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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5-Cyclohexyl-4-methyl-4H-[1,2,4]triazol-3-yl-sulfanyl)acetic acid 462066-86-0 C11H17N3O2S
    (5-Cyclohexyl-4-methyl-4H-[1,2,4]triazol-3-yl-sulfanyl)acetic acid
    —— 1H-Imidazole, 1-(2-((4-chlorophenoxy)thio)-3,3-dimethyl-1-oxobutyl)- 94125-97-0 C15H17ClN2OS
    1H-Imidazole, 1-(2-((4-chlorophenoxy)thio)-3,3-dimethyl-1-oxobutyl)-
    —— 2,1-Benzisoxazole, 5,5'-thiobis[3-phenyl- 106500-64-5 C26H16N2O2S
    2,1-Benzisoxazole, 5,5'-thiobis[3-phenyl-
    —— 2,4-Bis-phenylthio-6-chloro-s-triazin 38375-19-8 C15H10ClN3S2
    2,4-Bis-phenylthio-6-chloro-s-triazin
    —— methoxythiocarbonylmercapto-acetic acid amide 138111-22-5 C4H7NO2S2
    methoxythiocarbonylmercapto-acetic acid amide
    —— hexadecyl N,N'-dimethylcarbamimidothioate;hydron;bromide —— C19H41BrN2S
    hexadecyl N,N'-dimethylcarbamimidothioate;hydron;bromide
    —— [Amino-[2-[amino(azaniumylidene)methyl]sulfanylethylsulfanyl]methylidene]azanium;dibromide 6943-65-3 C4H12Br2N4S2
    [Amino-[2-[amino(azaniumylidene)methyl]sulfanylethylsulfanyl]methylidene]azanium;dibromide
    —— [amino-[5-[amino(azaniumylidene)methyl]sulfanylpentylsulfanyl]methylidene]azanium;dibromide —— C7H18Br2N4S2
    [amino-[5-[amino(azaniumylidene)methyl]sulfanylpentylsulfanyl]methylidene]azanium;dibromide
    —— Di-tert-butylheptasulfane 7330-34-9 C8H18S7
    Di-tert-butylheptasulfane
    —— Pseudourea, 2-decyl-1,3-dimethyl-2-thio-, hydriodide 6319-42-2 C13H29IN2S
    Pseudourea, 2-decyl-1,3-dimethyl-2-thio-, hydriodide
    —— Thioperoxydicarbonic diamide (((H2N)C(S))2S2),tetramethyl-, mixt. with pentachloronitrobenzene 55257-72-2 C12H12Cl5N3O4S2
    Thioperoxydicarbonic diamide (((H2N)C(S))2S2),tetramethyl-, mixt. with pentachloronitrobenzene
    —— Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydriodide 5339-45-7 C19H41IN2S
    Pseudourea, 2-hexadecyl-1,3-dimethyl-2-thio-, hydriodide
    —— decyl carbamimidothioate;hydron;chloride —— C11H25ClN2S
    decyl carbamimidothioate;hydron;chloride
    —— (β-Diethylaminoethyl)-isothioharnstoff 17124-83-3 C7H17N3S
    (β-Diethylaminoethyl)-isothioharnstoff
    —— dodecyl N,N'-diethylcarbamimidothioate;hydron;iodide —— C17H37IN2S
    dodecyl N,N'-diethylcarbamimidothioate;hydron;iodide
    —— <i>S</i>-tetradecyl-isothiourea 735203-55-1 C15H32N2S
    <i>S</i>-tetradecyl-isothiourea
    —— Pseudourea, 2-dodecyl-1,3-dimethyl-2-thio-, hydriodide 5395-98-2 C15H33IN2S
    Pseudourea, 2-dodecyl-1,3-dimethyl-2-thio-, hydriodide
    —— Pseudourea, 2-dodecyl-1,3-dimethyl-2-thio-, hydrochloride 5412-04-4 C15H33ClN2S
    Pseudourea, 2-dodecyl-1,3-dimethyl-2-thio-, hydrochloride
    —— 2-octyl-isothiourea; hydrochloride 3544-29-4 C9H20N2S*ClH
    2-octyl-isothiourea; hydrochloride
    —— 1,1'-Oxy-bis<2-(ethenylsulfonyl)>-ethane 3088-18-4 C8H14O5S2
    1,1'-Oxy-bis<2-(ethenylsulfonyl)>-ethane
    —— Dibutyl(octoxycarbonylsulfanylmethyl)stannanylium;2-octoxy-2-oxoethanethiolate —— C28H56O4S2Sn
    Dibutyl(octoxycarbonylsulfanylmethyl)stannanylium;2-octoxy-2-oxoethanethiolate
    —— 4H-Pyrimido(4,5-e)-1,2,4-thiadiazine, 8-amino-4-methyl-6-(methylthio)-, 1,1-dioxide 74039-27-3 C7H9N5O2S2
    4H-Pyrimido(4,5-e)-1,2,4-thiadiazine, 8-amino-4-methyl-6-(methylthio)-, 1,1-dioxide
    —— 7-methoxy-10H-pyrido[2,3-b]pyrimido[4,5-e][1,4]thiazine-2,4-diamine 42362-20-9 C10H10N6OS
    7-methoxy-10H-pyrido[2,3-b]pyrimido[4,5-e][1,4]thiazine-2,4-diamine
    —— <3-Carboxamid-5-nitro-2-pyridyl>-pyrimidyl-thioaether 73768-59-9 C10H7N5O3S
    <3-Carboxamid-5-nitro-2-pyridyl>-pyrimidyl-thioaether
    —— 10H-Pyrido(3,2-b)pyrimido(4,5-e)(1,4)thiazin-4-amine, 8-methyl- 55740-63-1 C10H9N5S
    10H-Pyrido(3,2-b)pyrimido(4,5-e)(1,4)thiazin-4-amine, 8-methyl-
    —— Chromrhodanid —— C3CrN3S3
    Chromrhodanid
    —— 1.2-Bis-propylmercapto-ethen 16330-20-4 C8H16S2
    1.2-Bis-propylmercapto-ethen
    —— 4-Methoxy-2-methyl-5-(methylsulfanyl)pyridin-3-ol 703-46-8 C8H11NO2S
    4-Methoxy-2-methyl-5-(methylsulfanyl)pyridin-3-ol
    —— 2,5-Cyclohexadien-1-one, 4-thioxo- 84615-34-9 C6H4OS
    2,5-Cyclohexadien-1-one, 4-thioxo-
    —— Zn(SCN)2 —— C2N2S2Zn
    Zn(SCN)2
    —— Sulfur mustard agent HT 172672-28-5 C12H24Cl4OS3
    Sulfur mustard agent HT
    —— N'-[3-(1-adamantyl)propyl]-2-[[2-[3-(1-adamantyl)propylimino]-2-aminoethyl]disulfanyl]ethanimidamide;hydron;dichloride;hydrate —— C30H54Cl2N4OS2
    N'-[3-(1-adamantyl)propyl]-2-[[2-[3-(1-adamantyl)propylimino]-2-aminoethyl]disulfanyl]ethanimidamide;hydron;dichloride;hydrate
    —— 3-Methylthio-5-(1'-adamantyl)-1,2,4-triazin 69466-73-5 C14H19N3S
    3-Methylthio-5-(1'-adamantyl)-1,2,4-triazin
    —— 2-[[2-amino-2-[(3,5-dimethyl-1-adamantyl)methylimino]ethyl]disulfanyl]-N'-[(3,5-dimethyl-1-adamantyl)methyl]ethanimidamide;hydron;dichloride;hydrate —— C30H54Cl2N4OS2
    2-[[2-amino-2-[(3,5-dimethyl-1-adamantyl)methylimino]ethyl]disulfanyl]-N'-[(3,5-dimethyl-1-adamantyl)methyl]ethanimidamide;hydron;dichloride;hydrate
    —— N'-[2-(1-adamantylsulfanyl)ethyl]-2-[[2-[2-(1-adamantylsulfanyl)ethylimino]-2-aminoethyl]disulfanyl]ethanimidamide;hydron;dichloride;hydrate —— C28H50Cl2N4OS4
    N'-[2-(1-adamantylsulfanyl)ethyl]-2-[[2-[2-(1-adamantylsulfanyl)ethylimino]-2-aminoethyl]disulfanyl]ethanimidamide;hydron;dichloride;hydrate
    —— 1-Adamantylmethyl-[2-[3-[amino(azaniumylidene)methyl]sulfanylpropylazaniumyl]ethyl]azanium;tribromide 88318-08-5 C17H35Br3N4S
    1-Adamantylmethyl-[2-[3-[amino(azaniumylidene)methyl]sulfanylpropylazaniumyl]ethyl]azanium;tribromide
    —— 2-(1-adamantylamino)ethyl carbamimidothioate;hydron;dibromide —— C13H25Br2N3S
    2-(1-adamantylamino)ethyl carbamimidothioate;hydron;dibromide
    —— N'-(1-adamantylmethyl)-2-[[2-(1-adamantylmethylimino)-2-aminoethyl]disulfanyl]ethanimidamide;hydron;tetrachloride;hydrate —— C52H90Cl4N8OS4
    N'-(1-adamantylmethyl)-2-[[2-(1-adamantylmethylimino)-2-aminoethyl]disulfanyl]ethanimidamide;hydron;tetrachloride;hydrate
    —— N-(3,5-Dimethyl-adamantan-1-ylmethyl)-2-[N-(3,5-dimethyl-adamantan-1-ylmethyl)-carbamimidoylmethyldisulfanyl]-acetamidine 90379-51-4 C30H50N4S2
    N-(3,5-Dimethyl-adamantan-1-ylmethyl)-2-[N-(3,5-dimethyl-adamantan-1-ylmethyl)-carbamimidoylmethyldisulfanyl]-acetamidine
    —— N'-[3-(1-adamantyl)propyl]-2-[[2-[3-(1-adamantyl)propylimino]-2-aminoethyl]disulfanyl]ethanimidamide 90379-54-7 C30H50N4S2
    N'-[3-(1-adamantyl)propyl]-2-[[2-[3-(1-adamantyl)propylimino]-2-aminoethyl]disulfanyl]ethanimidamide
    —— N,N-diethylcarbamodithioate;selenium(4+) —— C20H40N4S8Se
    N,N-diethylcarbamodithioate;selenium(4+)
    —— 2-(4-Aminobutyl)-2-thiopseudourea dihydrobromide 102274-22-6 C5H15Br2N3S
    2-(4-Aminobutyl)-2-thiopseudourea dihydrobromide
    —— ((4-Chlorophenyl)thio)acetic acid 3-((1-(hydroxymethyl)amino)cyclohexyl)oxy-1-propanol (1:1) 105892-12-4 C18H28ClNO5S
    ((4-Chlorophenyl)thio)acetic acid 3-((1-(hydroxymethyl)amino)cyclohexyl)oxy-1-propanol (1:1)
    —— 2,3-Dimethyl-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline 100280-24-8 C10H11F4NS
    2,3-Dimethyl-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline
    —— Aniline, 3-(methylthio)-N-(2-oxazolin-2-YL)- 102583-77-7 C10H12N2OS
    Aniline, 3-(methylthio)-N-(2-oxazolin-2-YL)-
    —— 3-Chloro-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline 100280-17-9 C8H6ClF4NS
    3-Chloro-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline
    —— MALONONITRILE, (p-(p-CHLOROBENZYLTHIO)BENZYLIDENE)- 101756-26-7 C17H11ClN2S
    MALONONITRILE, (p-(p-CHLOROBENZYLTHIO)BENZYLIDENE)-
    —— ANILINE, o-METHYLTHIO-N-(2-OXAZOLIN-2-YL)- 101831-55-4 C10H12N2OS
    ANILINE, o-METHYLTHIO-N-(2-OXAZOLIN-2-YL)-
    —— N~3~-{4-Chloro-2-[(4-chlorophenyl)sulfanyl]phenyl}-N~1~,N~1~-dimethylpropane-1,3-diamine--hydrogen chloride (1/1) 101831-51-0 C17H21Cl3N2S
    N~3~-{4-Chloro-2-[(4-chlorophenyl)sulfanyl]phenyl}-N~1~,N~1~-dimethylpropane-1,3-diamine--hydrogen chloride (1/1)
    —— 2-Bromo-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline 100280-23-7 C8H6BrF4NS
    2-Bromo-4-(1,1,2,2-tetrafluoroethylsulfanyl)aniline