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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl 9,9-ethylenedithio-5-methyl-4-oxadispiro(5.5)undecane-1-carboxylate 108643-44-3 C16H24O3S2
    methyl 9,9-ethylenedithio-5-methyl-4-oxadispiro(5.5)undecane-1-carboxylate
    —— 2-phenylsulfanylmethylene-malonic acid diethyl ester 72798-17-5 C14H16O4S
    2-phenylsulfanylmethylene-malonic acid diethyl ester
    —— Ethyl 3-[3-amino-5-[(4-chlorophenyl)methylsulfanyl]-4-cyanothiophen-2-yl]-3-oxopropanoate 1043384-27-5 C17H15ClN2O3S2
    Ethyl 3-[3-amino-5-[(4-chlorophenyl)methylsulfanyl]-4-cyanothiophen-2-yl]-3-oxopropanoate
    —— 10,10-ethylenedithio-3,3,13-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione 66607-10-1 C19H26O5S2
    10,10-ethylenedithio-3,3,13-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione
    —— N-[1-(Phenylsulfanyl)-3-(trimethylsilyl)prop-2-yn-1-yl]aniline 90261-26-0 C18H21NSSi
    N-[1-(Phenylsulfanyl)-3-(trimethylsilyl)prop-2-yn-1-yl]aniline
    —— 2-methyl-6-methylthiopyrimidine-4-thiol 88317-62-8 C6H8N2S2
    2-methyl-6-methylthiopyrimidine-4-thiol
    —— N,N-dimethyl-2<5'-(pyridin-4''-yl)-1',3',4'-oxadiazol-2'-ylthio>ethylamine 88317-55-9 C11H14N4OS
    N,N-dimethyl-2<5'-(pyridin-4''-yl)-1',3',4'-oxadiazol-2'-ylthio>ethylamine
    —— ethyl 4-methylthio-3-phenyl-2-thioxo-2,3-dihydro-1,3-oxazole-5-carboxylate 153648-49-8 C13H13NO3S2
    ethyl 4-methylthio-3-phenyl-2-thioxo-2,3-dihydro-1,3-oxazole-5-carboxylate
    —— Ethyl 3-[3-amino-4-cyano-5-[(4-methylphenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate 1043384-47-9 C18H18N2O3S2
    Ethyl 3-[3-amino-4-cyano-5-[(4-methylphenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate
    —— (1-Phenylsulfanyl-3-trimethylsilanyl-prop-2-ynyl)-o-tolyl-amine 90261-27-1 C19H23NSSi
    (1-Phenylsulfanyl-3-trimethylsilanyl-prop-2-ynyl)-o-tolyl-amine
    —— Ethyl 3-{3-amino-5-[(4-bromobenzyl)sulfanyl]-4-cyanothiophen-2-yl}-3-oxopropanoate 1043384-22-0 C17H15BrN2O3S2
    Ethyl 3-{3-amino-5-[(4-bromobenzyl)sulfanyl]-4-cyanothiophen-2-yl}-3-oxopropanoate
    —— 5-Phenyl-3-phenylsulfanylpentan-2-one 111036-67-0 C17H18OS
    5-Phenyl-3-phenylsulfanylpentan-2-one
    —— Ethyl 3-[3-amino-4-cyano-5-[(4-fluorophenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate 1043384-57-1 C17H15FN2O3S2
    Ethyl 3-[3-amino-4-cyano-5-[(4-fluorophenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate
    —— 4-methanesulfonyl-butyryl chloride 631910-85-5 C5H9ClO3S
    4-methanesulfonyl-butyryl chloride
    —— 1-phenyl-4,4-propylenedithio-3-pentanol 126884-76-2 C14H20OS2
    1-phenyl-4,4-propylenedithio-3-pentanol
    —— 4,4,7,7-Tetramethyl-2,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,8-dien 83569-35-1 C21H22N2S2
    4,4,7,7-Tetramethyl-2,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,8-dien
    —— 2,2,7,7-Tetramethyl-4,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-3,8-dien 84938-38-5 C21H22N2S2
    2,2,7,7-Tetramethyl-4,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-3,8-dien
    —— 2-cyano-3-(5-(4-chlorphenyl)thio-2-thienyl)acrylonitrile 76100-19-1 C14H7ClN2S2
    2-cyano-3-(5-(4-chlorphenyl)thio-2-thienyl)acrylonitrile
    —— 4,4,9,9-Tetramethyl-2,7-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,7-dien 52755-69-8 C21H22N2S2
    4,4,9,9-Tetramethyl-2,7-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,7-dien
    —— 1-Methyl-5-phenylthio-2-pyrrolecarboxaldehyde 94008-38-5 C12H11NOS
    1-Methyl-5-phenylthio-2-pyrrolecarboxaldehyde
    —— 2-[4-[S-(N-ethylcarbamoyl)thio]pheny]-5,5-dimethyl-1,3-dioxane 251989-46-5 C15H21NO3S
    2-[4-[S-(N-ethylcarbamoyl)thio]pheny]-5,5-dimethyl-1,3-dioxane
    —— (Z)-2-(2-(pyridin-4-yl)vinylthio)aniline 1088706-79-9 C13H12N2S
    (Z)-2-(2-(pyridin-4-yl)vinylthio)aniline
    —— 5,5-dimethyl-2-(4-methylsulfanylphenyl)-1,3-dioxane 251989-43-2 C13H18O2S
    5,5-dimethyl-2-(4-methylsulfanylphenyl)-1,3-dioxane
    —— 2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylonitrile 94033-70-2 C15H11N3S
    2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylonitrile
    —— 6-(4-methylsulfanylphenyl)-3,4-dihydro-2H-pyran 1041009-21-5 C12H14OS
    6-(4-methylsulfanylphenyl)-3,4-dihydro-2H-pyran
    —— (R)-1-(3-amino-4-(phenylthio)butyl)piperidin-4-yl di-tert-butyl phosphate 1619923-56-6 C23H41N2O4PS
    (R)-1-(3-amino-4-(phenylthio)butyl)piperidin-4-yl di-tert-butyl phosphate
    —— 2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylic acid methyl ester 94008-41-0 C16H14N2O2S
    2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylic acid methyl ester
    —— (1,1,3,3-tetramethyl-butyl)-thiourea 90228-54-9 C9H20N2S
    (1,1,3,3-tetramethyl-butyl)-thiourea
    —— <i>N</i>,<i>N</i>-dimethyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea 86375-37-3 C11H24N2S
    <i>N</i>,<i>N</i>-dimethyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— <i>N</i>-<i>tert</i>-butyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea 100799-06-2 C13H28N2S
    <i>N</i>-<i>tert</i>-butyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— <i>N</i>-isopropyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea 69330-77-4 C12H26N2S
    <i>N</i>-isopropyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— <i>N</i>,<i>N</i>'-bis-(1,1,3,3-tetramethyl-butyl)-thiourea 6959-72-4 C17H36N2S
    <i>N</i>,<i>N</i>'-bis-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— N,N-Diethyl-dithiooxamid 60359-13-9 C6H12N2S2
    N,N-Diethyl-dithiooxamid
    —— Methyl 3-ethoxy-2,2-dimethyl-4-(phenylsulfanyl)butanoate 89113-83-7 C15H22O3S
    Methyl 3-ethoxy-2,2-dimethyl-4-(phenylsulfanyl)butanoate
    —— 2,5-Diamino-6-benzylthio-4-methylpyrimidine 90072-38-1 C12H14N4S
    2,5-Diamino-6-benzylthio-4-methylpyrimidine
    —— (2-amino-ethyl)-octyl-dithiocarbamic acid 88240-40-8 C11H24N2S2
    (2-amino-ethyl)-octyl-dithiocarbamic acid
    —— 2-cyano-3-(5-phenylthio-2-thienyl)acrylonitrile 76100-13-5 C14H8N2S2
    2-cyano-3-(5-phenylthio-2-thienyl)acrylonitrile
    —— 2-(Phenylthio)cyclohexen-1-essigsaeure 37457-06-0 C14H16O2S
    2-(Phenylthio)cyclohexen-1-essigsaeure
    —— {[4-Bromo-5-(pyrimidin-2-ylsulfanyl)furan-2-yl]methylidene}propanedinitrile 93362-36-8 C12H5BrN4OS
    {[4-Bromo-5-(pyrimidin-2-ylsulfanyl)furan-2-yl]methylidene}propanedinitrile
    —— trans-4,5-dimethyl-1,3-dioxolane-2-thione 66841-50-7 C5H8O2S
    trans-4,5-dimethyl-1,3-dioxolane-2-thione
    —— 1-Methyl-4-{2-[(4-methylphenyl)sulfanyl]ethyl}pyridin-1-ium iodide 90158-95-5 C15H18NS*I
    1-Methyl-4-{2-[(4-methylphenyl)sulfanyl]ethyl}pyridin-1-ium iodide
    —— 1-(2-phenylthioethyl)-2-methylene-6,6-dimethylcyclohexane 84078-60-4 C17H24S
    1-(2-phenylthioethyl)-2-methylene-6,6-dimethylcyclohexane
    —— O-(n-Butyl)-S-(n-butyl)thiocarbonat 115347-45-0 C9H18O2S
    O-(n-Butyl)-S-(n-butyl)thiocarbonat
    —— 3-butylsulfonylprop-2-en-1-ol 101684-22-4 C7H14O3S
    3-butylsulfonylprop-2-en-1-ol
    —— 4,5-(diethoxyphosphorylmethylene)dithio-1,3-dithiol-2-one 172949-11-0 C8H11O4PS4
    4,5-(diethoxyphosphorylmethylene)dithio-1,3-dithiol-2-one
    —— (3-methyl-1-nitrobutan-2-yl)(p-tolyl)sulfide 1131454-38-0 C12H17NO2S
    (3-methyl-1-nitrobutan-2-yl)(p-tolyl)sulfide
    —— 4-methylthio-6-phenyl-2-oxo-2H-pyran-3-carboxamide 114361-63-6 C13H11NO3S
    4-methylthio-6-phenyl-2-oxo-2H-pyran-3-carboxamide
    —— 2-Chloro-3-(phenylsulfanyl)oxane 89113-95-1 C11H13ClOS
    2-Chloro-3-(phenylsulfanyl)oxane
    —— 4-(N,N'-bis(4-chlorophenyl))guanidino-2-methyl-5-methylthio-2H-1,2,4-triazol-3(4H)-one 116088-21-2 C17H16Cl2N6OS
    4-(N,N'-bis(4-chlorophenyl))guanidino-2-methyl-5-methylthio-2H-1,2,4-triazol-3(4H)-one
    —— 4-benzylamino-7-(1-methylethyl)-2-(methylsulfanyl)imidazo[2,1-f]-1,2,4-triazine 1099104-74-1 C16H19N5S
    4-benzylamino-7-(1-methylethyl)-2-(methylsulfanyl)imidazo[2,1-f]-1,2,4-triazine