
    —— tert-butyl 2-aminooxy-2-(phenylthio)acetate 135996-03-1 C12H17NO3S
    tert-butyl 2-aminooxy-2-(phenylthio)acetate
    —— 6-(p-tolylthio)pyrimidine-2,4(1H,3H)-dione 80947-49-5 C11H10N2O2S
    6-(p-tolylthio)pyrimidine-2,4(1H,3H)-dione
    —— 1-Ethylmercapto-2-cyclohexyliden-ethan-1-ol 103649-10-1 C10H18OS
    1-Ethylmercapto-2-cyclohexyliden-ethan-1-ol
    —— 3,3-bis-methylsulfanyl-propan-1-ol 36678-00-9 C5H12OS2
    3,3-bis-methylsulfanyl-propan-1-ol
    —— 4-(2-hydroxy-ethoxy)-2-methylthiopyrimidine 112010-47-6 C7H10N2O2S
    4-(2-hydroxy-ethoxy)-2-methylthiopyrimidine
    —— 1-((p-Chlorophenyl)thio)-3-(isopropyl(2-morpholinoethyl)amino)-2-propanol dihydrochloride 22820-25-3 C18H31Cl3N2O2S
    1-((p-Chlorophenyl)thio)-3-(isopropyl(2-morpholinoethyl)amino)-2-propanol dihydrochloride
    —— 1,1-Bis-methylsulfanyl-2-vinyl-cyclopropane 58681-15-5 C7H12S2
    1,1-Bis-methylsulfanyl-2-vinyl-cyclopropane
    —— N,N-diethyl-O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine 153714-89-7 C24H32FNO3S
    N,N-diethyl-O-{4-[5-fluoro-3-(4-methoxytetrahydropyran-4-yl)phenylthio]-α-methylbenzyl}hydroxylamine
    —— 6-(4-Chloro-phenylsulfanyl)-1H-pyrimidine-2,4-dione 80947-48-4 C10H7ClN2O2S
    6-(4-Chloro-phenylsulfanyl)-1H-pyrimidine-2,4-dione
    —— 6-<(3,5-dimethylphenyl)thio>uracil 155854-42-5 C12H12N2O2S
    6-<(3,5-dimethylphenyl)thio>uracil
    —— 6-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)pyrimidine-2,4(1H,3H)-dione 1275607-99-2 C14H15N5O3S
    6-(4-ethoxy-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)pyrimidine-2,4(1H,3H)-dione
    —— acryloyl-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine 827336-96-9 C10H10N2OS
    acryloyl-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine
    —— methyl mercaptoethyl sulfone 24517-45-1 C3H8O2S2
    methyl mercaptoethyl sulfone
    —— (4-Methoxycarbonylmethylsulfanyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester 112498-37-0 C10H12N2O4S2
    (4-Methoxycarbonylmethylsulfanyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester
    —— 4-[2-(4-Chloro-phenylsulfanyl)-phenyl]-6-methyl-2-phenyl-1,4-dihydro-pyrimidine-5-carboxylic acid ethyl ester 143996-71-8 C26H23ClN2O2S
    4-[2-(4-Chloro-phenylsulfanyl)-phenyl]-6-methyl-2-phenyl-1,4-dihydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 5-bromo-2chloro-4-(phenylthio)pyrimidine 358978-10-6 C10H6BrClN2S
    5-bromo-2chloro-4-(phenylthio)pyrimidine
    —— 2,4-bis(benzylthio)-5-bromopyridine 125154-09-8 C18H15BrN2S2
    2,4-bis(benzylthio)-5-bromopyridine
    —— methyl 2-methoxy-N-methyl-2,3-butadienimidothioate 188180-25-8 C7H11NOS
    methyl 2-methoxy-N-methyl-2,3-butadienimidothioate
    —— (Z)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile 76399-20-7 C12H17NS
    (Z)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile
    —— (E)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile 76399-21-8 C12H17NS
    (E)-3-ethylthio-5,5-dimethyl-2-cyclohexenylidene acetonitrile
    —— N-(5-bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyridin-2-yl-benzene-1,4-diamine 1034358-79-6 C16H14BrN5S
    N-(5-bromo-4-methylsulphanylpyrimidin-2-yl)-N'-pyridin-2-yl-benzene-1,4-diamine
    —— 4,5-bis(4-(prop-2-ynyloxy)phenylthio)phthalonitrile 1323159-12-1 C26H16N2O2S2
    4,5-bis(4-(prop-2-ynyloxy)phenylthio)phthalonitrile
    —— 4,5-bis(4-(pent-4-ynyloxy)phenylthio)phthalonitrile 1323159-14-3 C30H24N2O2S2
    4,5-bis(4-(pent-4-ynyloxy)phenylthio)phthalonitrile
    —— 4,5-bis(4-(but-3-ynyloxy)phenylthio)phthalonitrile 1323159-13-2 C28H20N2O2S2
    4,5-bis(4-(but-3-ynyloxy)phenylthio)phthalonitrile
    —— N,N-dimethyl-2-(phenylthio)benzamide 31913-95-8 C15H15NOS
    N,N-dimethyl-2-(phenylthio)benzamide
    —— 7-(phenylthio)-1,4-dioxaspiro<4.4>non-6-ene 96227-47-3 C13H14O2S
    7-(phenylthio)-1,4-dioxaspiro<4.4>non-6-ene
    —— 2-chloromethyl-3-methyl-4-(1-methyl-piperidin-3-ylmethylsulfanyl)-pyridine-hydrochloride 251345-05-8 C14H21ClN2S*ClH
    2-chloromethyl-3-methyl-4-(1-methyl-piperidin-3-ylmethylsulfanyl)-pyridine-hydrochloride
    —— 7-(phenylthio)-1,4-dioxaspiro<4.5>decane 96227-52-0 C14H18O2S
    7-(phenylthio)-1,4-dioxaspiro<4.5>decane
    —— 7-(phenylthio)1,4-dioxaspiro[4.4]nonane 96227-51-9 C13H16O2S
    7-(phenylthio)1,4-dioxaspiro[4.4]nonane
    —— 2-ethyl-2-(14,16-dioxaheptadec-5-ynyl)-1,3-dithiane 928030-70-0 C21H38O2S2
    2-ethyl-2-(14,16-dioxaheptadec-5-ynyl)-1,3-dithiane
    —— 7-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane 200860-53-3 C16H22O2S
    7-(3-Phenylsulfanyl-propyl)-1,4-dioxa-spiro[4.4]nonane
    —— 4-{5-fluoro-3-[4-(1-hydroxyethyl)phenylthio]-phenyl}-4-methoxytetrahydropyran 153714-86-4 C20H23FO3S
    4-{5-fluoro-3-[4-(1-hydroxyethyl)phenylthio]-phenyl}-4-methoxytetrahydropyran
    —— 2-chloromethyl-3-methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)-ethoxy]-ethylsulfanyl}-pyridine 198200-28-1 C13H17ClF3NO2S
    2-chloromethyl-3-methyl-4-{2-[2-(2,2,2-trifluoro-ethoxy)-ethoxy]-ethylsulfanyl}-pyridine
    —— 4-{2-[2-(2-chloro-ethoxy)-ethoxy]-ethylsulfanyl}-2-chloromethyl-3-methyl-pyridine-hydrochloride 251560-54-0 C13H19Cl2NO2S*ClH
    4-{2-[2-(2-chloro-ethoxy)-ethoxy]-ethylsulfanyl}-2-chloromethyl-3-methyl-pyridine-hydrochloride
    —— (E)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene 155335-83-4 C15H18OS
    (E)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene
    —— 2-[2-cyclohepta-2,4,6-trienyl-1-(4'-(tert-butylthio)phenyl)ethylidene]malononitrile 1430198-65-4 C22H22N2S
    2-[2-cyclohepta-2,4,6-trienyl-1-(4'-(tert-butylthio)phenyl)ethylidene]malononitrile
    —— N-benzyl-2-(phenylthio)-(E)-2-heptenamide 1294896-76-6 C20H23NOS
    N-benzyl-2-(phenylthio)-(E)-2-heptenamide
    —— (Z)-N-benzyl-4,4-di(ethoxycarbonyl)-2-(phenylthio)-2-butenamide 1294896-67-5 C23H25NO5S
    (Z)-N-benzyl-4,4-di(ethoxycarbonyl)-2-(phenylthio)-2-butenamide
    —— N-benzyl-2-(1,3-dioxolan-2-yl)-2-(phenylthio)acetamide 1294897-60-1 C18H19NO3S
    N-benzyl-2-(1,3-dioxolan-2-yl)-2-(phenylthio)acetamide
    —— (Z)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene 155335-81-2 C15H18OS
    (Z)-1-(Phenylthio)-4-(2-oxocyclopentyl)-1-butene
    —— (-)-(2S,3R)-(4E)-2,3-epoxy-6-methyl-4-(phenylsulfonyl)-4-heptene 304881-48-9 C14H18OS
    (-)-(2S,3R)-(4E)-2,3-epoxy-6-methyl-4-(phenylsulfonyl)-4-heptene
    —— (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)-diisopropylsilane 1147999-67-4 C16H23F3SSi
    (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)-diisopropylsilane
    —— (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)trimethylsilane 940881-11-8 C13H17F3SSi
    (E)-(3,3,3-trifluoro-1-(p-tolylthio)prop-1-enyl)trimethylsilane
    —— bis-3-(cyclohex-1-enyl)-2-propynyl sulfide 269717-78-4 C18H22S
    bis-3-(cyclohex-1-enyl)-2-propynyl sulfide
    —— bis(γ-cyclohexenylpropargyl)sulfone 269717-80-8 C18H22O2S
    bis(γ-cyclohexenylpropargyl)sulfone