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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5E)-5-(1-phenylsulfanylethylidene)oxolan-2-one 109574-08-5 C12H12O2S
    (5E)-5-(1-phenylsulfanylethylidene)oxolan-2-one
    —— 4-methyl-3-(phenylthio)-2-buten-4-olide 75717-37-2 C11H10O2S
    4-methyl-3-(phenylthio)-2-buten-4-olide
    —— 2-methyl-N-(2-methyl-2-propanyl)propanthioamide 21351-33-7 C8H17NS
    2-methyl-N-(2-methyl-2-propanyl)propanthioamide
    —— Bis(4-methylsulfanylphenyl)-propan-2-yloxyphosphane 139117-16-1 C17H21OPS2
    Bis(4-methylsulfanylphenyl)-propan-2-yloxyphosphane
    —— 1-phenylsulphenyl-2-methoxymethylethyne 109491-07-8 C10H10OS
    1-phenylsulphenyl-2-methoxymethylethyne
    —— 4-methylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-dithiole-2-thione 238419-82-4 C11H16O2S4Se
    4-methylseleno-5-[2-(tetrahydropyran-2-yloxy)ethylthio]-1,3-dithiole-2-thione
    —— (2-Fluoroethyl)(phenyl)sulfane 33740-59-9 C8H9FS
    (2-Fluoroethyl)(phenyl)sulfane
    —— 5,6-dihydro-2-thioxo-1,3-dithio[2,3-d][1,4]thiaselenin 238419-85-7 C5H4S4Se
    5,6-dihydro-2-thioxo-1,3-dithio[2,3-d][1,4]thiaselenin
    —— 5,6-dihydro-2-oxo-1,3-dithio[2,3-d][1,4]thiaselenin 238419-86-8 C5H4OS3Se
    5,6-dihydro-2-oxo-1,3-dithio[2,3-d][1,4]thiaselenin
    —— 4-methylseleno-5-(2-hydroxyethylthio)-1,3-dithiole-2-thione 238419-83-5 C6H8OS4Se
    4-methylseleno-5-(2-hydroxyethylthio)-1,3-dithiole-2-thione
    —— S-(2-fluoroethyl)isothiourea 44604-90-2 C3H7FN2S
    S-(2-fluoroethyl)isothiourea
    —— 5-fluoro-2-(4-isopropylphenylthio)benzyl alcohol 91527-97-8 C16H17FOS
    5-fluoro-2-(4-isopropylphenylthio)benzyl alcohol
    —— 2-<5-fluoro-2-(4-isopropylphenylthio)phenyl>acetic acid 91528-05-1 C17H17FO2S
    2-<5-fluoro-2-(4-isopropylphenylthio)phenyl>acetic acid
    —— (Cyclohexylsulfanyl)carbonyl chloride 54408-46-7 C7H11ClOS
    (Cyclohexylsulfanyl)carbonyl chloride
    —— Butyl octyl trithiocarbonate 89622-61-7 C13H26S3
    Butyl octyl trithiocarbonate
    —— phenylthiomethyl isothiocyanate 51989-38-9 C8H7NS2
    phenylthiomethyl isothiocyanate
    —— 1-methyl-3-phenylsulfenyl-2-(thiophen-3-yl)indole 1185744-06-2 C19H15NS2
    1-methyl-3-phenylsulfenyl-2-(thiophen-3-yl)indole
    —— Butylsulfanyl-cyclopentylsulfanylmethanethione 89622-64-0 C10H18S3
    Butylsulfanyl-cyclopentylsulfanylmethanethione
    —— 2-Mercapto-aethyldithiocarbamidsaeure 69353-03-3 C3H7NS3
    2-Mercapto-aethyldithiocarbamidsaeure
    —— 3-chloro-4-(phenylthio)-1,1,2-trifluoro-1-butene 113894-32-9 C10H8ClF3S
    3-chloro-4-(phenylthio)-1,1,2-trifluoro-1-butene
    —— (Z)-bromo-2 thiocyanato-1 pentene-1 100641-50-7 C6H8BrNS
    (Z)-bromo-2 thiocyanato-1 pentene-1
    —— E-2<(phenylthio)methylidene>cyclohexanone 116512-54-0 C13H14OS
    E-2<(phenylthio)methylidene>cyclohexanone
    —— [2,2-Dimethoxy-cyclohex-(E)-ylidenemethylsulfanyl]-benzene 119044-14-3 C15H20O2S
    [2,2-Dimethoxy-cyclohex-(E)-ylidenemethylsulfanyl]-benzene
    —— 1-methyl-2-<(phenylthio)methylidene>cyclohexane-1-ol 119044-31-4 C14H18OS
    1-methyl-2-<(phenylthio)methylidene>cyclohexane-1-ol
    —— N,N-dimethyl-2-phenylthio-3-methoxy-benzylamine 119018-65-4 C16H19NOS
    N,N-dimethyl-2-phenylthio-3-methoxy-benzylamine
    —— (amino-3 pyridyl-2) ethyl sulfure 89407-31-8 C7H10N2S
    (amino-3 pyridyl-2) ethyl sulfure
    —— methyl 2,3-dihydrobenzo[b][1,4]oxathiine-7-carboxylate 1420043-06-6 C10H10O3S
    methyl 2,3-dihydrobenzo[b][1,4]oxathiine-7-carboxylate
    —— (+/-)-α-dimethylphosphorylethyl p-tolyl sulphide 73778-48-0 C13H21O3PS
    (+/-)-α-dimethylphosphorylethyl p-tolyl sulphide
    —— 2,2,7,7-Tetramethylcycloheptanthion-Radikalanion 64274-57-3 C11H20S
    2,2,7,7-Tetramethylcycloheptanthion-Radikalanion
    —— 2-(4-bromo-2-nitrophenylthio)-5-(2-fluoroethoxy)-N,N-dimethylbenzamide 1004534-53-5 C17H16BrFN2O4S
    2-(4-bromo-2-nitrophenylthio)-5-(2-fluoroethoxy)-N,N-dimethylbenzamide
    —— bis(4-(diethylamino)phenyl)sulfide 23117-45-5 C20H28N2S
    bis(4-(diethylamino)phenyl)sulfide
    —— Phenyl 2-chloro-1-fluoroethyl sulfide 136370-30-4 C8H8ClFS
    Phenyl 2-chloro-1-fluoroethyl sulfide
    —— 2-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-1-(3-(isopropylamino)propyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061317-59-6 C19H22IN5O2S
    2-((6-iodobenzo[d][1,3]dioxol-5-yl)thio)-1-(3-(isopropylamino)propyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-<3-(phenylthio)prop-2-ynoxy>oxane 130659-33-5 C14H16O2S
    2-<3-(phenylthio)prop-2-ynoxy>oxane
    —— Methyl 2-methyl-3-oxo-2-(phenylsulfanyl)butanoate 82111-72-6 C12H14O3S
    Methyl 2-methyl-3-oxo-2-(phenylsulfanyl)butanoate
    —— 5-allyl-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one 54069-14-6 C9H12N2OS
    5-allyl-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one
    —— Tridecanethioic acid, 13-hydroxy-, S-2-pyridinyl ester 53379-05-8 C18H29NO2S
    Tridecanethioic acid, 13-hydroxy-, S-2-pyridinyl ester
    —— 2-(4-bromo-2-nitrophenylthio)-5-hydroxy-N,N-dimethylbenzamide 939022-07-8 C15H13BrN2O4S
    2-(4-bromo-2-nitrophenylthio)-5-hydroxy-N,N-dimethylbenzamide
    —— (2,2,6,6-Tetramethylcyclohexyl)-(2,2,5-trimethylbicyclo<3.1.0>hex-1-yl)-sulfid 89051-24-1 C19H34S
    (2,2,6,6-Tetramethylcyclohexyl)-(2,2,5-trimethylbicyclo<3.1.0>hex-1-yl)-sulfid
    —— (2,2,5,5-Tetramethylcyclopentyl)-(2,2,6-trimethylbicyclo<4.1.0>hept-1-yl)sulfid 89051-23-0 C19H34S
    (2,2,5,5-Tetramethylcyclopentyl)-(2,2,6-trimethylbicyclo<4.1.0>hept-1-yl)sulfid
    —— 2-(2-amino-4-methoxyphenylthio)imidazole 88251-72-3 C10H11N3OS
    2-(2-amino-4-methoxyphenylthio)imidazole
    —— 3-(phenylsulfenyl)-2-trimethylsilylbenzo[b]thiophene 1453485-27-2 C17H18S2Si
    3-(phenylsulfenyl)-2-trimethylsilylbenzo[b]thiophene
    —— 3,5-dibromophenyl phenyl sulfide 1262299-96-6 C12H8Br2S
    3,5-dibromophenyl phenyl sulfide
    —— 2-(4-chloro-2-nitrophenylthio)-5-(2-fluoroethoxy)-N,N-dimethylbenzamide 1004534-51-3 C17H16ClFN2O4S
    2-(4-chloro-2-nitrophenylthio)-5-(2-fluoroethoxy)-N,N-dimethylbenzamide
    —— 2-(4-chloro-2-nitrophenylthio)-5-hydroxy-N,N-dimethylbenzamide 1004534-44-4 C15H13ClN2O4S
    2-(4-chloro-2-nitrophenylthio)-5-hydroxy-N,N-dimethylbenzamide
    —— 5-(2-fluoroethoxy)-2-(2-nitrophenylthio)-N,N-dimethylbenzamide 1004534-47-7 C17H17FN2O4S
    5-(2-fluoroethoxy)-2-(2-nitrophenylthio)-N,N-dimethylbenzamide
    —— 5-(2-fluoroethoxy)-2-(4-fluoro-2-nitrophenylthio)-N,N-dimethylbenzamide 1004534-49-9 C17H16F2N2O4S
    5-(2-fluoroethoxy)-2-(4-fluoro-2-nitrophenylthio)-N,N-dimethylbenzamide
    —— 3-Amino-2-cyano-2-butenthiocarboxamid 41808-30-4 C5H7N3S
    3-Amino-2-cyano-2-butenthiocarboxamid
    —— 4-methyl-2-methylthio-4,5-dihydro-1,3,4-thiadiazole-5-thione 33682-80-3 C4H6N2S3
    4-methyl-2-methylthio-4,5-dihydro-1,3,4-thiadiazole-5-thione
    —— <(3-methyl-2-thio-1,3,4-thiadiazolin-5-yl)thio><5-(methylthio)-2-thioxo-1,3,4-thiadiazolin-3-yl>methane 91021-40-8 C7H8N4S6
    <(3-methyl-2-thio-1,3,4-thiadiazolin-5-yl)thio><5-(methylthio)-2-thioxo-1,3,4-thiadiazolin-3-yl>methane