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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Carbonic acid, (dicyclohexylamino)thioxomethyl ethyl ester 5439-73-6 C16H27NO3S
    Carbonic acid, (dicyclohexylamino)thioxomethyl ethyl ester
    —— isopropyl 2-chloro-2-phenylthioacetate 255876-18-7 C11H13ClO2S
    isopropyl 2-chloro-2-phenylthioacetate
    —— dicyclohexylcarbamothioyl N,N-dicyclohexylcarbamodithioate 5439-78-1 C26H44N2S3
    dicyclohexylcarbamothioyl N,N-dicyclohexylcarbamodithioate
    —— 3-(Methoxycarbonyl)-2-(2-(phenylthio)ethyl)-4,5-dihydrofuran 131905-83-4 C14H16O3S
    3-(Methoxycarbonyl)-2-(2-(phenylthio)ethyl)-4,5-dihydrofuran
    —— (2R)-2-[3-chloro-4-(methylsulfanyl)phenyl]-3-cyclopentylpropanoic acid 588940-80-1 C15H19ClO2S
    (2R)-2-[3-chloro-4-(methylsulfanyl)phenyl]-3-cyclopentylpropanoic acid
    —— 4-(o-aminophenythio)-N-butyl-4-phenylbutyramide 89569-11-9 C20H26N2OS
    4-(o-aminophenythio)-N-butyl-4-phenylbutyramide
    —— 6-(5-isoquinolylsulfanyl)-7-nitroquinoxaline 203338-87-8 C17H10N4O2S
    6-(5-isoquinolylsulfanyl)-7-nitroquinoxaline
    —— tert.-Butyl(2-nitro-5-(phenylthio)phenyl)acetate 89278-19-3 C18H19NO4S
    tert.-Butyl(2-nitro-5-(phenylthio)phenyl)acetate
    —— 2-(5-chloro-2-nitrophenylthio)aniline 105837-12-5 C12H9ClN2O2S
    2-(5-chloro-2-nitrophenylthio)aniline
    —— O,O'-Dimethyl S,S'-methylene biscarbonodithioate 89364-30-7 C5H8O2S4
    O,O'-Dimethyl S,S'-methylene biscarbonodithioate
    —— 5-(3,5-Dichlorophenylthio)-1,2-bis-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole 178980-42-2 C18H22Cl2N4O4S
    5-(3,5-Dichlorophenylthio)-1,2-bis-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-(3-carbamoyloxypropyl)-4-isopropyl-1H-imidazole 178980-46-6 C19H24Cl2N4O4S
    5-(3,5-Dichlorophenylthio)-1-(2-carbamoyloxyethyl)-2-(3-carbamoyloxypropyl)-4-isopropyl-1H-imidazole
    —— (4-chloromethyl-phenyl)-(4-nitro-phenyl)-sulfide 100398-42-3 C13H10ClNO2S
    (4-chloromethyl-phenyl)-(4-nitro-phenyl)-sulfide
    —— 4,4'-Bis-(phenylthio)-azoxybenzol 5333-73-3 C24H18N2OS2
    4,4'-Bis-(phenylthio)-azoxybenzol
    —— 5,6-dihydro-6-phenyl-4H-s-triazolo<3,4-e><1,6>benzothiazocine 89569-01-7 C17H15N3S
    5,6-dihydro-6-phenyl-4H-s-triazolo<3,4-e><1,6>benzothiazocine
    —— 2-(Propylsulfonyl)cyclohexanon 85058-04-4 C9H16O3S
    2-(Propylsulfonyl)cyclohexanon
    —— 5,6-dimethyl-3-(phenylthio)pyridazine-4-carbonitrile 93824-73-8 C13H11N3S
    5,6-dimethyl-3-(phenylthio)pyridazine-4-carbonitrile
    —— 5-Methyl-2-(phenylthio)hexyl-phenylsulfid 66164-98-5 C19H24S2
    5-Methyl-2-(phenylthio)hexyl-phenylsulfid
    —— 5-Methyl-2-(phenylthio)hexan-1-ol 61829-50-3 C13H20OS
    5-Methyl-2-(phenylthio)hexan-1-ol
    —— 5-Methyl-2-phenylthiohexanal 66332-73-8 C13H18OS
    5-Methyl-2-phenylthiohexanal
    —— 2-(3-Butenylsulfonyl)-1-cyclohexanon 89730-09-6 C10H16O3S
    2-(3-Butenylsulfonyl)-1-cyclohexanon
    —— 2-(Hexylsulfonyl)-1-cyclohexanon 89729-99-7 C12H22O3S
    2-(Hexylsulfonyl)-1-cyclohexanon
    —— 3-methyl-5-(pyridin-2-ylsulfanyl)-3H-imidazole-4-carbaldehyde 1258283-09-8 C10H9N3OS
    3-methyl-5-(pyridin-2-ylsulfanyl)-3H-imidazole-4-carbaldehyde
    —— 3-tert-butylthio-4-hydroxy-6-methyl-2-pyrone 53603-44-4 C10H14O3S
    3-tert-butylthio-4-hydroxy-6-methyl-2-pyrone
    —— 2-methylthio-4,6-pyrimidinyl ditriflate 154499-78-2 C7H4F6N2O6S3
    2-methylthio-4,6-pyrimidinyl ditriflate
    —— phenyl 2-deoxy-2-fluoro-1-thio-α-D-mannopyranoside 931095-45-3 C12H15FO4S
    phenyl 2-deoxy-2-fluoro-1-thio-α-D-mannopyranoside
    —— Dicyclohexyl-[[1-(phenylsulfanylmethyl)triazol-4-yl]methyl]phosphane 1186034-81-0 C22H32N3PS
    Dicyclohexyl-[[1-(phenylsulfanylmethyl)triazol-4-yl]methyl]phosphane
    —— 6-methyl-2-methylthio-4-pyrimidinyl triflate 154499-79-3 C7H7F3N2O3S2
    6-methyl-2-methylthio-4-pyrimidinyl triflate
    —— 2-chloro-3-(4-bromophenylthio)-4-aminopyridine 1235872-84-0 C11H8BrClN2S
    2-chloro-3-(4-bromophenylthio)-4-aminopyridine
    —— potassium N,N-di-n-propylthiocarbamate 115981-32-3 C7H14NOS*K
    potassium N,N-di-n-propylthiocarbamate
    —— 3,12-dioxa-7,8-dithiatetradecane-1,14-diol 1316759-69-9 C10H22O4S2
    3,12-dioxa-7,8-dithiatetradecane-1,14-diol
    —— 2-chloro-3-(phenylthio)pyridin-4-amine 1235876-44-4 C11H9ClN2S
    2-chloro-3-(phenylthio)pyridin-4-amine
    —— (1E,3E)-1-bromo-4-(phenylthio)-1,3-butadiene-1,2,3,4-d4 188802-32-6 C10H9BrS
    (1E,3E)-1-bromo-4-(phenylthio)-1,3-butadiene-1,2,3,4-d4
    —— tert-butyl-dimethyl-[2-[(2S,6S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,6-dihydro-2H-pyran-6-yl]ethoxy]silane 1373398-03-8 C23H38O2SSi
    tert-butyl-dimethyl-[2-[(2S,6S)-2-[(2R)-2-methyl-3-phenylsulfanylpropyl]-3,6-dihydro-2H-pyran-6-yl]ethoxy]silane
    —— 2-[(1R,2R,4R)-4-(2-Methoxy-ethoxymethoxy)-2-methylsulfanylmethoxymethyl-cyclopentyl]-oxirane 231291-47-7 C14H26O5S
    2-[(1R,2R,4R)-4-(2-Methoxy-ethoxymethoxy)-2-methylsulfanylmethoxymethyl-cyclopentyl]-oxirane
    —— 2(S)-methyl-3-(methyl sulfonyl)propionic acid t-butyl ester 143225-00-7 C9H18O4S
    2(S)-methyl-3-(methyl sulfonyl)propionic acid t-butyl ester
    —— 4-Amino-6-methylsulfanylpyrimidine-5-carbonitrile 900479-85-8 C6H6N4S
    4-Amino-6-methylsulfanylpyrimidine-5-carbonitrile
    —— 6,16,19,29-Tetraoxa-3,9,11,24,26,32-hexathia-13,22,39,40-tetrazatetracyclo[32.3.1.110,13.122,25]tetraconta-1(38),10(40),25(39),34,36-pentaene-12,23-dione 1041201-03-9 C26H36N4O6S6
    6,16,19,29-Tetraoxa-3,9,11,24,26,32-hexathia-13,22,39,40-tetrazatetracyclo[32.3.1.110,13.122,25]tetraconta-1(38),10(40),25(39),34,36-pentaene-12,23-dione
    —— 3,5-dimethylphenyl ethyl xanthate 89816-83-1 C11H14OS2
    3,5-dimethylphenyl ethyl xanthate
    —— 2-i-Propyl-propan-1,3-dithiol 24330-59-4 C6H14S2
    2-i-Propyl-propan-1,3-dithiol
    —— 2-[β-(1-pyrrolidinyl)ethylthio]phenyl-N-phenylbenzthioimidate hydrochloride 78455-24-0 C25H26N2S2*ClH
    2-[β-(1-pyrrolidinyl)ethylthio]phenyl-N-phenylbenzthioimidate hydrochloride
    —— 2-[β-(1-pyrrolidinyl)ethylthio]phenol 78455-23-9 C12H17NOS
    2-[β-(1-pyrrolidinyl)ethylthio]phenol
    —— isopropyl 2-(pentylsulfonyl) diazoacetate 1424362-21-9 C10H18N2O4S
    isopropyl 2-(pentylsulfonyl) diazoacetate
    —— 4-methoxy-4-{4-[4-(2-methyl-1,3-dioxolan-2-yl)benzyloxy]-2-methylthiopyrimidin-6-yl}tetrahydropyran 161386-27-2 C22H28N2O5S
    4-methoxy-4-{4-[4-(2-methyl-1,3-dioxolan-2-yl)benzyloxy]-2-methylthiopyrimidin-6-yl}tetrahydropyran
    —— (2R,3R,4S,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-6-fluoro-2-methyl-5-phenylsulfanyl-tetrahydro-pyran 306768-24-1 C24H43FO3SSi2
    (2R,3R,4S,5R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-6-fluoro-2-methyl-5-phenylsulfanyl-tetrahydro-pyran
    —— 4-(4-bromo-2-methylthiopyrimidin-6-yl)-4-methoxytetrahydropyran 161386-32-9 C11H15BrN2O2S
    4-(4-bromo-2-methylthiopyrimidin-6-yl)-4-methoxytetrahydropyran
    —— N,N'-hexanediyl bis-dithiocarbamic acid diphenyl ester 1370652-54-2 C20H24N2S4
    N,N'-hexanediyl bis-dithiocarbamic acid diphenyl ester
    —— 4-diethoxymethyl-2-hexylsulfanyl-6-methylpyrimidine 863672-51-9 C16H28N2O2S
    4-diethoxymethyl-2-hexylsulfanyl-6-methylpyrimidine
    —— 4-(trifluoromethyl)-2-(methylthio)-6-(thiophen-2-yl)pyridine-3-carbonitrile 285980-91-8 C12H7F3N2S2
    4-(trifluoromethyl)-2-(methylthio)-6-(thiophen-2-yl)pyridine-3-carbonitrile
    —— 2-(2-oxopropylthio)-4-(trifluoromethyl)-6-(thiophen-2-yl)pyridine-3-carbonitrile 332869-24-6 C14H9F3N2OS2
    2-(2-oxopropylthio)-4-(trifluoromethyl)-6-(thiophen-2-yl)pyridine-3-carbonitrile