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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-amino-pentane-1-thiol; hydrochloride 31110-78-8 C5H13NS*ClH
    5-amino-pentane-1-thiol; hydrochloride
    —— Acetonitrile dimethylsulfoxide 90030-82-3 C4H9NOS
    Acetonitrile dimethylsulfoxide
    —— 5-[(3-methoxyphenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H,3H)-dione 216685-46-0 C29H28N2O3S2
    5-[(3-methoxyphenyl)thio]-3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)thieno[2,3-d]pyrimidine-2,4-(1H,3H)-dione
    —— 4-[(2-Fluorophenylthio)methyl]piperidine hydrochloride 614730-30-2 C12H16FNS*ClH
    4-[(2-Fluorophenylthio)methyl]piperidine hydrochloride
    —— 1,5-Di(ethenesulfonyl)pentan-3-ol 593024-20-5 C9H16O5S2
    1,5-Di(ethenesulfonyl)pentan-3-ol
    —— 5-Methoxy-2-methyl-6-phenylsulfanyl-benzothiazole-4,7-dione 650635-76-0 C15H11NO3S2
    5-Methoxy-2-methyl-6-phenylsulfanyl-benzothiazole-4,7-dione
    —— bis(4-vinylphenyl)sulfane 93013-00-4 C16H14S
    bis(4-vinylphenyl)sulfane
    —— 6-cyclohexyloxymethyl-2-methylsulfanyl-3H-pyrimidin-4-one 684220-55-1 C12H18N2O2S
    6-cyclohexyloxymethyl-2-methylsulfanyl-3H-pyrimidin-4-one
    —— 3,5-Dichloro-4-(5-trifluoromethyl-benzothiazol-2-ylsulfanyl)-phenylamine 315229-01-7 C14H7Cl2F3N2S2
    3,5-Dichloro-4-(5-trifluoromethyl-benzothiazol-2-ylsulfanyl)-phenylamine
    —— 1-hydroxy-3-(1-methyl-1<i>H</i>-tetrazol-5-ylsulfanyl)-propan-2-one 62284-48-4 C5H8N4O2S
    1-hydroxy-3-(1-methyl-1<i>H</i>-tetrazol-5-ylsulfanyl)-propan-2-one
    —— 2,2,2-trifluoro-N-[2-[4-[(4-hydroxyphenyl)thio]phenyl]ethyl]acetamide 643093-68-9 C16H14F3NO2S
    2,2,2-trifluoro-N-[2-[4-[(4-hydroxyphenyl)thio]phenyl]ethyl]acetamide
    —— 2,2,2-trifluoro-N-[2-[4-[(4-methoxyphenyl)thio]phenyl]ethyl]acetamide 643093-67-8 C17H16F3NO2S
    2,2,2-trifluoro-N-[2-[4-[(4-methoxyphenyl)thio]phenyl]ethyl]acetamide
    —— 2-(methylthio)-4-(pyridin-2-yl)pyrimidine 374081-38-6 C10H9N3S
    2-(methylthio)-4-(pyridin-2-yl)pyrimidine
    —— 2-(4-Amino-2,6-dichloro-phenylsulfanyl)-benzothiazole-5-carbonitrile 315228-43-4 C14H7Cl2N3S2
    2-(4-Amino-2,6-dichloro-phenylsulfanyl)-benzothiazole-5-carbonitrile
    —— 5-(Benzylsulfanyl)-N,N,1,3-tetramethyl-1H-pyrazole-4-sulfonamide 88398-95-2 C14H19N3O2S2
    5-(Benzylsulfanyl)-N,N,1,3-tetramethyl-1H-pyrazole-4-sulfonamide
    —— 3-Acetyl-5-methyl-1-[2-(1-methyltetrazol-5-ylthio)ethyl]pyrazole 165743-94-2 C10H14N6OS
    3-Acetyl-5-methyl-1-[2-(1-methyltetrazol-5-ylthio)ethyl]pyrazole
    —— 2-(4-Amino-2-chloro-phenylsulfanyl)-benzothiazole-6-carbonitrile 315228-42-3 C14H8ClN3S2
    2-(4-Amino-2-chloro-phenylsulfanyl)-benzothiazole-6-carbonitrile
    —— 3-Chloro-4-(5-trifluoromethyl-benzothiazol-2-ylsulfanyl)-phenyl amine 315228-97-8 C14H8ClF3N2S2
    3-Chloro-4-(5-trifluoromethyl-benzothiazol-2-ylsulfanyl)-phenyl amine
    —— 2-(4-Amino-2-chloro-phenylsulfanyl)-benzothiazole-5-carbonitrile 315228-44-5 C14H8ClN3S2
    2-(4-Amino-2-chloro-phenylsulfanyl)-benzothiazole-5-carbonitrile
    —— 2-(4-Amino-2,6-dichloro-phenylsulfanyl)-benzothiazole-6-carbonitrile 315228-41-2 C14H7Cl2N3S2
    2-(4-Amino-2,6-dichloro-phenylsulfanyl)-benzothiazole-6-carbonitrile
    —— 5-(3,5-dichlorophenylthio)-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1-(pyridin-3-yl)methyl-1H-imidazole 178981-84-5 C27H27Cl2N3O2S
    5-(3,5-dichlorophenylthio)-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1-(pyridin-3-yl)methyl-1H-imidazole
    —— 2,2'-{Sulfanediylbis[(pyridine-6,2-diyl)sulfanediyl]}bis{6-[(6-bromopyridin-2-yl)sulfanyl]pyridine} 142802-52-6 C30H18Br2N6S5
    2,2'-{Sulfanediylbis[(pyridine-6,2-diyl)sulfanediyl]}bis{6-[(6-bromopyridin-2-yl)sulfanyl]pyridine}
    —— 5-(3,5-dichlorophenylthio)-1-dodecyl-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1H-imidazole 178981-07-2 C33H46Cl2N2O2S
    5-(3,5-dichlorophenylthio)-1-dodecyl-4-isopropyl-2-(p-methoxybenzyloxymethyl)-1H-imidazole
    —— 6-methylsulfanyl-pyrazin-2-ylamine 3430-08-8 C5H7N3S
    6-methylsulfanyl-pyrazin-2-ylamine
    —— 2-(2-Azidoethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazole 178981-79-8 C15H17Cl2N5S
    2-(2-Azidoethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazole
    —— 2-azidomethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(2,2,2-trifluoroethyl)-1H-imidazole 178981-74-3 C15H14Cl2F3N5S
    2-azidomethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(2,2,2-trifluoroethyl)-1H-imidazole
    —— 1-acetylmethyl-2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole 178982-47-3 C23H24Cl2N2O2S
    1-acetylmethyl-2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole
    —— 3-AMINO-2-BROMO-5-METHYLTHIOPYRAZINE 250659-54-2 C5H6BrN3S
    3-AMINO-2-BROMO-5-METHYLTHIOPYRAZINE
    —— 2-azidomethyl-1-benzyl-5-(3,5-dichlorophenylthio)-4-isopropylimidazole 178981-69-6 C20H19Cl2N5S
    2-azidomethyl-1-benzyl-5-(3,5-dichlorophenylthio)-4-isopropylimidazole
    —— 2-(N-chloroacetylcarbamoyloxy)methyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(pyridin-3-yl)methyl-1H-imidazole 178981-86-7 C22H21Cl3N4O3S
    2-(N-chloroacetylcarbamoyloxy)methyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(pyridin-3-yl)methyl-1H-imidazole
    —— 2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(2-hydroxy-2-methylpropyl)-4-isopropyl-1H-imidazole 178982-51-9 C24H28Cl2N2O2S
    2-benzyloxymethyl-5-(3,5-dichlorophenylthio)-1-(2-hydroxy-2-methylpropyl)-4-isopropyl-1H-imidazole
    —— 4-methyl-5-methylsulfanyl-2,4-dihydro-[1,2,4]triazole-3-thione 62770-12-1 C4H7N3S2
    4-methyl-5-methylsulfanyl-2,4-dihydro-[1,2,4]triazole-3-thione
    —— 5-(4-chlorophenylamino)-1,3-dimethyl-4-(2-pyrimidylthio)pyrazole 152527-25-8 C15H14ClN5S
    5-(4-chlorophenylamino)-1,3-dimethyl-4-(2-pyrimidylthio)pyrazole
    —— 1-bromo-3-[(3-chloropropyl)sulfanyl]benzene 19433-04-6 C9H10BrClS
    1-bromo-3-[(3-chloropropyl)sulfanyl]benzene
    —— 1-Bromo-2-[(3-chloropropyl)sulfanyl]benzene 487058-85-5 C9H10BrClS
    1-Bromo-2-[(3-chloropropyl)sulfanyl]benzene
    —— 5,5-dimethoxy-1-(4,4,5,5,5-pentafluoropentylsulfinyl)pentane 252947-04-9 C12H21F5O3S
    5,5-dimethoxy-1-(4,4,5,5,5-pentafluoropentylsulfinyl)pentane
    —— 2-thioxo-cyclohexanecarboxylic acid 824934-63-6 C7H10O2S
    2-thioxo-cyclohexanecarboxylic acid
    —— 2-Bromo-5-(methylsulfanyl)furan 474710-68-4 C5H5BrOS
    2-Bromo-5-(methylsulfanyl)furan
    —— 2,6-bis(benzylthio)pyrimidine-4,5-diamine 415920-33-1 C18H18N4S2
    2,6-bis(benzylthio)pyrimidine-4,5-diamine
    —— [[4-amino-2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile 415920-38-6 C20H15Cl2F2N5S2
    [[4-amino-2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-5-pyrimidinyl]amino]acetonitrile
    —— 1,3-bis(4-hydroxyphenylthio)-2-hydroxypropane 95971-33-8 C15H16O3S2
    1,3-bis(4-hydroxyphenylthio)-2-hydroxypropane
    —— 2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-4,5-pyrimidinediamine 415920-37-5 C18H14Cl2F2N4S2
    2,6-bis[[(3-chloro-2-fluorophenyl)methyl]thio]-4,5-pyrimidinediamine
    —— tributyl[5-(methylsulfanyl)-furan-2-yl)stannane 474710-69-5 C17H32OSSn
    tributyl[5-(methylsulfanyl)-furan-2-yl)stannane
    —— Isopropyl-5-nitropyrid-2-yl-sulfid 573676-13-8 C8H10N2O2S
    Isopropyl-5-nitropyrid-2-yl-sulfid
    —— 2-Bromo-5-(3-chloropropylsulfanyl)thiophene 474710-73-1 C7H8BrClS2
    2-Bromo-5-(3-chloropropylsulfanyl)thiophene
    —— tributyl[5-(ethylsulfanyl)-thien-2-yl]stannane 474710-65-1 C18H34S2Sn
    tributyl[5-(ethylsulfanyl)-thien-2-yl]stannane
    —— N-[4-(4-methoxyphenylsulfanyl)phenyl]guanidine 827610-24-2 C14H15N3OS
    N-[4-(4-methoxyphenylsulfanyl)phenyl]guanidine
    —— [2-methylsulfanyl-6-(morpholin-4-yl)-pyrimidin-4-yl]-(5-methyl-1H-pyrazol-3-yl)-amine 1417340-73-8 C13H18N6OS
    [2-methylsulfanyl-6-(morpholin-4-yl)-pyrimidin-4-yl]-(5-methyl-1H-pyrazol-3-yl)-amine
    —— Trihexylsulfanium;bromide 469912-67-2 C18H39BrS
    Trihexylsulfanium;bromide
    —— 4-(3-Methylphenyl)-2-(4-methylsulfonylphenyl)-5-(2-phenylthio-4-pyridyl)-1,3-thiazole 303163-42-0 C28H22N2O2S3
    4-(3-Methylphenyl)-2-(4-methylsulfonylphenyl)-5-(2-phenylthio-4-pyridyl)-1,3-thiazole