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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3-(dimethylcarbamoyl)-4-(2-nitrophenylthio)phenoxy)propyl methanesulfonate 1004534-69-3 C19H22N2O7S2
    3-(3-(dimethylcarbamoyl)-4-(2-nitrophenylthio)phenoxy)propyl methanesulfonate
    —— 2-(4-bromo-2-nitrophenylthio)-5-(2-hydroxyethoxy)-N,N-dimethylbenzamide 1004535-03-8 C17H17BrN2O5S
    2-(4-bromo-2-nitrophenylthio)-5-(2-hydroxyethoxy)-N,N-dimethylbenzamide
    —— 2-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)ethyl methanesulfonate 1004535-15-2 C18H21FN2O6S2
    2-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)ethyl methanesulfonate
    —— 2-(2-((dimethylamino)methyl)-4-(3-fluoropropoxy)phenylthio)-5-fluorobenzenamine 1004534-81-9 C18H22F2N2OS
    2-(2-((dimethylamino)methyl)-4-(3-fluoropropoxy)phenylthio)-5-fluorobenzenamine
    —— 3-(4-(2-amino-4-bromophenylthio)-3-((dimethylamino)methyl)phenoxy)-1-propanol 1004534-99-9 C18H23BrN2O2S
    3-(4-(2-amino-4-bromophenylthio)-3-((dimethylamino)methyl)phenoxy)-1-propanol
    —— 2-(4-chloro-2-nitrophenylthio)-5-(2-hydroxyethoxy)-N,N-dimethylbenzamide 1004535-01-6 C17H17ClN2O5S
    2-(4-chloro-2-nitrophenylthio)-5-(2-hydroxyethoxy)-N,N-dimethylbenzamide
    —— 2-(4-bromo-2-nitrophenylthio)-5-methoxy-N,N-dimethylbenzamide 939022-00-1 C16H15BrN2O4S
    2-(4-bromo-2-nitrophenylthio)-5-methoxy-N,N-dimethylbenzamide
    —— 5-bromo-2-(2-((dimethylamino)methyl)-4-(3-fluoropropoxy)phenylthio)benzenamine 1004534-83-1 C18H22BrFN2OS
    5-bromo-2-(2-((dimethylamino)methyl)-4-(3-fluoropropoxy)phenylthio)benzenamine
    —— 3-(3-((dimethylamino)methyl)-4-(2-nitrophenylthio)phenoxy)propanol 1004535-21-0 C18H22N2O4S
    3-(3-((dimethylamino)methyl)-4-(2-nitrophenylthio)phenoxy)propanol
    —— 3-(3-(dimethylcarbamoyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propyl methanesulfonate 1004534-71-7 C19H21FN2O7S2
    3-(3-(dimethylcarbamoyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propyl methanesulfonate
    —— 3-(3-((dimethylamino)methyl)-4-(4-bromo-2-nitrophenylthio)phenoxy)propyl methanesulfonate 1004535-31-2 C19H23BrN2O6S2
    3-(3-((dimethylamino)methyl)-4-(4-bromo-2-nitrophenylthio)phenoxy)propyl methanesulfonate
    —— 3-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propanol 1004535-23-2 C18H21FN2O4S
    3-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propanol
    —— 2-(2-((dimethylamino)methyl)-4-(3[18F]-fluoropropoxy)phenylthio)benzenamine 1004534-16-0 C18H23FN2OS
    2-(2-((dimethylamino)methyl)-4-(3[18F]-fluoropropoxy)phenylthio)benzenamine
    —— 2-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)ethanol 1004535-07-2 C17H19FN2O4S
    2-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)ethanol
    —— 2-(2-((dimethylamino)methyl)-4-(methoxy)phenylthio)benzenamine 1004534-85-3 C16H20N2OS
    2-(2-((dimethylamino)methyl)-4-(methoxy)phenylthio)benzenamine
    —— 2-(4-(2-aminophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol 1004534-93-3 C17H22N2O2S
    2-(4-(2-aminophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol
    —— 2-(4-(4-bromo-2-nitrophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol 1004535-11-8 C17H19BrN2O4S
    2-(4-(4-bromo-2-nitrophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol
    —— 3-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propyl methanesulfonate 1004535-29-8 C19H23FN2O6S2
    3-(3-((dimethylamino)methyl)-4-(4-fluoro-2-nitrophenylthio)phenoxy)propyl methanesulfonate
    —— 2-(4-(4-chloro-2-nitrophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol 1004535-09-4 C17H19ClN2O4S
    2-(4-(4-chloro-2-nitrophenylthio)-3-((dimethylamino)methyl)phenoxy)ethanol
    —— O2-(2-methylsulfonylethyl) 1-(N-Boc-isopropylamino)-diazen-1-ium-1,2-diolate 1404220-35-4 C11H23N3O6S
    O2-(2-methylsulfonylethyl) 1-(N-Boc-isopropylamino)-diazen-1-ium-1,2-diolate
    —— Cyclohexyl 2-(4-thiomethylphenyl)ethyl ketone 898781-93-6 C16H22OS
    Cyclohexyl 2-(4-thiomethylphenyl)ethyl ketone
    —— Cyclopropyl 2-(4-thiomethylphenyl)ethyl ketone 898781-87-8 C13H16OS
    Cyclopropyl 2-(4-thiomethylphenyl)ethyl ketone
    —— N-[2-(2-chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethylidene]hydroxylamine 1404219-08-4 C12H8Cl3NOS2
    N-[2-(2-chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethylidene]hydroxylamine
    —— 2-Bromo-3-[(2-methylthio)phenyl]-1-propene 951889-15-9 C10H11BrS
    2-Bromo-3-[(2-methylthio)phenyl]-1-propene
    —— 2-Chloro-3-[(4-Ethylthio)phenyl]-1-propene 951890-63-4 C11H13ClS
    2-Chloro-3-[(4-Ethylthio)phenyl]-1-propene
    —— (2-amino-thiazol-5-ylsulfanyl)-acetic acid methyl ester 1017047-89-0 C6H8N2O2S2
    (2-amino-thiazol-5-ylsulfanyl)-acetic acid methyl ester
    —— 6-phenylsulfanylhex-3-en-2-one 1415577-49-9 C12H14OS
    6-phenylsulfanylhex-3-en-2-one
    —— 6-(Carboxymethyl)-3-propyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 1017422-92-2 C9H12N4O2S
    6-(Carboxymethyl)-3-propyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-Methyl-2-[(5-nitro-2-pyridinyl)sulfanyl]-propanoic acid 952183-12-9 C9H10N2O4S
    2-Methyl-2-[(5-nitro-2-pyridinyl)sulfanyl]-propanoic acid
    —— Hexatriacontyl carbamimidothioate;hydrobromide 7509-95-7 C37H77BrN2S
    Hexatriacontyl carbamimidothioate;hydrobromide
    —— 4-(Methoxymethyl)-6-[(4-methylbenzyl)sulfanyl]-2-phenylpyrimidine 939762-12-6 C19H18N2OS
    4-(Methoxymethyl)-6-[(4-methylbenzyl)sulfanyl]-2-phenylpyrimidine
    —— Bis(1-chlorocyclopropyl) sulfone 27531-51-7 C6H8Cl2O2S
    Bis(1-chlorocyclopropyl) sulfone
    —— 2-(Prop-2-en-1-ylsulfanyl)[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-amine 1011408-20-0 C7H8N6S
    2-(Prop-2-en-1-ylsulfanyl)[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-amine
    —— Dotriacontyl carbamimidothioate;hydrobromide 7461-14-5 C33H69BrN2S
    Dotriacontyl carbamimidothioate;hydrobromide
    —— 5,7-diamino-3-phenyl-2-(4-methoxyphenylthio)quinoxaline 1135231-22-9 C21H18N4OS
    5,7-diamino-3-phenyl-2-(4-methoxyphenylthio)quinoxaline
    —— 2-[(2-Methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol;hydrochloride 3610-56-8 C13H16ClN3OS
    2-[(2-Methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol;hydrochloride
    —— 2-(Pyridyl)-2-thiopseudourea, N-oxide 1126-15-4 C6H7BrN3OS-
    2-(Pyridyl)-2-thiopseudourea, N-oxide
    —— N-methyl-1-[4-methyl-3-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide —— C12H19IN2OS
    N-methyl-1-[4-methyl-3-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide
    —— N-methyl-1-[4-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide —— C11H17IN2OS
    N-methyl-1-[4-(trimethylazaniumyl)phenyl]sulfanylmethanimidate;hydroiodide
    —— Dimethyl(tricyclo[3.3.1.1~3,7~]decan-1-yl)sulfanium iodide 37818-84-1 C12H21IS
    Dimethyl(tricyclo[3.3.1.1~3,7~]decan-1-yl)sulfanium iodide
    —— 2-Amino-3-(methylsulfanylmethylsulfanyl)propan-1-ol;hydrochloride 61827-16-5 C5H14ClNOS2
    2-Amino-3-(methylsulfanylmethylsulfanyl)propan-1-ol;hydrochloride
    —— (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine;hydrochloride 2178-12-3 C20H24ClNS
    (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine;hydrochloride
    —— (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N-methylpropan-1-amine;hydrochloride 2178-07-6 C19H22ClNS
    (3E)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N-methylpropan-1-amine;hydrochloride
    —— 1,5,6-Trimethyl-3-(methylsulfanyl)-1,2,4-triazin-1-ium iodide 35102-18-2 C7H12IN3S
    1,5,6-Trimethyl-3-(methylsulfanyl)-1,2,4-triazin-1-ium iodide
    —— N-methyl-N-[methyl-(methylsulfonylmethylidene)-oxo-lambda6-sulfanyl]methanamine 38709-87-4 C5H13NO3S2
    N-methyl-N-[methyl-(methylsulfonylmethylidene)-oxo-lambda6-sulfanyl]methanamine
    —— 38709-81-8 C6H13NO2S
    —— (2,2-Dimethyl-1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)-trimethyl-ammonium; iodide 92658-16-7 C8H18NO2S*I
    (2,2-Dimethyl-1,1-dioxo-1λ<sup>6</sup>-thietan-3-yl)-trimethyl-ammonium; iodide
    —— 2-(1-Methoxyethyl)-N,N,N-trimethyl-1,1-dioxo-1lambda~6~-thietan-3-aminium iodide 17346-39-3 C9H20INO3S
    2-(1-Methoxyethyl)-N,N,N-trimethyl-1,1-dioxo-1lambda~6~-thietan-3-aminium iodide
    —— 3-(4-Aminophenyl)sulfanylpropanoic acid;hydrochloride 30086-22-7 C9H12ClNO2S
    3-(4-Aminophenyl)sulfanylpropanoic acid;hydrochloride
    —— Bis(2-aminoethylsulfanyl)methanone;hydrochloride 13889-99-1 C5H13ClN2OS2
    Bis(2-aminoethylsulfanyl)methanone;hydrochloride