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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 72958-44-2 C10H21N3OSSn
    —— Dodecyldimethylsulfonium[Cu3I4(DodecylSMe)3] 749862-31-5 C14H31S*C39H84Cu3I4S3
    Dodecyldimethylsulfonium[Cu3I4(DodecylSMe)3]
    —— Bis-<4-chlor-phenylmercapto-methyl>-phenyl-amin 22959-39-3 C20H17Cl2NS2
    Bis-<4-chlor-phenylmercapto-methyl>-phenyl-amin
    —— 2-methylsulfanylthieno[3,2-b]pyran-5-one 1258560-21-2 C8H6O2S2
    2-methylsulfanylthieno[3,2-b]pyran-5-one
    —— 2-(4-Methylsulfanyl-phenylsulfanyl)-benzaldehyde 643763-20-6 C14H12OS2
    2-(4-Methylsulfanyl-phenylsulfanyl)-benzaldehyde
    —— N-[2-(4-chloro-2-nitrophenyl)sulfanyl-6-methylphenyl]formamide 500898-67-9 C14H11ClN2O3S
    N-[2-(4-chloro-2-nitrophenyl)sulfanyl-6-methylphenyl]formamide
    —— 2-Ethylthio-6-hydroxymethyl-5-fluor-4-pyrimidol 23865-48-7 C7H9FN2O2S
    2-Ethylthio-6-hydroxymethyl-5-fluor-4-pyrimidol
    —— 3-Phenylthio-4-aza-homoadamantan 34650-83-4 C16H21NS
    3-Phenylthio-4-aza-homoadamantan
    —— 2-bromo-N-[(2-bromophenyl)methyl]-N-(2-phenylsulfanylcyclohexen-1-yl)acetamide 205446-76-0 C21H21Br2NOS
    2-bromo-N-[(2-bromophenyl)methyl]-N-(2-phenylsulfanylcyclohexen-1-yl)acetamide
    —— (1,3-Bis-methylsulfanyl-propylidene)-cyclopropane 136380-08-0 C8H14S2
    (1,3-Bis-methylsulfanyl-propylidene)-cyclopropane
    —— N-(1-Acetylamino-3-phenylsulfanyl-butyl)-acetamide 92374-48-6 C14H20N2O2S
    N-(1-Acetylamino-3-phenylsulfanyl-butyl)-acetamide
    —— (R)-3-amino-7-((4-(3-((tert-butoxycarbonyl)amino)pyrrolidin-1-yl)-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl)thio)benzo[e][1,2,4]triazine 1-oxide 1425309-97-2 C24H29N9O3S
    (R)-3-amino-7-((4-(3-((tert-butoxycarbonyl)amino)pyrrolidin-1-yl)-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl)thio)benzo[e][1,2,4]triazine 1-oxide
    —— (2Z,4Z)-2,3,4,5-Tetrachloro-5-pentachlorophenylsulfanyl-penta-2,4-dienoyl chloride 65954-72-5 C11Cl10OS
    (2Z,4Z)-2,3,4,5-Tetrachloro-5-pentachlorophenylsulfanyl-penta-2,4-dienoyl chloride
    —— 3,7-Dimethyl-8-(methylthio)-2-thioxanthin 51292-13-8 C8H10N4OS2
    3,7-Dimethyl-8-(methylthio)-2-thioxanthin
    —— S-(2-<2-(Pyridyl-(2)-mercapto)-ethylamino>-ethyl)-hydrogenthiosulfat 22278-58-6 C9H14N2O3S3
    S-(2-<2-(Pyridyl-(2)-mercapto)-ethylamino>-ethyl)-hydrogenthiosulfat
    —— butyl 3-methyl-2-(phenylthiocarbonyl)butanoate 1319740-99-2 C16H22O3S
    butyl 3-methyl-2-(phenylthiocarbonyl)butanoate
    —— 2,4-bis(perfluoro-n-butyl)-2,4-bis(trifluoromethyl)-1,3-dithiethane 916-26-7 C12F24S2
    2,4-bis(perfluoro-n-butyl)-2,4-bis(trifluoromethyl)-1,3-dithiethane
    —— 1-[4-(4-chlorophenyl)sulfanyl-4H-pyridin-1-yl]pyridin-4-one 78526-41-7 C16H13ClN2OS
    1-[4-(4-chlorophenyl)sulfanyl-4H-pyridin-1-yl]pyridin-4-one
    —— Cr(acacen)(H2O)2(1+) 73347-24-7 C12H22CrN2O4
    Cr(acacen)(H2O)2(1+)
    —— 1-(ethoxycarbonothioylthio)-2,2,2-trifluoroethyl acetate 845523-51-5 C7H9F3O3S2
    1-(ethoxycarbonothioylthio)-2,2,2-trifluoroethyl acetate
    —— 3,3-Bis(phenylsulfanyl)propionitrile 105961-91-9 C15H13NS2
    3,3-Bis(phenylsulfanyl)propionitrile
    —— ω-Allyl-dithiobiuret 21248-59-9 C5H9N3S2
    ω-Allyl-dithiobiuret
    —— Ethyl-phosphonothioic acid O-(6-tert-butyl-2-methylsulfanyl-pyrimidin-4-yl) ester O-methyl ester 66698-45-1 C12H21N2O2PS2
    Ethyl-phosphonothioic acid O-(6-tert-butyl-2-methylsulfanyl-pyrimidin-4-yl) ester O-methyl ester
    —— [1-Amino-2-(2-amino-2-hydroxyphosphinoyl-ethyldisulfanyl)-ethyl]-phosphinic acid 95711-02-7 C4H14N2O4P2S2
    [1-Amino-2-(2-amino-2-hydroxyphosphinoyl-ethyldisulfanyl)-ethyl]-phosphinic acid
    —— Methyl-phosphonodithioic acid S-sec-butyl ester O-(6-methoxymethyl-2-methylsulfanyl-pyrimidin-4-yl) ester 68067-98-1 C12H21N2O2PS3
    Methyl-phosphonodithioic acid S-sec-butyl ester O-(6-methoxymethyl-2-methylsulfanyl-pyrimidin-4-yl) ester
    —— Ethyl-N-(4-chlor-2-methylthio-6-pyrimidinyl)-aminomethylen-malonat 37946-29-5 C13H16ClN3O4S
    Ethyl-N-(4-chlor-2-methylthio-6-pyrimidinyl)-aminomethylen-malonat
    —— Dithiophosphoric acid O,O'-diethyl ester S-(2-oxo-azonan-1-ylmethyl) ester 96731-49-6 C13H26NO3PS2
    Dithiophosphoric acid O,O'-diethyl ester S-(2-oxo-azonan-1-ylmethyl) ester
    —— 2,4-diisopropoxy-6-phenylsulfanyl-[1,3,5]triazine 3060-78-4 C15H19N3O2S
    2,4-diisopropoxy-6-phenylsulfanyl-[1,3,5]triazine
    —— [Rh(CH(SPh)CH2CH2PCy2-κC,κP)(dppe)] 1259037-31-4 C47H56P3RhS
    [Rh(CH(SPh)CH2CH2PCy2-κC,κP)(dppe)]
    —— 3-phenyl-5-<i>o</i>-tolylsulfanyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione 65491-52-3 C15H12N2S3
    3-phenyl-5-<i>o</i>-tolylsulfanyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione
    —— 2-((2-phenethyl)lthio)pyrimidine-4,5,6-triamine 1099593-16-4 C12H15N5S
    2-((2-phenethyl)lthio)pyrimidine-4,5,6-triamine
    —— N-[4-chloro-3-(trifluoromethyl)phenyl]-[4-(N-methylformamide)(4-pyridylthio)phenyl]thiourea toluenesulfonate 1246391-77-4 C7H8O3S*C21H16ClF3N4OS2
    N-[4-chloro-3-(trifluoromethyl)phenyl]-[4-(N-methylformamide)(4-pyridylthio)phenyl]thiourea toluenesulfonate
    —— 3-methylcyclohexa-2,5-dien-4-one spiro-1,2'-(1',3'-dithiane) 125016-62-8 C10H12OS2
    3-methylcyclohexa-2,5-dien-4-one spiro-1,2'-(1',3'-dithiane)
    —— 2,2-Bis-methylsulfanyl-malonic acid dimethyl ester 34282-16-1 C7H12O4S2
    2,2-Bis-methylsulfanyl-malonic acid dimethyl ester
    —— <i>cis</i>-1-ethanesulfonyl-2-methylsulfanyl-ethene 30647-68-8 C5H10O2S2
    <i>cis</i>-1-ethanesulfonyl-2-methylsulfanyl-ethene
    —— Acetic acid 7-oxa-bicyclo[4.2.1]non-1-yl ester 27025-20-3 C10H16O3
    Acetic acid 7-oxa-bicyclo[4.2.1]non-1-yl ester
    —— (4-phenylsulfanyl-quinolin-2-yl)-carbamic acid ethyl ester 26625-69-4 C18H16N2O2S
    (4-phenylsulfanyl-quinolin-2-yl)-carbamic acid ethyl ester
    —— 2-p-Chlorphenylthio-4-tert-butyl-pyridin 28856-75-9 C15H16ClNS
    2-p-Chlorphenylthio-4-tert-butyl-pyridin
    —— Trimethylgermyl-dimethyl-sulfoximid 24952-54-3 C5H15GeNOS
    Trimethylgermyl-dimethyl-sulfoximid
    —— [4-(3-Chloro-5-trifluoromethyl-pyridin-2-yl)-pyrimidin-2-ylsulfanyl]-acetic acid 1311278-94-0 C12H7ClF3N3O2S
    [4-(3-Chloro-5-trifluoromethyl-pyridin-2-yl)-pyrimidin-2-ylsulfanyl]-acetic acid
    —— 1<i>c</i>-isopropylsulfanyl-but-1-en-3-yne 19458-02-7 C7H10S
    1<i>c</i>-isopropylsulfanyl-but-1-en-3-yne
    —— N-[[2-(1H-benzimidazol-2-ylsulfanyl)-5-chlorophenyl]carbamothioyl]benzamide 157168-71-3 C21H15ClN4OS2
    N-[[2-(1H-benzimidazol-2-ylsulfanyl)-5-chlorophenyl]carbamothioyl]benzamide
    —— dibromobis(diethylthiocarbamato)tin(IV) 84204-53-5 C10H20Br2N2O2S2Sn
    dibromobis(diethylthiocarbamato)tin(IV)
    —— 1243724-17-5 C28H42N2O3S5
    —— 5-bromo-3-methoxy-2-methylsulfanyl-pyridine 1446002-40-9 C7H8BrNOS
    5-bromo-3-methoxy-2-methylsulfanyl-pyridine
    —— 7-[1,3]dithiolan-2-ylidene-3-methylsulfanyl-2-phenyl-4,5,6,7-tetrahydro-benzo[<i>d</i>]isothiazolium; iodide 62328-37-4 C17H18NS4*I
    7-[1,3]dithiolan-2-ylidene-3-methylsulfanyl-2-phenyl-4,5,6,7-tetrahydro-benzo[<i>d</i>]isothiazolium; iodide
    —— 2-(2-hydroxy-ethanesulfonyl)-propan-1-ol 39093-50-0 C5H12O4S
    2-(2-hydroxy-ethanesulfonyl)-propan-1-ol
    —— 3-nitro-2-phenylsulfanyldecan-4-ol 94421-51-9 C16H25NO3S
    3-nitro-2-phenylsulfanyldecan-4-ol
    —— 1-(Ethylthio)-2-(trimethylsilyl)benzene 128102-33-0 C11H18SSi
    1-(Ethylthio)-2-(trimethylsilyl)benzene
    —— (aquo)(dimethyl sulfoxide)(1,2-diaminoethane)platinium(II) cation 51542-85-9 C4H16N2O2PtS
    (aquo)(dimethyl sulfoxide)(1,2-diaminoethane)platinium(II) cation