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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (<i>R</i>)-2,3-dimercapto-propan-1-ol 16495-08-2 C3H8OS2
    (<i>R</i>)-2,3-dimercapto-propan-1-ol
    —— 9-(3-(isopropylamino)propyl)-8-(6-(1-methyl-1H-pyrazol-5-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine 1289543-90-3 C22H26N8O2S
    9-(3-(isopropylamino)propyl)-8-(6-(1-methyl-1H-pyrazol-5-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine
    —— 4-Chloro-1-(4-fluoro-phenylsulfanyl)-2-nitro-benzene 89733-03-9 C12H7ClFNO2S
    4-Chloro-1-(4-fluoro-phenylsulfanyl)-2-nitro-benzene
    —— 2-Chloro-3-(2'-chloro)benzylthiopyridine 129836-63-1 C12H9Cl2NS
    2-Chloro-3-(2'-chloro)benzylthiopyridine
    —— 5-(4-Fluoro-phenyl)-3-(2-piperidin-1-yl-ethylsulfanyl)-[1,2,4]triazine 87992-22-1 C16H19FN4S
    5-(4-Fluoro-phenyl)-3-(2-piperidin-1-yl-ethylsulfanyl)-[1,2,4]triazine
    —— 1-[(2R,3R,5S,9R)-9-[tert-butyl(dimethyl)silyl]oxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]-5-methylpyrimidine-2,4-dione 629665-61-8 C25H36N2O4SSi
    1-[(2R,3R,5S,9R)-9-[tert-butyl(dimethyl)silyl]oxy-3-phenylsulfanyl-1-oxaspiro[4.4]nonan-2-yl]-5-methylpyrimidine-2,4-dione
    —— 1-methylthio-4,5-dipropionyl-4,5-dihydro-s-triazolo[3,4-c]-benzo-as-triazine 77497-16-6 C15H17N5O2S
    1-methylthio-4,5-dipropionyl-4,5-dihydro-s-triazolo[3,4-c]-benzo-as-triazine
    —— 5-bromo-6-<(bromomethyl)sulfonyl>decane 102683-69-2 C11H22Br2O2S
    5-bromo-6-<(bromomethyl)sulfonyl>decane
    —— [5-(4-Fluoro-phenyl)-[1,2,4]triazin-3-ylsulfanyl]-acetic acid 87992-30-1 C11H8FN3O2S
    [5-(4-Fluoro-phenyl)-[1,2,4]triazin-3-ylsulfanyl]-acetic acid
    —— 1,1'-Disulfanediylbis{2,3,4,5-tetrakis[(trifluoromethyl)sulfanyl]-1H-pyrrole} 87841-00-7 C16F24N2S10
    1,1'-Disulfanediylbis{2,3,4,5-tetrakis[(trifluoromethyl)sulfanyl]-1H-pyrrole}
    —— dithiobis(6-hexaneamine) 45186-02-5 C12H28N2S2
    dithiobis(6-hexaneamine)
    —— bis-(8-amino-octyl)-disulfide 220008-86-6 C16H36N2S2
    bis-(8-amino-octyl)-disulfide
    —— (2-ethylmercapto-6-oxo-1,6-dihydro-pyrimidin-4-yl)-acetic acid ethyl ester 20763-90-0 C10H14N2O3S
    (2-ethylmercapto-6-oxo-1,6-dihydro-pyrimidin-4-yl)-acetic acid ethyl ester
    —— 1,1-Dichlor-2,2-bis-(p-tolylmercapto>-ethen 88388-95-8 C16H14Cl2S2
    1,1-Dichlor-2,2-bis-(p-tolylmercapto>-ethen
    —— 2-<4-(dimethylamino)phenylmethylene>-5-hexylbenzo<b>thiophen-3(2H)-one 141399-86-2 C23H27NOS
    2-<4-(dimethylamino)phenylmethylene>-5-hexylbenzo<b>thiophen-3(2H)-one
    —— 1-diazomethanesulfonyl-octane 3052-98-0 C9H18N2O2S
    1-diazomethanesulfonyl-octane
    —— N-(4-fluorophenyl)-4-(methylthio)benzenecarboximidamide 193422-48-9 C14H13FN2S
    N-(4-fluorophenyl)-4-(methylthio)benzenecarboximidamide
    —— N-[(Phenylsulfanyl)methyl]butan-1-amine--hydrogen chloride (1/1) 33704-65-3 C11H17NS*ClH
    N-[(Phenylsulfanyl)methyl]butan-1-amine--hydrogen chloride (1/1)
    —— 3-Methyl-2-[(4-methylphenyl)sulfanyl]cyclohexan-1-one 89816-71-7 C14H18OS
    3-Methyl-2-[(4-methylphenyl)sulfanyl]cyclohexan-1-one
    —— 2,3-dihydro-2-oxobenzo<b>thien-3-yl diethyl phosphate 88690-91-9 C12H15O5PS
    2,3-dihydro-2-oxobenzo<b>thien-3-yl diethyl phosphate
    —— (4-(azidomethyl)phenyl)(methyl)sulfane 142070-82-4 C8H9N3S
    (4-(azidomethyl)phenyl)(methyl)sulfane
    —— methanesulfonic acid 4-(methylthio)benzyl ester 68982-45-6 C9H12O3S2
    methanesulfonic acid 4-(methylthio)benzyl ester
    —— 2-(6-Methyl-5-oxo-2,5-dihydro-[1,2,4]triazin-3-ylsulfanylmethyl)-acrylic acid 90982-64-2 C8H9N3O3S
    2-(6-Methyl-5-oxo-2,5-dihydro-[1,2,4]triazin-3-ylsulfanylmethyl)-acrylic acid
    —— 2,3-dihydro-2-oxobenzo<b>thien-3-yl dimethyl phosphate 88690-90-8 C10H11O5PS
    2,3-dihydro-2-oxobenzo<b>thien-3-yl dimethyl phosphate
    —— 4-phenylazo-5-methylthio-3-phenylisoxazole 74099-12-0 C16H13N3OS
    4-phenylazo-5-methylthio-3-phenylisoxazole
    —— phenyl 3,5-bis[O-(t-butyldimethylsilyl)]-2-deoxy-1-thio-D-erythro-pentofuranoside 174289-74-8 C23H42O3SSi2
    phenyl 3,5-bis[O-(t-butyldimethylsilyl)]-2-deoxy-1-thio-D-erythro-pentofuranoside
    —— tert-butyl-diphenyl-[[(2S)-5-phenylsulfanyl-2,5-dihydrofuran-2-yl]methoxy]silane 190725-04-3 C27H30O2SSi
    tert-butyl-diphenyl-[[(2S)-5-phenylsulfanyl-2,5-dihydrofuran-2-yl]methoxy]silane
    —— 1-cycloheptyl-3-phenylthio-1-propanone 70910-89-3 C16H22OS
    1-cycloheptyl-3-phenylthio-1-propanone
    —— (3aα,6aα)-tetrahydro-2,2-dimethylspiro<cyclopenta<1,3>dioxole-5,2'-<1,3>dithiane> 135598-36-6 C11H18O2S2
    (3aα,6aα)-tetrahydro-2,2-dimethylspiro<cyclopenta<1,3>dioxole-5,2'-<1,3>dithiane>
    —— 2-Amino-3-methylthio-6-t-butyl-5-oxo-2,5-dihydro-1,2,4-triazine 81941-69-7 C8H14N4OS
    2-Amino-3-methylthio-6-t-butyl-5-oxo-2,5-dihydro-1,2,4-triazine
    —— tert-butyl-dimethyl-[[(2S)-5-phenylsulfanyl-2,5-dihydrofuran-2-yl]methoxy]silane 190725-03-2 C17H26O2SSi
    tert-butyl-dimethyl-[[(2S)-5-phenylsulfanyl-2,5-dihydrofuran-2-yl]methoxy]silane
    —— 6-(2-chlorophenyl)-4-(methylthio)-2-oxo-2H-pyran-3-carbonitrile 215729-53-6 C13H8ClNO2S
    6-(2-chlorophenyl)-4-(methylthio)-2-oxo-2H-pyran-3-carbonitrile
    —— 2-Ethylthio-5-methylfuran 4218-15-9 C7H10OS
    2-Ethylthio-5-methylfuran
    —— ethyl 1-ethyl-2-oxo-3-phenylthiocyclohexanecarboxylate 89816-95-5 C17H22O3S
    ethyl 1-ethyl-2-oxo-3-phenylthiocyclohexanecarboxylate
    —— Allyl-[1-dimethylamino-meth-(Z)-ylidene]-sulfonium 89524-41-4 C6H12NS
    Allyl-[1-dimethylamino-meth-(Z)-ylidene]-sulfonium
    —— 1-methyl-4-<2-(4-chlorphenylthio)benzoyl>piperazine 93288-93-8 C18H19ClN2OS
    1-methyl-4-<2-(4-chlorphenylthio)benzoyl>piperazine
    —— Prop-2-en-1-yl ethanimidothioate 89524-39-0 C5H9NS
    Prop-2-en-1-yl ethanimidothioate
    —— 5-Methyl-2-[(4-methylphenyl)sulfanyl]cyclohexan-1-one 89816-72-8 C14H18OS
    5-Methyl-2-[(4-methylphenyl)sulfanyl]cyclohexan-1-one
    —— bis<methoxy(thiocarbonyl)>tetrasulfane 74568-23-3 C4H6O2S6
    bis<methoxy(thiocarbonyl)>tetrasulfane
    —— 3-Bromo-2-(bromomethylsulfonyl)octane 86823-70-3 C9H18Br2O2S
    3-Bromo-2-(bromomethylsulfonyl)octane
    —— Ethyl methyl tetrasulfane-1,4-dicarboxylate 88766-55-6 C5H8O4S4
    Ethyl methyl tetrasulfane-1,4-dicarboxylate
    —— all-cis-12-Methylthio-1,3,6,9-dodecatetraen 115465-56-0 C13H20S
    all-cis-12-Methylthio-1,3,6,9-dodecatetraen
    —— 5-acetyl-4-[(5-mercapto-1,3,4-oxadiazol-2-yl)methyl]thio-6-methyl-2-[(E)-2-(2-thienyl)vinyl]pyrimidine 1094816-83-7 C16H14N4O2S3
    5-acetyl-4-[(5-mercapto-1,3,4-oxadiazol-2-yl)methyl]thio-6-methyl-2-[(E)-2-(2-thienyl)vinyl]pyrimidine
    —— 1-Propenyl triflone 61795-20-8 C4H5F3O2S
    1-Propenyl triflone
    —— 2-(5,6-Dihydro-4H-cyclopenta[1,3]dithiol-2-ylidene)-benzo[1,3]dithiole 90703-79-0 C13H10S4
    2-(5,6-Dihydro-4H-cyclopenta[1,3]dithiol-2-ylidene)-benzo[1,3]dithiole
    —— 1-Methyl-4-(2-(4-methylphenylthio)benzoyl)piperazine hydrogen maleate 93288-92-7 C23H26N2O5S
    1-Methyl-4-(2-(4-methylphenylthio)benzoyl)piperazine hydrogen maleate
    —— 2-Nitro-4-phenylthio-chlorbenzol 92114-68-6 C12H8ClNO2S
    2-Nitro-4-phenylthio-chlorbenzol
    —— 1-Methyl-4-(2-(2-methylphenylthio)benzoyl)piperazine hydrogen maleate 93288-90-5 C23H26N2O5S
    1-Methyl-4-(2-(2-methylphenylthio)benzoyl)piperazine hydrogen maleate
    —— 1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzoyl)-4-methylpiperazine hydrogen maleate 93289-07-7 C24H27ClN2O6S
    1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzoyl)-4-methylpiperazine hydrogen maleate
    —— 1-phenylthio-1-trimethylsilylundecane 87505-44-0 C20H36SSi
    1-phenylthio-1-trimethylsilylundecane