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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Prop-2-ynylsulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one 1186646-14-9 C10H10N2OS
    2-Prop-2-ynylsulfanyl-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one
    —— 2-(4,6-diphenethoxypyrimidin-2-ylthio)acetic acid 1077626-45-9 C22H22N2O4S
    2-(4,6-diphenethoxypyrimidin-2-ylthio)acetic acid
    —— 4-Amino-18,20-dimethylspiro[7-thia-3,5,11,15-tetrazatricyclo[15.3.1.12,6]docosa-1(21),2(22),3,5,17,19-hexaene-13,3'-oxetane]-10,16-dione 1052646-64-6 C21H25N5O3S
    4-Amino-18,20-dimethylspiro[7-thia-3,5,11,15-tetrazatricyclo[15.3.1.12,6]docosa-1(21),2(22),3,5,17,19-hexaene-13,3'-oxetane]-10,16-dione
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[3-(trifluoromethyl)phenyl]thio}aniline 1100794-95-3 C21H25ClF3N3S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[3-(trifluoromethyl)phenyl]thio}aniline
    —— 3-[2-(tert-butyldiphenylsilyloxy)ethyl]-6-methylsulfonyl-8-methylsulfanylimidazo[2,1-f ][1,2,4]-triazine 1097624-36-6 C25H30N4O3S2Si
    3-[2-(tert-butyldiphenylsilyloxy)ethyl]-6-methylsulfonyl-8-methylsulfanylimidazo[2,1-f ][1,2,4]-triazine
    —— 5-chloro-N-(3-chloropropyl)-2-(pyridin-2-ylthio)aniline 1100794-79-3 C14H14Cl2N2S
    5-chloro-N-(3-chloropropyl)-2-(pyridin-2-ylthio)aniline
    —— 3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-8-hydrazino-6-methylsulfanylimidazo[2,1-f ][1,2,4]-triazine 1097624-34-4 C24H30N6OSSi
    3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-8-hydrazino-6-methylsulfanylimidazo[2,1-f ][1,2,4]-triazine
    —— 2-[(4-chlorophenyl)thio]-5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]aniline 192388-04-8 C20H25Cl2N3S
    2-[(4-chlorophenyl)thio]-5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]aniline
    —— 2-[2,4-Bis(methylsulfanyl)imidazo[2,1-f][1,2,4]triazin-7-yl]ethyl methanesulfonate 1097624-38-8 C10H14N4O3S3
    2-[2,4-Bis(methylsulfanyl)imidazo[2,1-f][1,2,4]triazin-7-yl]ethyl methanesulfonate
    —— (7'aR)-7'a-(3-hydroxypropyl)spiro[1,3-dithiane-2,5'-2,3,6,7-tetrahydroindene]-1'-one 1108206-50-3 C15H22O2S2
    (7'aR)-7'a-(3-hydroxypropyl)spiro[1,3-dithiane-2,5'-2,3,6,7-tetrahydroindene]-1'-one
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-(1-naphthylthio)aniline 1100794-87-3 C24H28ClN3S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-(1-naphthylthio)aniline
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[4-(trifluoromethyl)phenyl]thio}aniline 1100794-98-6 C21H25ClF3N3S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[4-(trifluoromethyl)phenyl]thio}aniline
    —— 2-[(4-bromophenyl)thio]-5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]aniline 1100794-30-6 C20H25BrClN3S
    2-[(4-bromophenyl)thio]-5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]aniline
    —— 3-[2-(tert-butyldiphenylsilyloxy)ethyl]-8-methylsulfanylimidazo[2,1-f ][1,2,4]triazine 1097624-37-7 C24H28N4OSSi
    3-[2-(tert-butyldiphenylsilyloxy)ethyl]-8-methylsulfanylimidazo[2,1-f ][1,2,4]triazine
    —— 2,4-bis-methylsulfanyl-7-vinyl-imidazo[2,1-f ][1,2,4]triazine 1097624-39-9 C9H10N4S2
    2,4-bis-methylsulfanyl-7-vinyl-imidazo[2,1-f ][1,2,4]triazine
    —— 1-(3-(5-chloro-2-(phenylthio)phenoxy)propyl)-4-methylpiperazine 1100794-04-4 C20H25ClN2OS
    1-(3-(5-chloro-2-(phenylthio)phenoxy)propyl)-4-methylpiperazine
    —— 3-(2-hydroxyethyl)-6,8-bis(methylsulfanyl)imidazo[2,1-f ][1,2,4]triazine 1097624-33-3 C9H12N4OS2
    3-(2-hydroxyethyl)-6,8-bis(methylsulfanyl)imidazo[2,1-f ][1,2,4]triazine
    —— 5-acetylamino-2-(7-chloro-benzothiazol-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide 1102466-83-0 C19H23ClN6O2S2
    5-acetylamino-2-(7-chloro-benzothiazol-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide
    —— 2-[[4-Amino-5-(2-furanyl)-4H-1,2,4-triazol-3-yl]thio]-N-(2-methylcyclohexyl)propanamide 1186646-12-7 C16H23N5O2S
    2-[[4-Amino-5-(2-furanyl)-4H-1,2,4-triazol-3-yl]thio]-N-(2-methylcyclohexyl)propanamide
    —— 5-amino-1-(3-isopropylamino-propyl)-2-(naphthalen-2-ylsulfanyl)-1H-imidazole-4-carboxamide 1102466-77-2 C20H25N5OS
    5-amino-1-(3-isopropylamino-propyl)-2-(naphthalen-2-ylsulfanyl)-1H-imidazole-4-carboxamide
    —— 5-amino-2-(7-chloro-benzothiazol-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide 1102466-71-6 C17H21ClN6OS2
    5-amino-2-(7-chloro-benzothiazol-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide
    —— 5-amino-1-(3-isopropylamino-propyl)-2-(4-phenyl-thiazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide 1102466-79-4 C19H24N6OS2
    5-amino-1-(3-isopropylamino-propyl)-2-(4-phenyl-thiazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide
    —— 2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-5-[(methylsulfonyl)amino]-1H-imidazole-4-carboxamide 1102467-04-8 C13H13BrN4O5S2
    2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-5-[(methylsulfonyl)amino]-1H-imidazole-4-carboxamide
    —— 5-amino-1-(3-isopropylamino-propyl)-2-(1-isopropyl-1H-benzoimidazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide 1102466-73-8 C20H29N7OS
    5-amino-1-(3-isopropylamino-propyl)-2-(1-isopropyl-1H-benzoimidazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide
    —— 5-(acetylamino)-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide 1102467-06-0 C14H13BrN4O4S
    5-(acetylamino)-2-[(6-bromo-1,3-benzodioxol-5-yl)thio]-1-methyl-1H-imidazole-4-carboxamide
    —— 5-amino-2-(3-chloro-5-trifluoromethyl-pyridin-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide 1102466-75-0 C16H20ClF3N6OS
    5-amino-2-(3-chloro-5-trifluoromethyl-pyridin-2-ylsulfanyl)-1-(3-isopropylamino-propyl)-1H-imidazole-4-carboxamide
    —— 5-acetamido-2-(benzo[d][1,3]dioxol-5-ylthio)-1-butyl-1H-imidazole-4-carboxamide 1102466-35-2 C17H20N4O4S
    5-acetamido-2-(benzo[d][1,3]dioxol-5-ylthio)-1-butyl-1H-imidazole-4-carboxamide
    —— N-[5-(ethylthio)-1,3,4-thiadiazol-2-yl]sulfamide 1098266-15-9 C4H8N4O2S3
    N-[5-(ethylthio)-1,3,4-thiadiazol-2-yl]sulfamide
    —— 2-methylthio-4-[N-(2-morpholin-4-ylethyl)amino]-5-nitro-6-phenylethynylpyrimidine 1097967-00-4 C19H21N5O3S
    2-methylthio-4-[N-(2-morpholin-4-ylethyl)amino]-5-nitro-6-phenylethynylpyrimidine
    —— 2-methylsulfanyl-6-(4-morpholin-4-yl-pyridin-2-yl)-pyrimidin-4-ylamine 1082056-77-6 C14H17N5OS
    2-methylsulfanyl-6-(4-morpholin-4-yl-pyridin-2-yl)-pyrimidin-4-ylamine
    —— 1-(2,3-dihydroxypropyl)-2-(methylthio)-5-methylpyrimidin-4(1H)-one 1160617-79-7 C9H14N2O3S
    1-(2,3-dihydroxypropyl)-2-(methylthio)-5-methylpyrimidin-4(1H)-one
    —— 1-(2,3-dihydroxypropyl)-4-(methylthio)pyrimidin-2(1H)-one 1160617-83-3 C8H12N2O3S
    1-(2,3-dihydroxypropyl)-4-(methylthio)pyrimidin-2(1H)-one
    —— 2,4-bis[(2,3-dihydroxypropyl)thio]-6-methylpyrimidine 1160617-89-9 C11H18N2O4S2
    2,4-bis[(2,3-dihydroxypropyl)thio]-6-methylpyrimidine
    —— 1-(2,3-dihydroxypropyl)-4-[(2,3-dihydroxypropyl)thio]-5-methylpyrimidin-2(1H)-one 1160617-72-0 C11H18N2O5S
    1-(2,3-dihydroxypropyl)-4-[(2,3-dihydroxypropyl)thio]-5-methylpyrimidin-2(1H)-one
    —— 1-(2,3-dihydroxypropyl)-4-(methylthio)-5-methylpyrimidin-2(1H)-one 1160617-84-4 C9H14N2O3S
    1-(2,3-dihydroxypropyl)-4-(methylthio)-5-methylpyrimidin-2(1H)-one
    —— 1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]pyrimidin-4(1H)-one 1160617-64-0 C10H16N2O5S
    1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]pyrimidin-4(1H)-one
    —— 1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]-6-methylpyrimidin-4(1H)-one 1160617-65-1 C11H18N2O5S
    1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]-6-methylpyrimidin-4(1H)-one
    —— 1-(2,3-dihydroxypropyl)-2-(methylthio)pyrimidin-4(1H)-one 1160617-76-4 C8H12N2O3S
    1-(2,3-dihydroxypropyl)-2-(methylthio)pyrimidin-4(1H)-one
    —— 2,4-bis[(2,3-dihydroxypropyl)thio]pyrimidine 1160617-88-8 C10H16N2O4S2
    2,4-bis[(2,3-dihydroxypropyl)thio]pyrimidine
    —— 1-(2,3-dihydroxypropyl)-2-(methylthio)-6-methylpyrimidin-4(1H)-one 1160617-78-6 C9H14N2O3S
    1-(2,3-dihydroxypropyl)-2-(methylthio)-6-methylpyrimidin-4(1H)-one
    —— 2,4-bis[(2,3-dihydroxypropyl)thio]-5-methylpyrimidine 1160617-91-3 C11H18N2O4S2
    2,4-bis[(2,3-dihydroxypropyl)thio]-5-methylpyrimidine
    —— 1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]-5-methylpyrimidin-4(1H)-one 1160617-66-2 C11H18N2O5S
    1-(2,3-dihydroxypropyl)-2-[(2,3-dihydroxypropyl)thio]-5-methylpyrimidin-4(1H)-one
    —— 6-[6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-3-ylsulfanyl]-quinoline 1086329-96-5 C16H11N7S2
    6-[6-(1-methyl-1H-pyrazol-4-yl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-3-ylsulfanyl]-quinoline
    —— 3-[(4-fluorophenyl)sulfanyl]-N-(1-methyl-1H-pyrazol-3-yl)-6-(4H-1,2,4-triazol-3-ylsulfanyl)pyrazine-2-carboxamide 1093382-48-9 C17H13FN8OS2
    3-[(4-fluorophenyl)sulfanyl]-N-(1-methyl-1H-pyrazol-3-yl)-6-(4H-1,2,4-triazol-3-ylsulfanyl)pyrazine-2-carboxamide
    —— cis-3-Methyl-1-phenylmercapto-butadien-(1,3) 16627-78-4 C11H12S
    cis-3-Methyl-1-phenylmercapto-butadien-(1,3)
    —— trimethyl-[(3Z)-3-[3-(2-propan-2-yl-1,3-dithiolan-2-yl)prop-2-ynylidene]hept-1-ynyl]silane 1072800-73-7 C19H30S2Si
    trimethyl-[(3Z)-3-[3-(2-propan-2-yl-1,3-dithiolan-2-yl)prop-2-ynylidene]hept-1-ynyl]silane
    —— (E)-7-phenylsulfanyldodec-7-en-6-ol 1094759-22-4 C18H28OS
    (E)-7-phenylsulfanyldodec-7-en-6-ol
    —— (E)-1-phenylthio-3-(tetrahydropyran-2-yl)oxy-1-propene 1094758-96-9 C14H18O2S
    (E)-1-phenylthio-3-(tetrahydropyran-2-yl)oxy-1-propene
    —— 2,4-bis-benzylsulfanyl-6-phenethyl-pyrimidine 1067679-04-2 C26H24N2S2
    2,4-bis-benzylsulfanyl-6-phenethyl-pyrimidine
    —— 2,4,6-tris-benzylsulfanyl-pyrimidine 1067679-79-1 C25H22N2S3
    2,4,6-tris-benzylsulfanyl-pyrimidine