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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(Methylsulfanyl)pyrazino[2,3-e][1,2,4]triazine 831218-37-2 C6H5N5S
    3-(Methylsulfanyl)pyrazino[2,3-e][1,2,4]triazine
    —— 5,5-dideuterio-1,5-dihydro-3-methyl-10-thia-5-deazaflavin 69139-14-6 C12H10N2O2S
    5,5-dideuterio-1,5-dihydro-3-methyl-10-thia-5-deazaflavin
    —— 2-(2-Chloro-pyridin-3-ylsulfanyl)-3,5,6-trimethyl-phenol 103424-57-3 C14H14ClNOS
    2-(2-Chloro-pyridin-3-ylsulfanyl)-3,5,6-trimethyl-phenol
    —— Methyl 2,4-dioxo-3-phenylthiobutyrate 119493-28-6 C11H10O4S
    Methyl 2,4-dioxo-3-phenylthiobutyrate
    —— 5-ethylthio-3-methyl-4-nitrosoisothiazole 74840-89-4 C6H8N2OS2
    5-ethylthio-3-methyl-4-nitrosoisothiazole
    —— 2-n-propylthietane 1,1-dioxide 80324-93-2 C6H12O2S
    2-n-propylthietane 1,1-dioxide
    —— 4-n-propylthiete 1,1-dioxide 154012-37-0 C6H10O2S
    4-n-propylthiete 1,1-dioxide
    —— (Z)-4-Dimethylamino-3-phenylsulfanyl-1-(tetrahydro-pyran-2-yloxy)-but-3-en-2-one 115412-98-1 C17H23NO3S
    (Z)-4-Dimethylamino-3-phenylsulfanyl-1-(tetrahydro-pyran-2-yloxy)-but-3-en-2-one
    —— 5-Chloro-2H-1,3-benzodithiole 133532-83-9 C7H5ClS2
    5-Chloro-2H-1,3-benzodithiole
    —— <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-3-(tert-butyldimethylsiloxy)-2H-pyran 121620-35-7 C24H46O3S2Si
    <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-3-(tert-butyldimethylsiloxy)-2H-pyran
    —— <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-2H-pyran-3-ol 101696-65-5 C18H32O3S2
    <2α<Z(S<sup>*</sup>)>,3β>-2-<3-<3,3-bis(ethylthio)tetrahydro-2H-pyran-2-yl>-2-propenyl>tetrahydro-2-methyl-2H-pyran-3-ol
    —— 2-(4-Bromophenyl)-6-methyl-5-phenylsulfanyl-2,3-dihydropyran-4-one 129435-93-4 C18H15BrO2S
    2-(4-Bromophenyl)-6-methyl-5-phenylsulfanyl-2,3-dihydropyran-4-one
    —— 3-(2-phenylthio-3,3-dimethyl-1-butenyl)-2-pyridinol 142502-93-0 C17H19NOS
    3-(2-phenylthio-3,3-dimethyl-1-butenyl)-2-pyridinol
    —— Methyl <1-(Phenylthio)-3,3-dimethylbutylidene>hydrazinocarboxylate 114393-61-2 C14H20N2O2S
    Methyl <1-(Phenylthio)-3,3-dimethylbutylidene>hydrazinocarboxylate
    —— 4-n-Propylmercapto-2-methylpyridin 5613-23-0 C9H13NS
    4-n-Propylmercapto-2-methylpyridin
    —— cis-3-Methoxy-1-methylmercapto-prop-1-en 13168-92-8 C5H10OS
    cis-3-Methoxy-1-methylmercapto-prop-1-en
    —— 2-(3-Bromo-thien-2-ylthio)valeric acid 142578-09-4 C9H11BrO2S2
    2-(3-Bromo-thien-2-ylthio)valeric acid
    —— 2-tert-butyl-4-chloro-5-(4-n-propoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-35-5 C19H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-n-propoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane 68409-14-3 C6H10F4S
    2-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane
    —— 2-tert-butyl-4-chloro-5-(4-cyclopropylmethoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-34-4 C20H31ClN2O2S
    2-tert-butyl-4-chloro-5-(4-cyclopropylmethoxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— Dimethyl-2-(3-bromo-2-thienylthio)-2-methylglutarate 142578-01-6 C12H15BrO4S2
    Dimethyl-2-(3-bromo-2-thienylthio)-2-methylglutarate
    —— 2-tert-butyl-4-chloro-5-(4-n-hexyloxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone 141604-39-9 C22H37ClN2O2S
    2-tert-butyl-4-chloro-5-(4-n-hexyloxymethyl-cyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-(hexane-1-sulfonyl)-ethylamine 771574-30-2 C8H19NO2S
    2-(hexane-1-sulfonyl)-ethylamine
    —— 2-tert-butyl-4-chloro-5-(4-isobutylthiomethylcyclohexyl)methylthio-3(2H)-pyridazinone 141604-42-4 C20H33ClN2OS2
    2-tert-butyl-4-chloro-5-(4-isobutylthiomethylcyclohexyl)methylthio-3(2H)-pyridazinone
    —— 2-tert-butyl-4-chloro-5-(4-cyclohexyloxymethylcyclohexyl)methylthio-3(2H)-pyridazinone 141604-40-2 C22H35ClN2O2S
    2-tert-butyl-4-chloro-5-(4-cyclohexyloxymethylcyclohexyl)methylthio-3(2H)-pyridazinone
    —— 1-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane 68409-10-9 C6H10F4S
    1-(1,1,2,2-Tetrafluoro-ethylsulfanyl)-butane
    —— 4-Fluor-2-methylthiothiophen 32431-73-5 C5H5FS2
    4-Fluor-2-methylthiothiophen
    —— 3,3-Dimethyl-5-(phenylsulfanyl)oxolan-2-one 144500-38-9 C12H14O2S
    3,3-Dimethyl-5-(phenylsulfanyl)oxolan-2-one
    —— 4-cyano-4-thioethyl (1'-ethoxy) hepta-1,6-diene 135986-76-4 C12H19NOS
    4-cyano-4-thioethyl (1'-ethoxy) hepta-1,6-diene
    —— 1-Butylmercapto-2-phenylmercapto-propan 6839-05-0 C13H20S2
    1-Butylmercapto-2-phenylmercapto-propan
    —— 3-Methyl-1-methylsulfanylcyclopentene 70871-33-9 C7H12S
    3-Methyl-1-methylsulfanylcyclopentene
    —— 4-chlorobutyl 4,4,5,5,5-pentafluoropentyl sulphide 199730-57-9 C9H14ClF5S
    4-chlorobutyl 4,4,5,5,5-pentafluoropentyl sulphide
    —— 1,1,1,2,2-Pentafluoro-2-(2-iodo-ethylsulfanyl)-ethane 1206523-87-6 C4H4F5IS
    1,1,1,2,2-Pentafluoro-2-(2-iodo-ethylsulfanyl)-ethane
    —— 3-(2-Aminoethyl)thietane 1,1-dioxide 1352242-98-8 C5H11NO2S
    3-(2-Aminoethyl)thietane 1,1-dioxide
    —— 2,6-Anhydro-3-deoxy-L-erythro-hex-2-enonothioamide 136590-79-9 C6H9NO3S
    2,6-Anhydro-3-deoxy-L-erythro-hex-2-enonothioamide
    —— Dnlmctzrkphjfk-uhfffaoysa- 103698-11-9 C9H12N2O2S
    Dnlmctzrkphjfk-uhfffaoysa-
    —— (1S,4R,5S,6S)-5-chloro-6-phenylsulfanylbicyclo[2.2.1]hept-2-ene 71040-90-9 C13H13ClS
    (1S,4R,5S,6S)-5-chloro-6-phenylsulfanylbicyclo[2.2.1]hept-2-ene
    —— 2-ethanesulfonyl-1,1-dimethoxy-ethane 71185-74-5 C6H14O4S
    2-ethanesulfonyl-1,1-dimethoxy-ethane
    —— 1,1,1,3,3,3-Hexafluoro-2-[phenylsulfanyl(triphenylstannyl)methyl]propan-2-ol 147102-04-3 C28H22F6OSSn
    1,1,1,3,3,3-Hexafluoro-2-[phenylsulfanyl(triphenylstannyl)methyl]propan-2-ol
    —— 1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-87-9 C17H23ClO2S
    1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— 1-chloro-trans,cis-3,5-dimethyl-cis,cis-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-82-4 C17H23ClO2S
    1-chloro-trans,cis-3,5-dimethyl-cis,cis-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide 81939-88-0 C17H24O2S2
    cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide
    —— phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-4-O-(1-imino-1-trichloromethyl)-α-D-threo-hex-2-enopyranoside 177263-31-9 C20H28Cl3NO3SSi
    phenylthio-6-O-tert-butyldimethylsilyl-2,3-dideoxy-4-O-(1-imino-1-trichloromethyl)-α-D-threo-hex-2-enopyranoside
    —— (Z)-1-ethoxy-4-phenylthio-1-butene 124224-91-5 C12H16OS
    (Z)-1-ethoxy-4-phenylthio-1-butene
    —— (5-methylthio-1,3,4-thiadiazol-2-yl)methylamine 933693-22-2 C4H7N3S2
    (5-methylthio-1,3,4-thiadiazol-2-yl)methylamine
    —— 4-chloro-5H,6H,7H-pyrimido[4,5-b][1,4]thiazin-6-one 20015-70-7 C6H4ClN3OS
    4-chloro-5H,6H,7H-pyrimido[4,5-b][1,4]thiazin-6-one
    —— 2-isopropyl-2-methyl-propane-1,3-dithiol 56472-21-0 C7H16S2
    2-isopropyl-2-methyl-propane-1,3-dithiol
    —— 2-(1,1,1-Trifluoropropan-2-yl)propane-1,3-dithiol 130624-22-5 C6H11F3S2
    2-(1,1,1-Trifluoropropan-2-yl)propane-1,3-dithiol
    —— 3-Brom-exo-4-phenyl-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en 102870-52-0 C19H17BrS
    3-Brom-exo-4-phenyl-endo-6-(phenylthio)bicyclo<3.1.1>hept-2-en
    —— 3-Brom-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol 102870-53-1 C13H13BrOS
    3-Brom-endo-6-(phenylthio)bicyclo<3.1.1>hept-3-en-endo-2-ol