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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-chloro-6-(1-methylpyrrolidin-3-ylmethylsulfanyl)pyridine 752972-52-4 C11H15ClN2S
    2-chloro-6-(1-methylpyrrolidin-3-ylmethylsulfanyl)pyridine
    —— 4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-69-9 C20H19FN2O2S2
    4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-53-1 C20H19FN2O3S
    4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— N-Methallylthiocarbamidsaeure-O-ethylester 64454-48-4 C7H13NOS
    N-Methallylthiocarbamidsaeure-O-ethylester
    —— 5-acetyl-4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-54-2 C19H17FN2O2S
    5-acetyl-4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 1-{4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone 1173658-70-2 C19H17FN2OS2
    1-{4-[4-(4-fluoro-phenylsulfanyl)-phenyl]-6-methyl-2-thioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-ethanone
    —— Benzamide, 4-[[4-[(4,5-dihydro-1H-imidazol-2-yl)amino]phenyl]thio]- 827610-38-8 C16H16N4OS
    Benzamide, 4-[[4-[(4,5-dihydro-1H-imidazol-2-yl)amino]phenyl]thio]-
    —— 6-[1-(2,6-difluorophenyl)ethyl]-3,4-dihydro-2-methylthiopyrimidin-4(3H)-one 255898-88-5 C13H12F2N2OS
    6-[1-(2,6-difluorophenyl)ethyl]-3,4-dihydro-2-methylthiopyrimidin-4(3H)-one
    —— Pyrrolidine, 1-[[4-[(4-methoxyphenyl)thio]phenyl]methyl]- 677343-21-4 C18H21NOS
    Pyrrolidine, 1-[[4-[(4-methoxyphenyl)thio]phenyl]methyl]-
    —— 1-benzylsulfanyl-3-bromo-2-ethylbenzene 1182728-08-0 C15H15BrS
    1-benzylsulfanyl-3-bromo-2-ethylbenzene
    —— N-(3-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-ylthio)propyl)acetamide 1266480-74-3 C15H24BNO3S2
    N-(3-(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-ylthio)propyl)acetamide
    —— N-(3-(5-bromothiophen-2-ylthio)propyl)acetamide 1266480-73-2 C9H12BrNOS2
    N-(3-(5-bromothiophen-2-ylthio)propyl)acetamide
    —— 5-((3,5-dichloropyridin-4-yl)thio)-N-(2-(methylthio)ethyl)-4-nitrothiophene-2-carboxamide 1247820-36-5 C13H11Cl2N3O3S3
    5-((3,5-dichloropyridin-4-yl)thio)-N-(2-(methylthio)ethyl)-4-nitrothiophene-2-carboxamide
    —— 3-cyclohexyl-2-(phenylthio)-1,3-butadiene 144453-31-6 C16H20S
    3-cyclohexyl-2-(phenylthio)-1,3-butadiene
    —— N-[2-(4-bromo-phenylsulfanyl)-ethyl]-i-propanesulfonamide 851199-48-9 C11H16BrNO2S2
    N-[2-(4-bromo-phenylsulfanyl)-ethyl]-i-propanesulfonamide
    —— N-[2-((4(4,4,5,5-tetramethyl)-[1,3,2]dioxaborolan-2-yl)phenylsulfanyl)-ethyl]-i-propanesulfonamide 851199-52-5 C17H28BNO4S2
    N-[2-((4(4,4,5,5-tetramethyl)-[1,3,2]dioxaborolan-2-yl)phenylsulfanyl)-ethyl]-i-propanesulfonamide
    —— Ethanethiol, 2,2'-[1,3,4-thiadiazole-2,5-diylbis(thio)]bis- 194918-42-8 C6H10N2S5
    Ethanethiol, 2,2'-[1,3,4-thiadiazole-2,5-diylbis(thio)]bis-
    —— 1,3,4,5-tetramethyl-2[(2-oxopropyl)thio]imidazolium chloride 134218-50-1 C10H17N2OS*Cl
    1,3,4,5-tetramethyl-2[(2-oxopropyl)thio]imidazolium chloride
    —— 2-(4-Methoxyphenyl)sulfanyl-6-nitrobenzonitrile 168910-87-0 C14H10N2O3S
    2-(4-Methoxyphenyl)sulfanyl-6-nitrobenzonitrile
    —— 8-methylthiopyrazolo<5,1-c><1,2,4>benzotriazine 5-oxide 177158-66-6 C10H8N4OS
    8-methylthiopyrazolo<5,1-c><1,2,4>benzotriazine 5-oxide
    —— N'-cyclopentyl-methyl-thiourea 117694-94-7 C7H14N2S
    N'-cyclopentyl-methyl-thiourea
    —— 2-chloro-6-(1-methylpiperidin-3-ylmethylsulfanyl)pyridine 289677-77-6 C12H17ClN2S
    2-chloro-6-(1-methylpiperidin-3-ylmethylsulfanyl)pyridine
    —— (E)-3-[1-Benzenesulfonyl-3-(3-benzyloxymethyl-2-phenylsulfanyl-3H-imidazol-4-yl)-1H-indol-2-yl]-acrylic acid ethyl ester 391913-52-3 C36H31N3O5S2
    (E)-3-[1-Benzenesulfonyl-3-(3-benzyloxymethyl-2-phenylsulfanyl-3H-imidazol-4-yl)-1H-indol-2-yl]-acrylic acid ethyl ester
    —— 2-methylpropanedithioperoxy acid methyl ester 118087-46-0 C5H10OS2
    2-methylpropanedithioperoxy acid methyl ester
    —— 1,2-bis-(2-ethoxy-ethanesulfonyl)-ethane 343595-56-2 C10H22O6S2
    1,2-bis-(2-ethoxy-ethanesulfonyl)-ethane
    —— Cyclopropanecarboxaldehyde, 3-methyl-2,2-bis(phenylthio)-, trans- 90141-35-8 C17H16OS2
    Cyclopropanecarboxaldehyde, 3-methyl-2,2-bis(phenylthio)-, trans-
    —— 3-isopropyl-5-prop-2-ynylsulfanyl-1<i>H</i>-[1,2,4]triazole 58876-06-5 C8H11N3S
    3-isopropyl-5-prop-2-ynylsulfanyl-1<i>H</i>-[1,2,4]triazole
    —— 2-[(3E)-7-chloro-4,8-dimethylnona-3,8-dienyl]-2-methyl-1,3-dithiane 142669-96-3 C16H27ClS2
    2-[(3E)-7-chloro-4,8-dimethylnona-3,8-dienyl]-2-methyl-1,3-dithiane
    —— methyl 2-{[3-({[tert-butyl(dimethyl)silyl]oxy}methyl)-2-methylphenyl]sulfanyl}acetate 339544-50-2 C17H28O3SSi
    methyl 2-{[3-({[tert-butyl(dimethyl)silyl]oxy}methyl)-2-methylphenyl]sulfanyl}acetate
    —— 5-ethylsulfanyl-N-phenyl-1,3,4-thiadiazol-2-amine 50432-47-8 C10H11N3S2
    5-ethylsulfanyl-N-phenyl-1,3,4-thiadiazol-2-amine
    —— 2-ethylsulfanyl-5-(methylcarbamothioylamino)-1H-pyrrole-3,4-dicarboxamide 153621-09-1 C10H15N5O2S2
    2-ethylsulfanyl-5-(methylcarbamothioylamino)-1H-pyrrole-3,4-dicarboxamide
    —— 5-Ethylthio-2-aminopyrrol-3,4-dicarbonsaeurediamid 128815-97-4 C8H12N4O2S
    5-Ethylthio-2-aminopyrrol-3,4-dicarbonsaeurediamid
    —— 1-phenylmercapto-2-methylbut-2Z-en-4-ol 95684-44-9 C11H14OS
    1-phenylmercapto-2-methylbut-2Z-en-4-ol
    —— 6,6-dimethyl-3-methylthio-1-(1-(tert-butyloxycarbonyl)pyrrol-2-yl)-6,7-dihydro-2-benzothiophen-4(5H)-one 207307-85-5 C20H25NO3S2
    6,6-dimethyl-3-methylthio-1-(1-(tert-butyloxycarbonyl)pyrrol-2-yl)-6,7-dihydro-2-benzothiophen-4(5H)-one
    —— 4-(1,3-Benzodithiol-2-ylidene)-2,6-diphenylpyran 104845-93-4 C24H16OS2
    4-(1,3-Benzodithiol-2-ylidene)-2,6-diphenylpyran
    —— (3aRS,4RS,6aSR)-4-phenylsulfanylmethyl-3,3a,4,6a-tetrahydrocyclopenta[b]furan-2-one —— C14H14O2S
    (3aRS,4RS,6aSR)-4-phenylsulfanylmethyl-3,3a,4,6a-tetrahydrocyclopenta[b]furan-2-one
    —— 2-<(α-Methylbenzyl)thio>phenol 29549-70-0 C14H14OS
    2-<(α-Methylbenzyl)thio>phenol
    —— Lithium, [2-(methylthio)phenyl]- 51894-94-1 C7H7LiS
    Lithium, [2-(methylthio)phenyl]-
    —— (<i>E</i>)-1-methanesulfinyl-2-methyl-buta-1,3-diene 55833-46-0 C6H10OS
    (<i>E</i>)-1-methanesulfinyl-2-methyl-buta-1,3-diene
    —— (+/-)-methyl 1-propynyl sulfoxide 55833-42-6 C4H6OS
    (+/-)-methyl 1-propynyl sulfoxide
    —— 1-(1-Propylsulfinylethylsulfinyl)propane 130385-37-4 C8H18O2S2
    1-(1-Propylsulfinylethylsulfinyl)propane
    —— ethyl 4-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydro-2-naphthylthio)benzoate 179762-68-6 C24H30O2S
    ethyl 4-(3,5,5,8,8-pentamethyl-5,6,7,8-tetrahydro-2-naphthylthio)benzoate
    —— 6-(4-chlorobenzyl)-3-(methylsulfanyl)-1,2,4-triazin-5(4H)-one 118779-02-5 C11H10ClN3OS
    6-(4-chlorobenzyl)-3-(methylsulfanyl)-1,2,4-triazin-5(4H)-one
    —— 6-[(4-Chlorophenyl)methyl]-3-methylsulfanyl-4-phenyl-1,2,4-triazin-5-one 117530-80-0 C17H14ClN3OS
    6-[(4-Chlorophenyl)methyl]-3-methylsulfanyl-4-phenyl-1,2,4-triazin-5-one
    —— 10,10-(ethylenedithio)-2,6-dimethylundec-6E-en-3-one 251636-37-0 C15H26OS2
    10,10-(ethylenedithio)-2,6-dimethylundec-6E-en-3-one
    —— 4-Tert-butyl-2-(2-phenylsulfanylphenyl)sulfanylphenol 163774-58-1 C22H22OS2
    4-Tert-butyl-2-(2-phenylsulfanylphenyl)sulfanylphenol
    —— (4S,5R)-5-Pentadec-12-ynyl-2-thioxo-[1,3]dioxolane-4-carboxylic acid ethyl ester 1055030-43-7 C21H34O4S
    (4S,5R)-5-Pentadec-12-ynyl-2-thioxo-[1,3]dioxolane-4-carboxylic acid ethyl ester
    —— phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside 241490-66-4 C20H25NO3S
    phenyl 3-(O-benzylhydroxyamino)-2,3,6-trideoxy-3-C-methyl-1-thio-α-ribo-hexopyranoside
    —— 8-Chloro-3-methyl-5,5-dioxo-imidazo[1,2-b][1,4,2]benzodithiazine-7-carboxylic acid 885042-19-3 C11H7ClN2O4S2
    8-Chloro-3-methyl-5,5-dioxo-imidazo[1,2-b][1,4,2]benzodithiazine-7-carboxylic acid
    —— 2-tert-butylthio-3-(pyrrolidin-1-yl)cyclopropenethione 172039-95-1 C11H17NS2
    2-tert-butylthio-3-(pyrrolidin-1-yl)cyclopropenethione