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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5-benzooxazol-2-ylsulfanyl-furan-2-ylmethylene)-malononitrile 65807-36-5 C15H7N3O2S
    (5-benzooxazol-2-ylsulfanyl-furan-2-ylmethylene)-malononitrile
    —— 5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl stearoylcarbamate 196406-14-1 C38H54Cl2N4O3S
    5-(3,5-Dichlorophenylthio)-4-isopropyl-1-(pyridin-4-ylmethyl)-1H-imidazol-2-ylmethyl stearoylcarbamate
    —— 1-(phenylsulfonyl)-3-(phenylthio)indole 80360-18-5 C20H15NO2S2
    1-(phenylsulfonyl)-3-(phenylthio)indole
    —— 5-benzooxazol-2-ylsulfanyl-furan-2-carbaldehyde 57590-86-0 C12H7NO3S
    5-benzooxazol-2-ylsulfanyl-furan-2-carbaldehyde
    —— phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-2-oxo-1-thio-α-L-rhamnopyranoside 400737-65-7 C19H30O4SSi
    phenyl 3-O-tert-butyldimethylsilyl-4-O-methyl-2-oxo-1-thio-α-L-rhamnopyranoside
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)acetaldehyde 482661-87-0 C10H10N2OS
    2-(3-cyano-4,6-dimethylpyridin-2-yl)acetaldehyde
    —— 2-(1-methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzonitrile 756839-31-3 C15H10FN3S
    2-(1-methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzonitrile
    —— 4-Methyl-2-{[(pyridin-3-yl)methyl]sulfanyl}pyrimidine 88579-41-3 C11H11N3S
    4-Methyl-2-{[(pyridin-3-yl)methyl]sulfanyl}pyrimidine
    —— 5-benzothiazol-2-ylsulfanyl-furan-2-carbaldehyde 39689-07-1 C12H7NO2S2
    5-benzothiazol-2-ylsulfanyl-furan-2-carbaldehyde
    —— lead(II) bis(2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl trithiocarbonate) 202465-46-1 C62H134PbS6Si14
    lead(II) bis(2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl trithiocarbonate)
    —— 1-bromo-2-[2-[2-(2-bromoethylthio)ethylthio]ethylthio]ethane 89595-63-1 C8H16Br2S3
    1-bromo-2-[2-[2-(2-bromoethylthio)ethylthio]ethylthio]ethane
    —— S-(5-Chloropentyl) diethylcarbamothioate 86433-28-5 C10H20ClNOS
    S-(5-Chloropentyl) diethylcarbamothioate
    —— Aethylnonafluor-butylsulfon 71561-60-9 C6H5F9O2S
    Aethylnonafluor-butylsulfon
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-5-[[2-(dimethylamino)ethyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol 666752-74-5 C18H24F2N4O2S2
    2-[[(2,3-difluorophenyl)methyl]thio]-5-[[2-(dimethylamino)ethyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl] amino]-4-pyrimidinol
    —— N,N-dimethyl-2-(5-phenyl-1,2,4-triazin-3-ylthio)-ethanamine 1222866-77-4 C13H16N4S
    N,N-dimethyl-2-(5-phenyl-1,2,4-triazin-3-ylthio)-ethanamine
    —— Dimethyl {[(5-nitropyridin-2-yl)sulfanyl]methylidene}propanedioate 88716-75-0 C11H10N2O6S
    Dimethyl {[(5-nitropyridin-2-yl)sulfanyl]methylidene}propanedioate
    —— 6-(2-dimethylaminoethylthio)imidazo[1,2-b]pyridazine 113501-26-1 C10H14N4S
    6-(2-dimethylaminoethylthio)imidazo[1,2-b]pyridazine
    —— N-(2-tert-butoxy-ethyl)-thioacetamide 786686-53-1 C8H17NOS
    N-(2-tert-butoxy-ethyl)-thioacetamide
    —— 4-Chlor-2-nitro-5-phenylthio-anilin 20066-71-1 C12H9ClN2O2S
    4-Chlor-2-nitro-5-phenylthio-anilin
    —— {[(1-Methyl-1H-imidazol-2-yl)sulfanyl]methylidene}propanedinitrile 88716-82-9 C8H6N4S
    {[(1-Methyl-1H-imidazol-2-yl)sulfanyl]methylidene}propanedinitrile
    —— 1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane 127705-80-0 C11H12O3S
    1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane
    —— 1-(pivaloyloxy)-1-(phenylthio)cyclopropane 127705-78-6 C14H18O2S
    1-(pivaloyloxy)-1-(phenylthio)cyclopropane
    —— 1-(ethoxycarbonyloxy)-1-(phenylthio)cyclopropane 127705-81-1 C12H14O3S
    1-(ethoxycarbonyloxy)-1-(phenylthio)cyclopropane
    —— 1-(3-chlorophenyl)-3-ethyl-5-methoxy-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dithione 1636169-89-5 C16H15ClN4OS3
    1-(3-chlorophenyl)-3-ethyl-5-methoxy-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dithione
    —— 3-(2-amino-2-methylpropylthio)-6-chloropyridazine 89514-64-7 C8H12ClN3S
    3-(2-amino-2-methylpropylthio)-6-chloropyridazine
    —— 1-(phenylthio)-1-(propanoyloxy)cyclopropane 127705-76-4 C12H14O2S
    1-(phenylthio)-1-(propanoyloxy)cyclopropane
    —— 1-(isobutyryloxy)-1-(phenylthio)cyclopropane 127705-77-5 C13H16O2S
    1-(isobutyryloxy)-1-(phenylthio)cyclopropane
    —— (2-methylbut-3-en-2-ylsulfonyl)cyclohexane 1335133-90-8 C11H20O2S
    (2-methylbut-3-en-2-ylsulfonyl)cyclohexane
    —— S-(4-Chlorobutyl) diethylcarbamothioate 86433-27-4 C9H18ClNOS
    S-(4-Chlorobutyl) diethylcarbamothioate
    —— 5-methyl-5,6-dihydro-[1,4]dithiine-2,3-dicarbonitrile 56342-49-5 C7H6N2S2
    5-methyl-5,6-dihydro-[1,4]dithiine-2,3-dicarbonitrile
    —— 2-amino-ethanethiosulfonic acid <i>S</i>-(2-amino-ethyl ester) 2458-50-6 C4H12N2O2S2
    2-amino-ethanethiosulfonic acid <i>S</i>-(2-amino-ethyl ester)
    —— 3-ethyl-5-methoxy-7-methylsulfanyl-1-phenyl-4-thioxo-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one 1636170-01-8 C16H16N4O2S2
    3-ethyl-5-methoxy-7-methylsulfanyl-1-phenyl-4-thioxo-3,4-dihydropyrimido[4,5-d]pyrimidin-2(1H)-one
    —— Dimethyl {[(3-nitropyridin-2-yl)sulfanyl]methylidene}propanedioate 88716-76-1 C11H10N2O6S
    Dimethyl {[(3-nitropyridin-2-yl)sulfanyl]methylidene}propanedioate
    —— 1-phenyl-3-(phenylthio)propan-2-one 69798-70-5 C15H14OS
    1-phenyl-3-(phenylthio)propan-2-one
    —— S-(6-Chlorohexyl) diethylcarbamothioate 86433-29-6 C11H22ClNOS
    S-(6-Chlorohexyl) diethylcarbamothioate
    —— {[(Pyridin-2-yl)sulfanyl]methylidene}propanedinitrile 88716-72-7 C9H5N3S
    {[(Pyridin-2-yl)sulfanyl]methylidene}propanedinitrile
    —— 1-(o-tolylthio)propan-2-one 112091-20-0 C10H12OS
    1-(o-tolylthio)propan-2-one
    —— 2-(2-Aminomethyl-phenylsulfanyl)-5-methyl-phenylamine 850662-97-4 C14H16N2S
    2-(2-Aminomethyl-phenylsulfanyl)-5-methyl-phenylamine
    —— S-(8-Chlorooctyl) diethylcarbamothioate 90012-04-7 C13H26ClNOS
    S-(8-Chlorooctyl) diethylcarbamothioate
    —— 1-(4-bromo-phenylsulfanyl)-3,5-difluoro-benzene 1451093-07-4 C12H7BrF2S
    1-(4-bromo-phenylsulfanyl)-3,5-difluoro-benzene
    —— S-(1-chlorobutyl) butanesulphonothioate 90466-86-7 C8H17ClO2S2
    S-(1-chlorobutyl) butanesulphonothioate
    —— bis(isocyanatomethylthio)methane 149683-01-2 C5H6N2O2S2
    bis(isocyanatomethylthio)methane
    —— (3,4-dichloro-benzyl)-phenyl sulfide 102871-56-7 C13H10Cl2S
    (3,4-dichloro-benzyl)-phenyl sulfide
    —— {[(Hexyloxy)methyl]sulfanyl}benzene 90280-90-3 C13H20OS
    {[(Hexyloxy)methyl]sulfanyl}benzene
    —— 1,3-bis(2-chloroethylthio)-n-propane 63905-10-2 C7H14Cl2S2
    1,3-bis(2-chloroethylthio)-n-propane
    —— {[(Pyrimidin-2-yl)sulfanyl]methylidene}propanedinitrile 88716-78-3 C8H4N4S
    {[(Pyrimidin-2-yl)sulfanyl]methylidene}propanedinitrile
    —— bis-(1-chloro-vinyl) sulfoxide 17911-99-8 C4H4Cl2OS
    bis-(1-chloro-vinyl) sulfoxide
    —— {[(5-Nitropyridin-2-yl)sulfanyl]methylidene}propanedinitrile 88716-74-9 C9H4N4O2S
    {[(5-Nitropyridin-2-yl)sulfanyl]methylidene}propanedinitrile
    —— <i>N'</i>-[5-chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine 71753-64-5 C17H20Cl2N2S
    <i>N'</i>-[5-chloro-2-(4-chloro-phenylsulfanyl)-phenyl]-<i>N,N</i>-dimethyl-propanediyldiamine
    —— (Z)-[3-methyl-1-(octylthio)but-1-en-2-yl](p-tolyl)sulfane 1360053-29-7 C20H32S2
    (Z)-[3-methyl-1-(octylthio)but-1-en-2-yl](p-tolyl)sulfane