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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Acetic acid 2-furan-3-yl-2-phenylsulfanyl-ethyl ester 117770-29-3 C14H14O3S
    Acetic acid 2-furan-3-yl-2-phenylsulfanyl-ethyl ester
    —— N-(2-fluoro-4-phenylsulphanylphenyl)-2-hydroxy-2-methylpropanamide 252016-95-8 C16H16FNO2S
    N-(2-fluoro-4-phenylsulphanylphenyl)-2-hydroxy-2-methylpropanamide
    —— o-decylthioaniline 141945-26-8 C16H27NS
    o-decylthioaniline
    —— 1-methoxy-2-phenyl-1-(phenylthio)-2-propanol 78614-66-1 C16H18O2S
    1-methoxy-2-phenyl-1-(phenylthio)-2-propanol
    —— 2-(4-bromo-phenylsulfanyl)benzoic acid benzyl ester 1005513-47-2 C20H15BrO2S
    2-(4-bromo-phenylsulfanyl)benzoic acid benzyl ester
    —— α-Methoxy-aethyl-phenyl-sulfid 10429-09-1 C9H12OS
    α-Methoxy-aethyl-phenyl-sulfid
    —— 3-mercapto-5,5-dimethyl-2-cyclohexenethione 73705-06-3 C8H12S2
    3-mercapto-5,5-dimethyl-2-cyclohexenethione
    —— 1-Methoxy-4-methyl-1-phenylsulfanylpentan-2-ol 200347-22-4 C13H20O2S
    1-Methoxy-4-methyl-1-phenylsulfanylpentan-2-ol
    —— 2-methyl-2-<3'(1,3-dithiolanyl)octyl>thiazolidine 156000-20-3 C14H27NS3
    2-methyl-2-<3'(1,3-dithiolanyl)octyl>thiazolidine
    —— diethyl 2,5-bis(o-hexylthioanilino)-3,6-dihydroterephthalate 141945-27-9 C36H50N2O4S2
    diethyl 2,5-bis(o-hexylthioanilino)-3,6-dihydroterephthalate
    —— diethyl 2,5-bis(o-decylthioanilino)-3,6-dihydroterephthalate 141945-29-1 C44H66N2O4S2
    diethyl 2,5-bis(o-decylthioanilino)-3,6-dihydroterephthalate
    —— 3-({2-[(1-benzofuran-2-ylsulfonyl)amino]-4-chlorophenyl}sulfanyl)benzoic acid 1451261-80-5 C21H14ClNO5S2
    3-({2-[(1-benzofuran-2-ylsulfonyl)amino]-4-chlorophenyl}sulfanyl)benzoic acid
    —— 1-(2-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-38-6 C22H24Cl2N4O2S
    1-(2-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— 2-pentyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine 156000-19-0 C14H27NS3
    2-pentyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine
    —— N-[2-[(2,4-difluorophenyl)thio]-4-oxo-6-phenylthieno[2,3-d]pyrimidin-3(4H)-yl]methanesulfonamide 1415720-12-5 C19H13F2N3O3S3
    N-[2-[(2,4-difluorophenyl)thio]-4-oxo-6-phenylthieno[2,3-d]pyrimidin-3(4H)-yl]methanesulfonamide
    —— N-[2-[(2,4-difluorophenyl)thio]-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]methanesulfonamide 1018471-33-4 C13H9F2N3O3S3
    N-[2-[(2,4-difluorophenyl)thio]-4-oxothieno[3,2-d]pyrimidin-3(4H)-yl]methanesulfonamide
    —— 2-(2-Carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(o-nitrobenzyl)-1H-imidazole 178980-65-9 C22H22Cl2N4O4S
    2-(2-Carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(o-nitrobenzyl)-1H-imidazole
    —— methyl 3-((4-chloro-2-nitrophenyl)thio)benzoate 1451261-92-9 C14H10ClNO4S
    methyl 3-((4-chloro-2-nitrophenyl)thio)benzoate
    —— 1-(3-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-36-4 C22H24Cl2N4O2S
    1-(3-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— (1SR,2RS)-2-methyl-1-(phenylthiomethyl)cyclooctanol 125335-00-4 C16H24OS
    (1SR,2RS)-2-methyl-1-(phenylthiomethyl)cyclooctanol
    —— 5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-m-nitrobenzyl-1H-imidazole 178980-68-2 C21H21Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-m-nitrobenzyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-o-nitrobenzyl-1H-imidazole 178980-67-1 C21H21Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-2-(2-hydroxyethyl)-4-isopropyl-1-o-nitrobenzyl-1H-imidazole
    —— 8-methyl-1-(phenylthiomethyl)cyclooctene 125335-12-8 C16H22S
    8-methyl-1-(phenylthiomethyl)cyclooctene
    —— 2-(3-(1-carboxy-1-methyl(ethylsulfanyl))-phenylsulfanyl)-2-methylpropanoic acid 694520-72-4 C14H18O4S2
    2-(3-(1-carboxy-1-methyl(ethylsulfanyl))-phenylsulfanyl)-2-methylpropanoic acid
    —— 4,4'Thiobis-(2-methyl-6-tert.-butylanisol) 54519-54-9 C24H34O2S
    4,4'Thiobis-(2-methyl-6-tert.-butylanisol)
    —— (S)-3-((S)-1-Methyl-2-oxo-cyclohexyl)-2-phenylsulfanyl-propionic acid methyl ester 118664-20-3 C17H22O3S
    (S)-3-((S)-1-Methyl-2-oxo-cyclohexyl)-2-phenylsulfanyl-propionic acid methyl ester
    —— bis-(4-hydroxy-3-methyl-5-t-butylphenyl) sulphide radical 40190-57-6 C22H29O2S
    bis-(4-hydroxy-3-methyl-5-t-butylphenyl) sulphide radical
    —— sec-butyl tert-butyl sulfoxide 13153-07-6 C8H18OS
    sec-butyl tert-butyl sulfoxide
    —— 2,3-dimethylphenyl ethyl xanthate 89816-80-8 C11H14OS2
    2,3-dimethylphenyl ethyl xanthate
    —— 4,8-Di-tert-butyl-2,10-dimethyl-6-phenyl-5,7-dioxa-12-thia-6-phospha-dibenzo[a,d]cyclooctene 95497-31-7 C28H33O2PS
    4,8-Di-tert-butyl-2,10-dimethyl-6-phenyl-5,7-dioxa-12-thia-6-phospha-dibenzo[a,d]cyclooctene
    —— (Z)-4-Mercapto-3-penten-2-one 73059-87-7 C5H8OS
    (Z)-4-Mercapto-3-penten-2-one
    —— 6-acetyl-2-(4-chlorophenyl)-4-(4-chlorophenylthio)-5-methyl-3(2H)-pyridazinone 259192-42-2 C19H14Cl2N2O2S
    6-acetyl-2-(4-chlorophenyl)-4-(4-chlorophenylthio)-5-methyl-3(2H)-pyridazinone
    —— 3-(phenylthio)-2-butenoic acid 67959-53-9 C10H10O2S
    3-(phenylthio)-2-butenoic acid
    —— 6-nitroso-2,3-dihydro-4H-5-aminothiazole<2,3-a>pyrimidin-7-one 224433-77-6 C6H6N4O2S
    6-nitroso-2,3-dihydro-4H-5-aminothiazole<2,3-a>pyrimidin-7-one
    —— 2-n-butylthio-1-hydroxymethyl-cyclohept-1-ene 119044-23-4 C12H22OS
    2-n-butylthio-1-hydroxymethyl-cyclohept-1-ene
    —— (Z)-8-bromo-3-(phenylthio)-1,3-octadiene 123289-34-9 C14H17BrS
    (Z)-8-bromo-3-(phenylthio)-1,3-octadiene
    —— 2-Propylmercapto-imidazol 17303-07-0 C6H10N2S
    2-Propylmercapto-imidazol
    —— N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)acrylamide 1299484-50-6 C19H15F2NOS2
    N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)acrylamide
    —— 8-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide 494226-33-4 C11H14N4OS
    8-(butylsulfanyl)-1,2,4-benzotriazin-3-amine 1-oxide
    —— 4,5-bis(propylthio)-5'-propylimidazole[4',5'-f]-2,2'-bi-1,3-dithiolylidene 1455499-66-7 C16H22N2S6
    4,5-bis(propylthio)-5'-propylimidazole[4',5'-f]-2,2'-bi-1,3-dithiolylidene
    —— (E)-2-Methyl-3-phenylsulfanyl-but-2-enoic acid ethyl ester 53700-03-1 C13H16O2S
    (E)-2-Methyl-3-phenylsulfanyl-but-2-enoic acid ethyl ester
    —— 3-(phenylthio)-5,6,4a,8a-tetrahydro-2,5,5-trimethylnaphthalene-1,8-(4H,7H)-dione 105090-19-5 C19H22O2S
    3-(phenylthio)-5,6,4a,8a-tetrahydro-2,5,5-trimethylnaphthalene-1,8-(4H,7H)-dione
    —— 1,1-dimethylethyl (4S)-4-[(2R)-2-[(2-cyano-3-thienyl)thio]-2-phenylethyl]-2,2-dimethyl-3-oxazolidinecarboxylate 651353-89-8 C23H28N2O3S2
    1,1-dimethylethyl (4S)-4-[(2R)-2-[(2-cyano-3-thienyl)thio]-2-phenylethyl]-2,2-dimethyl-3-oxazolidinecarboxylate
    —— 2-(4-(2-chloro-4-methylphenyl)thiazol-5-ylthio)acetic acid 871476-83-4 C12H10ClNO2S2
    2-(4-(2-chloro-4-methylphenyl)thiazol-5-ylthio)acetic acid
    —— 4-thiophenoxy<1>benzothieno<2,3-e>pyrrolo<1,2-a>pyrazine 107363-16-6 C19H12N2S2
    4-thiophenoxy<1>benzothieno<2,3-e>pyrrolo<1,2-a>pyrazine
    —— 4-chloro-N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)butanamide 1299484-49-3 C20H18ClF2NOS2
    4-chloro-N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)butanamide
    —— 2,2-bis(ethylthio)ethylamine 122807-21-0 C6H15NS2
    2,2-bis(ethylthio)ethylamine
    —— 3-(p-methylphenylthio)-2-decalone 83656-91-1 C17H22OS
    3-(p-methylphenylthio)-2-decalone
    —— 1-Ethylthio-3-phenylthiopropan 4911-42-6 C11H16S2
    1-Ethylthio-3-phenylthiopropan
    —— 1-Ethylthio-3-isopropylthio-propan 4911-39-1 C8H18S2
    1-Ethylthio-3-isopropylthio-propan