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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-ethylsulfanyl-5-methyl-pyrimidin-4-ylamine 54410-87-6 C7H11N3S
    2-ethylsulfanyl-5-methyl-pyrimidin-4-ylamine
    —— (1R,2R)-2-Phenylsulfanyl-cyclopent-3-enol 77520-12-8 C11H12OS
    (1R,2R)-2-Phenylsulfanyl-cyclopent-3-enol
    —— 4-amino-2-(methylthio)pyrimidine-5-carbothioamide 55441-41-3 C6H8N4S2
    4-amino-2-(methylthio)pyrimidine-5-carbothioamide
    —— 1-(2-(4-Chlorophenylthio)benzoyl)-4-methylpiperazine hydrogen maleate 93288-94-9 C22H23ClN2O5S
    1-(2-(4-Chlorophenylthio)benzoyl)-4-methylpiperazine hydrogen maleate
    —— S-n-octylisothiourea 34316-89-7 C9H20N2S
    S-n-octylisothiourea
    —— bis-octylmercapto-[1,3,4]thiadiazole 96521-01-6 C18H34N2S3
    bis-octylmercapto-[1,3,4]thiadiazole
    —— acetoxymethyl vinyl sulfide 137501-50-9 C5H8O2S
    acetoxymethyl vinyl sulfide
    —— (3-Phenyl-4-p-tolylazo-isoxazol-5-ylsulfanyl)-acetic acid ethyl ester 91816-20-5 C20H19N3O3S
    (3-Phenyl-4-p-tolylazo-isoxazol-5-ylsulfanyl)-acetic acid ethyl ester
    —— 1-Methyl-4-(2-(phenylthio)benzoyl)piperazine hydrogen maleate 93288-88-1 C22H24N2O5S
    1-Methyl-4-(2-(phenylthio)benzoyl)piperazine hydrogen maleate
    —— (5-Methylsulfanyl-3-phenyl-isoxazol-4-yl)-p-tolyl-diazene 91816-13-6 C17H15N3OS
    (5-Methylsulfanyl-3-phenyl-isoxazol-4-yl)-p-tolyl-diazene
    —— Ethyl 2-[(3-phenyl-4-phenyldiazenyl-1,2-oxazol-5-yl)sulfanyl]acetate 91816-19-2 C19H17N3O3S
    Ethyl 2-[(3-phenyl-4-phenyldiazenyl-1,2-oxazol-5-yl)sulfanyl]acetate
    —— 2,2-diethyl-5-{4-(methylthio)phenyl}-3(2H)-furanone 301699-14-9 C15H18O2S
    2,2-diethyl-5-{4-(methylthio)phenyl}-3(2H)-furanone
    —— 1-(3-Methyl-1-phenylsulfanyl-buta-1,2-dienyl)-cyclohexanol 92616-90-5 C17H22OS
    1-(3-Methyl-1-phenylsulfanyl-buta-1,2-dienyl)-cyclohexanol
    —— 3-[(4-chlorophenyl)sulfanyl]propan-1-amine 104864-09-7 C9H12ClNS
    3-[(4-chlorophenyl)sulfanyl]propan-1-amine
    —— N-{3-(benzylidene-hydrazinocarbonylmethylsulfanyl)-5-[2-(2-chloro-acetylamino)-4,5,6,7-tetrahydro-benzo[b]thiophen-3-ylmethyl]-[1,2,4]triazol-4-yl}-benzamide 1310547-59-1 C29H28ClN7O3S2
    N-{3-(benzylidene-hydrazinocarbonylmethylsulfanyl)-5-[2-(2-chloro-acetylamino)-4,5,6,7-tetrahydro-benzo[b]thiophen-3-ylmethyl]-[1,2,4]triazol-4-yl}-benzamide
    —— 2-[3-(caprylamino)propylthio]pyridine 155965-46-1 C18H30N2OS
    2-[3-(caprylamino)propylthio]pyridine
    —— N-{3-[4-acetylamino-5-(benzylidene-hydrazinocarbonylmethylsulfanyl)-4H-[1,2,4] triazol-3-ylmethyl]-4,5,6,7-tetrahydro-benzo[b]thiophen-2-yl}-2-chloro-acetamide 1310547-63-7 C24H26ClN7O3S2
    N-{3-[4-acetylamino-5-(benzylidene-hydrazinocarbonylmethylsulfanyl)-4H-[1,2,4] triazol-3-ylmethyl]-4,5,6,7-tetrahydro-benzo[b]thiophen-2-yl}-2-chloro-acetamide
    —— N6-(3-(4-chlorophenylthio)propyl)-2,2-dimethyl-1,2-dihydro-1,3,5-triazine-4,6-diamine hydrochloride 1310538-16-9 C14H20ClN5S*ClH
    N6-(3-(4-chlorophenylthio)propyl)-2,2-dimethyl-1,2-dihydro-1,3,5-triazine-4,6-diamine hydrochloride
    —— 5-(2-phenylsulfanylphenyl)-3H-1,3,4-oxadiazole-2-thione 945031-07-2 C14H10N2OS2
    5-(2-phenylsulfanylphenyl)-3H-1,3,4-oxadiazole-2-thione
    —— (R)-decyl methyl sulfoxide 211501-62-1 C11H24OS
    (R)-decyl methyl sulfoxide
    —— 1-(Benzenesulfonyl)-3-(4-methylphenyl)sulfanylindole 170499-47-5 C21H17NO2S2
    1-(Benzenesulfonyl)-3-(4-methylphenyl)sulfanylindole
    —— 1-[4-(Phenylsulfanyl)but-3-yn-1-yl]pyrrolidine-2,5-dione 73711-01-0 C14H13NO2S
    1-[4-(Phenylsulfanyl)but-3-yn-1-yl]pyrrolidine-2,5-dione
    —— 1-Phenylseleno-1-phenylthiocyclohexan 64042-29-1 C18H20SSe
    1-Phenylseleno-1-phenylthiocyclohexan
    —— N-{2-[3-(Methylsulfanyl)phenyl]ethyl}methanimine 90265-78-4 C10H13NS
    N-{2-[3-(Methylsulfanyl)phenyl]ethyl}methanimine
    —— 3,3-Dimethyl-dithiocarbazidsaeure 14353-59-4 C3H8N2S2
    3,3-Dimethyl-dithiocarbazidsaeure
    —— N-[3-methylthiophenyl-(tolylthio)methyl]formamide 165806-89-3 C16H17NOS2
    N-[3-methylthiophenyl-(tolylthio)methyl]formamide
    —— ethyl 3-bromo-4-[3-(methylthio)phenyl]-2-oxobutanoate 874899-37-3 C13H15BrO3S
    ethyl 3-bromo-4-[3-(methylthio)phenyl]-2-oxobutanoate
    —— N-formyl-2-(3-methylthiophenyl)ethylamine 90265-79-5 C10H13NOS
    N-formyl-2-(3-methylthiophenyl)ethylamine
    —— N'-(3-(methylthio)benzylidene)stearohydrazide 1273028-57-1 C26H44N2OS
    N'-(3-(methylthio)benzylidene)stearohydrazide
    —— N'-(3-(methylthio)benzylidene)tetradecanehydrazide 1273028-53-7 C22H36N2OS
    N'-(3-(methylthio)benzylidene)tetradecanehydrazide
    —— dimethyl 4-(methylthio)phenylmethylphosphonate 481679-70-3 C10H15O3PS
    dimethyl 4-(methylthio)phenylmethylphosphonate
    —— 1,2-Dibromo-3-(methylthio)propane 86823-45-2 C4H8Br2S
    1,2-Dibromo-3-(methylthio)propane
    —— (2R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-7-ethyl-4-phenylsulfanyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]oxazin-8-one 323582-29-2 C22H32N2O3SSi
    (2R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-7-ethyl-4-phenylsulfanyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]oxazin-8-one
    —— 2-Pyridinecarbothioamide, 4-(decylthio)- 186044-67-7 C16H26N2S2
    2-Pyridinecarbothioamide, 4-(decylthio)-
    —— 2-[1-(1-decylsulfanyl)-3-(phenylsulfanyl)prop-2-ynyl]thiophene 1356911-67-5 C23H30S3
    2-[1-(1-decylsulfanyl)-3-(phenylsulfanyl)prop-2-ynyl]thiophene
    —— 1-Allyl-5-methylsulfanyl-1H-tetrazole 87996-18-7 C5H8N4S
    1-Allyl-5-methylsulfanyl-1H-tetrazole
    —— MeC(CH2S(n)C10H21)3 1019772-47-4 C35H72S3
    MeC(CH2S(n)C10H21)3
    —— 3-(decane-1-sulfonyl)-propionic acid 116709-96-7 C13H26O4S
    3-(decane-1-sulfonyl)-propionic acid
    —— 5-(5-decylthio-2-thienyl)penta-2,4-dienal 146333-49-5 C19H28OS2
    5-(5-decylthio-2-thienyl)penta-2,4-dienal
    —— ethyl 4-sulfonyltetradecanoate 294201-71-1 C15H30O4S
    ethyl 4-sulfonyltetradecanoate
    —— N,2-dimethylbutanethioamide 72807-36-4 C6H13NS
    N,2-dimethylbutanethioamide
    —— 5-ethyl-1-<<1'-phenyl-2'(t-butyldimethylsilyloxy)ethoxy>methyl>-6-(phenylthio)uracil 155831-66-6 C27H36N2O4SSi
    5-ethyl-1-<<1'-phenyl-2'(t-butyldimethylsilyloxy)ethoxy>methyl>-6-(phenylthio)uracil
    —— di-n-decyl thiosulfonate 1309877-85-7 C20H42O2S2
    di-n-decyl thiosulfonate
    —— 5-decylthiothiophene-2-carbaldehyde 146333-47-3 C15H24OS2
    5-decylthiothiophene-2-carbaldehyde
    —— 5-decylsulfanyl-3-methoxythiophene-2,4-dicarbonitrile 119754-43-7 C17H24N2OS2
    5-decylsulfanyl-3-methoxythiophene-2,4-dicarbonitrile
    —— 1-[(3S)-4-[tert-butyl(dimethyl)silyl]oxy-3-hydroxy-1-phenylsulfanylbutyl]-5-ethylpyrimidine-2,4-dione 323582-27-0 C22H34N2O4SSi
    1-[(3S)-4-[tert-butyl(dimethyl)silyl]oxy-3-hydroxy-1-phenylsulfanylbutyl]-5-ethylpyrimidine-2,4-dione
    —— decyl(methoxymethyl)sulfane 1425608-30-5 C12H26OS
    decyl(methoxymethyl)sulfane
    —— 3-decylsulfanylthiophene 92372-03-7 C14H24S2
    3-decylsulfanylthiophene
    —— 2-[((2,5-dimethylphenyl)methyl)thio]-3-methylpyridine-1-oxide 81167-57-9 C15H17NOS
    2-[((2,5-dimethylphenyl)methyl)thio]-3-methylpyridine-1-oxide
    —— 6,6-dimethyl-3-methylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one —— C12H14N4OS2
    6,6-dimethyl-3-methylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one