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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Amino-4-methylthiopyrimidine-5-carbonitrile 86700-24-5 C6H6N4S
    2-Amino-4-methylthiopyrimidine-5-carbonitrile
    —— 1-phenylthio-1-trimethylsilylhexane 76200-39-0 C15H26SSi
    1-phenylthio-1-trimethylsilylhexane
    —— S-<(Z)-oct-2'-enyl> N,N-dimethyl(thiocarbamate) 111835-81-5 C11H21NOS
    S-<(Z)-oct-2'-enyl> N,N-dimethyl(thiocarbamate)
    —— 5-chloro-2-(methylthio)-6-(trifluoromethyl)pyrimidin-4-ol 85730-38-7 C6H4ClF3N2OS
    5-chloro-2-(methylthio)-6-(trifluoromethyl)pyrimidin-4-ol
    —— 1-methyl-5-[3-(2-furoyl)propyl]thio-1,2,3,4-tetrazole 80087-47-4 C10H12N4O2S
    1-methyl-5-[3-(2-furoyl)propyl]thio-1,2,3,4-tetrazole
    —— 4-(4-aminophenylthio)pyridin-2-ol 1020087-63-1 C11H10N2OS
    4-(4-aminophenylthio)pyridin-2-ol
    —— 1-phenyl-1-phenylthio-1-trimethylsilylhexane 105494-73-3 C21H30SSi
    1-phenyl-1-phenylthio-1-trimethylsilylhexane
    —— bis-(4-methanesulfonyl-phenyl)-sulfide 500900-67-4 C14H14O4S3
    bis-(4-methanesulfonyl-phenyl)-sulfide
    —— 5-(methylthio)pentan-1-ol 57774-99-9 C6H14OS
    5-(methylthio)pentan-1-ol
    —— 2-cyclohexyl-2-ethynyl-1,3-dithiolane 920979-34-6 C11H16S2
    2-cyclohexyl-2-ethynyl-1,3-dithiolane
    —— 5,5,6,6,6-pentafluoro-2-(3,3,3-trifluoropropylsulfonyl)hexanenitrile 939048-13-2 C9H9F8NO2S
    5,5,6,6,6-pentafluoro-2-(3,3,3-trifluoropropylsulfonyl)hexanenitrile
    —— 2-<4-(trifluoromethyl)pyridin-2-ylsulfanyl>ethanol 173729-51-6 C8H8F3NOS
    2-<4-(trifluoromethyl)pyridin-2-ylsulfanyl>ethanol
    —— Methyl-1-cyclobutan-1-phenylthio-carboxylat 72548-18-6 C12H14O2S
    Methyl-1-cyclobutan-1-phenylthio-carboxylat
    —— 1-mercapto-1,1-bis(trimethylsilyl)heptane-2-thione 1493804-02-6 C13H30S2Si2
    1-mercapto-1,1-bis(trimethylsilyl)heptane-2-thione
    —— 4-(4-chlorophenylthio)benzene-1,3-diol 19349-41-8 C12H9ClO2S
    4-(4-chlorophenylthio)benzene-1,3-diol
    —— 2-(methylthio)-4-(thiophen-2-yl)-6-(trifluoromethyl)pyrimidine 2627-53-4 C10H7F3N2S2
    2-(methylthio)-4-(thiophen-2-yl)-6-(trifluoromethyl)pyrimidine
    —— 2-benzylsulfanyl-4-thiophen-2-yl-6-trifluoromethyl-pyrimidine 71445-37-9 C16H11F3N2S2
    2-benzylsulfanyl-4-thiophen-2-yl-6-trifluoromethyl-pyrimidine
    —— 2-Phenyl-1-(phenylthio)-3-oxabicyclo[3.1.0]hexan-4-one 112146-29-9 C17H14O2S
    2-Phenyl-1-(phenylthio)-3-oxabicyclo[3.1.0]hexan-4-one
    —— butyl 2,2,2-trifluoroethyl sulfone 86808-93-7 C6H11F3O2S
    butyl 2,2,2-trifluoroethyl sulfone
    —— 5-amino-4-phenylthiophthalodinitrile 620175-17-9 C14H9N3S
    5-amino-4-phenylthiophthalodinitrile
    —— 2-Nonylsulfanylphenol 24312-58-1 C15H24OS
    2-Nonylsulfanylphenol
    —— tetrakis([1,4,7,10,13]trioxadithiacyclopentadeceno)[11,12-b:11',12'-g:11'',12''-l:11''',12'''-q]porphyrazinate 154480-74-7 C48H66N8O12S8
    tetrakis([1,4,7,10,13]trioxadithiacyclopentadeceno)[11,12-b:11',12'-g:11'',12''-l:11''',12'''-q]porphyrazinate
    —— dinonyl trisulfide 116214-16-5 C18H38S3
    dinonyl trisulfide
    —— 5-acetylamino-4-phenylthiophthalodinitrile 620175-19-1 C16H11N3OS
    5-acetylamino-4-phenylthiophthalodinitrile
    —— 5-octanoylamino-4-phenylthiophthalodinitrile 620175-21-5 C22H23N3OS
    5-octanoylamino-4-phenylthiophthalodinitrile
    —— 11-(3-dimethylaminopropyl)-11H-dibenzo<b,e>-1,4-dithiepin 81890-72-4 C18H21NS2
    11-(3-dimethylaminopropyl)-11H-dibenzo<b,e>-1,4-dithiepin
    —— (2-bromobenzyl)(4-chlorophenyl)sulfane 1443354-46-8 C13H10BrClS
    (2-bromobenzyl)(4-chlorophenyl)sulfane
    —— 4-(2-ethoxy-2-methoxyethyl)thioanisole 1097200-08-2 C12H18O2S
    4-(2-ethoxy-2-methoxyethyl)thioanisole
    —— 4-chlorophenyl trichloromethyl sulfide 706-29-6 C7H4Cl4S
    4-chlorophenyl trichloromethyl sulfide
    —— 5-ethylthio-3,4-dihydro-2H-pyrrole 144571-72-2 C6H11NS
    5-ethylthio-3,4-dihydro-2H-pyrrole
    —— thieno[3,2-b][1,4]thiazinone 85930-26-3 C6H5NOS2
    thieno[3,2-b][1,4]thiazinone
    —— 7-(2-Nonyl-1,3-dithian-2-yl)heptan-1-ol 861997-73-1 C20H40OS2
    7-(2-Nonyl-1,3-dithian-2-yl)heptan-1-ol
    —— acetyl-4 dihydro-2,3 oxo-3 thieno<2,3-e>thiazine-1,4 85930-42-3 C8H7NO2S2
    acetyl-4 dihydro-2,3 oxo-3 thieno<2,3-e>thiazine-1,4
    —— 3-methyl-7,8,9,10,11,12,13,14,15,15a-decahydro-6<i>H</i>-cyclododeca[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60060-41-5 C15H24N4S
    3-methyl-7,8,9,10,11,12,13,14,15,15a-decahydro-6<i>H</i>-cyclododeca[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— n-nonylisothiouronium bromide 64570-26-9 BrH*C10H22N2S
    n-nonylisothiouronium bromide
    —— 3-(Methanesulfonyl)-2-methoxy-5-(methylsulfanyl)thiophene 88234-96-2 C7H10O3S3
    3-(Methanesulfonyl)-2-methoxy-5-(methylsulfanyl)thiophene
    —— 2,5,2',5'-tetrachloro-4,4'-sulfanediyl-di-phenol 82911-56-6 C12H6Cl4O2S
    2,5,2',5'-tetrachloro-4,4'-sulfanediyl-di-phenol
    —— 1-Acetoxy-4,4-dimethyl-1-phenylthio-2-pentanon 65303-02-8 C15H20O3S
    1-Acetoxy-4,4-dimethyl-1-phenylthio-2-pentanon
    —— 1-(4-trimethylsilylphenyl)thiononane 850186-10-6 C18H32SSi
    1-(4-trimethylsilylphenyl)thiononane
    —— 2-(4-Chlorophenyl)-9-propyl-5,6-dihydrothieno[2',3':2,3]thiepino[4,5-c]pyridazin-3(2H)-one 135301-44-9 C19H17ClN2OS2
    2-(4-Chlorophenyl)-9-propyl-5,6-dihydrothieno[2',3':2,3]thiepino[4,5-c]pyridazin-3(2H)-one
    —— 2-ethoxycarbonylethyl (3-methylthio-1,2,4-triazol-5-yl)aminodithiocarbonate 131023-15-9 C9H14N4O2S3
    2-ethoxycarbonylethyl (3-methylthio-1,2,4-triazol-5-yl)aminodithiocarbonate
    —— 6-(2-bromo-phenylsulfanyl)-3-chloro-2-isopropoxy-aniline 16762-89-3 C15H15BrClNOS
    6-(2-bromo-phenylsulfanyl)-3-chloro-2-isopropoxy-aniline
    —— 2-(4-Chlorophenyl)-9-ethyl-4,4a,5,6-tetrahydrothieno-[2',3':2,3]thiepino[4,5-c]pyridazin-3(2H)-one 135279-22-0 C18H17ClN2OS2
    2-(4-Chlorophenyl)-9-ethyl-4,4a,5,6-tetrahydrothieno-[2',3':2,3]thiepino[4,5-c]pyridazin-3(2H)-one
    —— 2-(4-oxo-2-propyl-6,7-dihydro-5H-thieno[2,3-b]thiepin-5-yl)acetonitrile 1026429-08-2 C13H15NOS2
    2-(4-oxo-2-propyl-6,7-dihydro-5H-thieno[2,3-b]thiepin-5-yl)acetonitrile
    —— 4-oxo-2-propyl-4,5,6,7-tetrahydrothieno[2,3-b]thiepin-5-acetic acid 135279-00-4 C13H16O3S2
    4-oxo-2-propyl-4,5,6,7-tetrahydrothieno[2,3-b]thiepin-5-acetic acid
    —— 13-(4-Chlorophenyl)-4-propyl-5,7-dithia-13,14-diazatricyclo[8.4.0.02,6]tetradeca-1(14),2(6),3-trien-12-one 173549-00-3 C19H19ClN2OS2
    13-(4-Chlorophenyl)-4-propyl-5,7-dithia-13,14-diazatricyclo[8.4.0.02,6]tetradeca-1(14),2(6),3-trien-12-one
    —— 2-ethyl-4-oxo-4,5,6,7-tetrahydrothieno[2,3-b]thiepin-5-acetic acid 135278-99-8 C12H14O3S2
    2-ethyl-4-oxo-4,5,6,7-tetrahydrothieno[2,3-b]thiepin-5-acetic acid
    —— 2-(4-chlorophenyl)-9-ethyl-5,6-dihydrothieno[2',3':2,3]-thiepino[4,5-c]pyridazin-3(2H)-one 135279-23-1 C18H15ClN2OS2
    2-(4-chlorophenyl)-9-ethyl-5,6-dihydrothieno[2',3':2,3]-thiepino[4,5-c]pyridazin-3(2H)-one
    —— 2-(2-ethyl-4-oxo-6,7-dihydro-5H-thieno[2,3-b]thiepin-5-yl)acetonitrile 135279-12-8 C12H13NOS2
    2-(2-ethyl-4-oxo-6,7-dihydro-5H-thieno[2,3-b]thiepin-5-yl)acetonitrile
    —— 3,3-bis-phenylsulfanyl-decan-4-ol 61173-88-4 C22H30OS2
    3,3-bis-phenylsulfanyl-decan-4-ol