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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— p-tolyl 2,3-anhydro-1-thio-β-D-gulofuranoside 920267-59-0 C13H16O4S
    p-tolyl 2,3-anhydro-1-thio-β-D-gulofuranoside
    —— 1,10-bis-carbamimidoylmercapto-decane 2986-39-2 C12H26N4S2
    1,10-bis-carbamimidoylmercapto-decane
    —— 3-Methyl-2-butenyl methanethiolsulfonate 55055-72-6 C6H12O2S2
    3-Methyl-2-butenyl methanethiolsulfonate
    —— 5-((4-bromobenzyl)thio)-1,3,4-thiadiazol-2-amine 332110-07-3 C9H8BrN3S2
    5-((4-bromobenzyl)thio)-1,3,4-thiadiazol-2-amine
    —— Dimethylcarbamyl diethylthiocarbamyl sulfide 69654-93-9 C8H16N2OS2
    Dimethylcarbamyl diethylthiocarbamyl sulfide
    —— 3-(phenylthio)-9-oxobicyclo<3.3.1>non-2-ene 90838-49-6 C15H16OS
    3-(phenylthio)-9-oxobicyclo<3.3.1>non-2-ene
    —— 5,6-bis(phenylsulfanyl)acenaphthene 1365421-54-0 C24H18S2
    5,6-bis(phenylsulfanyl)acenaphthene
    —— 2,4-diamino-6<<3-(trifluoromethyl)phenyl>thio>thieno<2,3-d>pyrimidin 130750-43-5 C13H9F3N4S2
    2,4-diamino-6<<3-(trifluoromethyl)phenyl>thio>thieno<2,3-d>pyrimidin
    —— (4-Chloro-3,3-dimethyl-2-methylsulfanylcyclopenten-1-yl)sulfanylbenzene 335343-25-4 C14H17ClS2
    (4-Chloro-3,3-dimethyl-2-methylsulfanylcyclopenten-1-yl)sulfanylbenzene
    —— 2-(3-methyl-2-butenylthio)-4-amino-1H-pyrimidin-6-one 847180-04-5 C9H13N3OS
    2-(3-methyl-2-butenylthio)-4-amino-1H-pyrimidin-6-one
    —— (5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-(4-fluoro-phenyl)-amine 73311-01-0 C10H10FN3S2
    (5-ethylsulfanyl-[1,3,4]thiadiazol-2-yl)-(4-fluoro-phenyl)-amine
    —— bis(pyrrolo-[3,4-d])tetrathiafulvalene 125113-35-1 C10H6N2S4
    bis(pyrrolo-[3,4-d])tetrathiafulvalene
    —— 2-isopropylidene-1,3-dithiolo<4,5-d>-1,3-dithiol-2-one 144000-05-5 C7H6OS4
    2-isopropylidene-1,3-dithiolo<4,5-d>-1,3-dithiol-2-one
    —— dibenzo<d,g><1,3,6>trithiocin 12-oxide 175696-16-9 C13H10OS3
    dibenzo<d,g><1,3,6>trithiocin 12-oxide
    —— cis/trans-3-isopropenyl-2-phenylthiocyclopentan-1-one 137380-55-3 C14H16OS
    cis/trans-3-isopropenyl-2-phenylthiocyclopentan-1-one
    —— (4-Chloro-5,5-dimethyl-2-methylsulfanylcyclopenten-1-yl)sulfanylbenzene 335343-24-3 C14H17ClS2
    (4-Chloro-5,5-dimethyl-2-methylsulfanylcyclopenten-1-yl)sulfanylbenzene
    —— dimethyl benzotetrathiafulvalene-1,2-dicarboxylate 62921-53-3 C14H10O4S4
    dimethyl benzotetrathiafulvalene-1,2-dicarboxylate
    —— 2,2'-Bi-1,3-benzodithiol 61666-73-7 C14H10S4
    2,2'-Bi-1,3-benzodithiol
    —— 2-methyl-2-(methylthio)-1,3-benzo-dithiolate 90703-72-3 C9H10S3
    2-methyl-2-(methylthio)-1,3-benzo-dithiolate
    —— cyclopentanylidiene-1,3-dithiolo<4,5-d>-1,3-dithiol-2-one 148256-86-4 C9H8OS4
    cyclopentanylidiene-1,3-dithiolo<4,5-d>-1,3-dithiol-2-one
    —— <1-(Trimethylsilyl)cyclopropyl>methyl Sulfone 91606-50-7 C14H30O2SSi2
    <1-(Trimethylsilyl)cyclopropyl>methyl Sulfone
    —— 4-(2-methyl-furan-3-ylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester 631909-70-1 C11H9NO5S2
    4-(2-methyl-furan-3-ylsulfanyl)-5-nitro-thiophene-2-carboxylic acid methyl ester
    —— 2-(1,3-benzodithiol-2-ylidene)-5H-[1,3]dithiolo[4,5-c]pyrrole 1215267-03-0 C12H7NS4
    2-(1,3-benzodithiol-2-ylidene)-5H-[1,3]dithiolo[4,5-c]pyrrole
    —— [5-(4-fluoro-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid 68161-36-4 C10H8FN3O2S2
    [5-(4-fluoro-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid
    —— 2-methyl-3-phenylthio-6,10-dithiaspiro<4.5>dec-2-en-1-one 88791-32-6 C15H16OS3
    2-methyl-3-phenylthio-6,10-dithiaspiro<4.5>dec-2-en-1-one
    —— 1-amino-3-(2-chloro-phenylsulfanyl)-propan-2-ol 35550-45-9 C9H12ClNOS
    1-amino-3-(2-chloro-phenylsulfanyl)-propan-2-ol
    —— (R)-tert-butyldimethylsiloxy(2-pyridyl)methyl 4-methylpheny sulfide 161151-92-4 C19H27NOSSi
    (R)-tert-butyldimethylsiloxy(2-pyridyl)methyl 4-methylpheny sulfide
    —— 2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-furan 89863-49-0 C18H11F13O3S2
    2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-furan
    —— 2-(2-(2-chlorophenylthio)-3-(trimethylsilyl)propyl)cyclohexanone 1046204-46-9 C18H27ClOSSi
    2-(2-(2-chlorophenylthio)-3-(trimethylsilyl)propyl)cyclohexanone
    —— 13-phenyl-5<i>H</i>,11<i>H</i>-5,11-epiazano-[1,5]dithiocino[2,3-<i>b</i>;6,7-<i>b</i>']dipyridine 72397-25-2 C18H13N3S2
    13-phenyl-5<i>H</i>,11<i>H</i>-5,11-epiazano-[1,5]dithiocino[2,3-<i>b</i>;6,7-<i>b</i>']dipyridine
    —— 5-ethylthio-3-phenyl-1,2,3,4-oxatriazolium ion 60078-21-9 C9H10N3OS
    5-ethylthio-3-phenyl-1,2,3,4-oxatriazolium ion
    —— 3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-6-methylsulfanylimidazo[2,1-f ][1,2,4]triazine 1097624-35-5 C24H28N4OSSi
    3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-6-methylsulfanylimidazo[2,1-f ][1,2,4]triazine
    —— (2-chlorophenyl)(cyclohexyl)sulfane 1610363-64-8 C12H15ClS
    (2-chlorophenyl)(cyclohexyl)sulfane
    —— bis<2-<(6-aminohexyl)oxy>ethyl> disulfide 108296-15-7 C16H36N2O2S2
    bis<2-<(6-aminohexyl)oxy>ethyl> disulfide
    —— 2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-thiophene 89863-48-9 C18H11F13O2S3
    2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-thiophene
    —— 1-Methyl-4-[1-phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-benzene 89863-50-3 C21H15F13O2S2
    1-Methyl-4-[1-phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-benzene
    —— 1-phenyl-1-phenylthio-1-trimethylsilylethane 77815-44-2 C17H22SSi
    1-phenyl-1-phenylthio-1-trimethylsilylethane
    —— bis(2-methyl-6-methylthiopyrimidin-4-yl) disulfide 88317-69-5 C12H14N4S4
    bis(2-methyl-6-methylthiopyrimidin-4-yl) disulfide
    —— N-[2-chloro-4-(4-mesylaminophenylsulphanyl)phenyl]-2-hydroxy-2-methylpropanamide 252016-97-0 C17H19ClN2O4S2
    N-[2-chloro-4-(4-mesylaminophenylsulphanyl)phenyl]-2-hydroxy-2-methylpropanamide
    —— 1-Cyclohexyl-4-[1-[4-(4-methoxyphenyl)sulfanylphenyl]ethyl]piperazine 182135-90-6 C25H34N2OS
    1-Cyclohexyl-4-[1-[4-(4-methoxyphenyl)sulfanylphenyl]ethyl]piperazine
    —— N-Carbamothioyl-2-cyclopentylacetamide 572923-99-0 C8H14N2OS
    N-Carbamothioyl-2-cyclopentylacetamide
    —— (2S)-2-[(4R,6R)-6-[(2R,3R)-3-[2-[(Z,3S,5R,7S,10R)-10-[[tert-butyl(diphenyl)silyl]oxymethyl]-7-hydroxy-5-methoxy-3-(methoxymethoxy)-2,8-dimethyldodec-8-en-2-yl]-1,3-dithian-2-yl]-3-hydroxy-2-methoxypropyl]-2,2-dimethyl-1,3-dioxan-4-yl]-2-(2-trimethylsilylethoxymethoxy)acetic acid 1092070-91-1 C56H94O13S2Si2
    (2S)-2-[(4R,6R)-6-[(2R,3R)-3-[2-[(Z,3S,5R,7S,10R)-10-[[tert-butyl(diphenyl)silyl]oxymethyl]-7-hydroxy-5-methoxy-3-(methoxymethoxy)-2,8-dimethyldodec-8-en-2-yl]-1,3-dithian-2-yl]-3-hydroxy-2-methoxypropyl]-2,2-dimethyl-1,3-dioxan-4-yl]-2-(2-trimethylsilylethoxymethoxy)acetic acid
    —— (R)-2-phenyl-2-(phenylthio)acetic acid 13136-48-6 C14H12O2S
    (R)-2-phenyl-2-(phenylthio)acetic acid
    —— isopropylidene 1,4-dithiaspiro<4.5>decan-8-ylidene malonate 66607-07-6 C14H18O4S2
    isopropylidene 1,4-dithiaspiro<4.5>decan-8-ylidene malonate
    —— (S)-2-phenyl-2-(phenylthio)acetic acid 321038-73-7 C14H12O2S
    (S)-2-phenyl-2-(phenylthio)acetic acid
    —— 4-phenyl-4-(phenylthio)-1-butene 21213-27-4 C16H16S
    4-phenyl-4-(phenylthio)-1-butene
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[2-(trifluoromethyl)phenyl]thio}aniline 1100794-92-0 C21H25ClF3N3S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[2-(trifluoromethyl)phenyl]thio}aniline
    —— 1-isothiocyanatohex-2-yne 17620-80-3 C7H9NS
    1-isothiocyanatohex-2-yne
    —— 10,10-ethylenedithio-3,3,16-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,15-trione 66607-11-2 C19H26O5S2
    10,10-ethylenedithio-3,3,16-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,15-trione
    —— ethyl-5-(3-methyl-4-nitropyrazolyl)sulphide 76143-55-0 C6H9N3O2S
    ethyl-5-(3-methyl-4-nitropyrazolyl)sulphide