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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Isocyanato-4-[(2-methylpropyl)sulfanyl]benzene 58555-11-6 C11H13NOS
    1-Isocyanato-4-[(2-methylpropyl)sulfanyl]benzene
    —— 2-[2-Hydroxy-3-(2-hydroxyphenyl)sulfanylpropyl]sulfanylphenol 58952-74-2 C15H16O3S2
    2-[2-Hydroxy-3-(2-hydroxyphenyl)sulfanylpropyl]sulfanylphenol
    —— 4-phenylthiobut-2-yn-1-amine 586976-04-7 C10H11NS
    4-phenylthiobut-2-yn-1-amine
    —— 2-{9-[2-(4-[1,3]Dithian-2-yl-butyl)-[1,3]dithian-2-yl]-nonyl}-[1,3]dioxolane 59014-61-8 C24H44O2S4
    2-{9-[2-(4-[1,3]Dithian-2-yl-butyl)-[1,3]dithian-2-yl]-nonyl}-[1,3]dioxolane
    —— 1,1,1-Trifluor-3-trifluormethansulfonyl-aceton 58510-76-2 C4H2F6O3S
    1,1,1-Trifluor-3-trifluormethansulfonyl-aceton
    —— 4-[(3-Chloroprop-2-en-1-yl)sulfanyl]benzene-1,2-diamine 58841-09-1 C9H11ClN2S
    4-[(3-Chloroprop-2-en-1-yl)sulfanyl]benzene-1,2-diamine
    —— 2-(Heptadecane-1-sulfinyl)ethan-1-ol 58840-41-8 C19H40O2S
    2-(Heptadecane-1-sulfinyl)ethan-1-ol
    —— 1,1-Bis(trifluoromethanesulfonyl)penta-1,3-diene 58510-89-7 C7H6F6O4S2
    1,1-Bis(trifluoromethanesulfonyl)penta-1,3-diene
    —— 1-Isocyanato-4-[(propan-2-yl)sulfanyl]benzene 58555-10-5 C10H11NOS
    1-Isocyanato-4-[(propan-2-yl)sulfanyl]benzene
    —— 2-Amino-1,1-bis-trifluormethansulfonyl-ethen 58510-92-2 C4H3F6NO4S2
    2-Amino-1,1-bis-trifluormethansulfonyl-ethen
    —— 4-(Phenylselanyl)-3-(phenylsulfanyl)but-3-en-1-ol 582290-45-7 C16H16OSSe
    4-(Phenylselanyl)-3-(phenylsulfanyl)but-3-en-1-ol
    —— Pent-4-enethioic acid dimethylamide 58170-52-8 C7H13NS
    Pent-4-enethioic acid dimethylamide
    —— 3,3-dimethyl-4-methylsulfanyl-hex-1-ene 57121-78-5 C9H18S
    3,3-dimethyl-4-methylsulfanyl-hex-1-ene
    —— 4-ethylsulfanyl-3,3-dimethyl-hex-1-ene 57121-80-9 C10H20S
    4-ethylsulfanyl-3,3-dimethyl-hex-1-ene
    —— 1-Methylsulfanyl-2-[4-(2-methylsulfanylphenyl)sulfanylbutylsulfanyl]benzene 56977-03-8 C18H22S4
    1-Methylsulfanyl-2-[4-(2-methylsulfanylphenyl)sulfanylbutylsulfanyl]benzene
    —— 1-Methylsulfanyl-2-[3-(2-methylsulfanylphenyl)sulfanylpropylsulfanyl]benzene 56977-02-7 C17H20S4
    1-Methylsulfanyl-2-[3-(2-methylsulfanylphenyl)sulfanylpropylsulfanyl]benzene
    —— 4-methoxy-2,6-dimethyl-4<i>H</i>-[1,4]thiaphosphinine 4-oxide 57044-91-4 C7H11O2PS
    4-methoxy-2,6-dimethyl-4<i>H</i>-[1,4]thiaphosphinine 4-oxide
    —— 2-Amino-4-methoxy-6-methylthio-pyrimidin 56922-40-8 C6H9N3OS
    2-Amino-4-methoxy-6-methylthio-pyrimidin
    —— 3-(N,N-Dimethylaminomethylen)-2(3H)-benzothiophenon 56429-30-2 C11H11NOS
    3-(N,N-Dimethylaminomethylen)-2(3H)-benzothiophenon
    —— {[(2,6,6-Trimethylcyclohex-2-en-1-yl)methyl]sulfanyl}benzene 56691-70-4 C16H22S
    {[(2,6,6-Trimethylcyclohex-2-en-1-yl)methyl]sulfanyl}benzene
    —— N-[3-(Diethylamino)butyl]thiourea 928122-16-1 C9H21N3S
    N-[3-(Diethylamino)butyl]thiourea
    —— Ethyl {[(prop-2-en-1-yl)carbamoyl]sulfanyl}acetate 56235-27-9 C8H13NO3S
    Ethyl {[(prop-2-en-1-yl)carbamoyl]sulfanyl}acetate
    —— 3,3'-(Hexane-1,6-diyldisulfanediyl)bis(2,5-dibromothiophene) 928329-34-4 C14H14Br4S4
    3,3'-(Hexane-1,6-diyldisulfanediyl)bis(2,5-dibromothiophene)
    —— 4-[(Oxan-2-yl)oxy]-2,6-bis[(phenylsulfanyl)methyl]pyridine 925695-01-8 C24H25NO2S2
    4-[(Oxan-2-yl)oxy]-2,6-bis[(phenylsulfanyl)methyl]pyridine
    —— 6-(2,2-Diethoxyethoxy)-2-(methylsulfanyl)pyrimidin-4-amine 928468-02-4 C11H19N3O3S
    6-(2,2-Diethoxyethoxy)-2-(methylsulfanyl)pyrimidin-4-amine
    —— 2,2'-(Butane-1,4-diyldisulfanediyl)bis(1,3,4-thiadiazole) 927384-67-6 C8H10N4S4
    2,2'-(Butane-1,4-diyldisulfanediyl)bis(1,3,4-thiadiazole)
    —— 1-Hexylsulfinylhexane;hydrochloride 924266-35-3 C12H27ClOS
    1-Hexylsulfinylhexane;hydrochloride
    —— N,N-Diethyl-4-methyl-4,5-dihydro-3H-pyrazole-3-carbothioamide 923275-58-5 C9H17N3S
    N,N-Diethyl-4-methyl-4,5-dihydro-3H-pyrazole-3-carbothioamide
    —— 3,7-Dimethyl-1-(phenylsulfanyl)oct-6-EN-1-YN-3-OL 923002-16-8 C16H20OS
    3,7-Dimethyl-1-(phenylsulfanyl)oct-6-EN-1-YN-3-OL
    —— 1-Chloro-2,3-bis-ethylsulfanyl-propane 923057-17-4 C7H15ClS2
    1-Chloro-2,3-bis-ethylsulfanyl-propane
    —— 1-Bromo-2,3-bis(ethylsulfanyl)propane 923057-18-5 C7H15BrS2
    1-Bromo-2,3-bis(ethylsulfanyl)propane
    —— 2-Bromo-1,3-bis(ethylsulfanyl)propane 923057-19-6 C7H15BrS2
    2-Bromo-1,3-bis(ethylsulfanyl)propane
    —— 4-Bromo-1-ethenyl-5-(methylsulfanyl)-1H-pyrazole 923036-05-9 C6H7BrN2S
    4-Bromo-1-ethenyl-5-(methylsulfanyl)-1H-pyrazole
    —— 4-Amino-6-(methylsulfanyl)-2-(tetradecylsulfanyl)pyrimidine-5-carbonitrile 922526-96-3 C20H34N4S2
    4-Amino-6-(methylsulfanyl)-2-(tetradecylsulfanyl)pyrimidine-5-carbonitrile
    —— 4-Amino-2-(hexadecylsulfanyl)-6-(methylsulfanyl)pyrimidine-5-carbonitrile 922526-97-4 C22H38N4S2
    4-Amino-2-(hexadecylsulfanyl)-6-(methylsulfanyl)pyrimidine-5-carbonitrile
    —— 2-Methyl-3-phenylmercapto-propionsaeure-butylester 30039-26-0 C14H20O2S
    2-Methyl-3-phenylmercapto-propionsaeure-butylester
    —— O2-(2-methylsulfonylethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate 1404220-19-4 C6H15N3O4S
    O2-(2-methylsulfonylethyl) 1-(isopropylamino)diazen-1-ium-1,2-diolate
    —— 6-[6-Amino-9-[2-(1-formylpiperidin-4-yl)ethyl]purin-8-yl]sulfanyl-1,3-benzodioxole-5-carbonitrile 1396789-79-9 C21H21N7O3S
    6-[6-Amino-9-[2-(1-formylpiperidin-4-yl)ethyl]purin-8-yl]sulfanyl-1,3-benzodioxole-5-carbonitrile
    —— 2-[(2,4-Difluorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole 1404052-49-8 C13H8F2N4OS
    2-[(2,4-Difluorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole
    —— N-[4-methyl-5-(2-pyridin-3-ylsulfanyl-1,3-oxazol-5-yl)-1,3-thiazol-2-yl]acetamide 1415569-82-2 C14H12N4O2S2
    N-[4-methyl-5-(2-pyridin-3-ylsulfanyl-1,3-oxazol-5-yl)-1,3-thiazol-2-yl]acetamide
    —— 2-[(2-bromobenzyl)thio]-5-(pyrazin-2-yl)-1,3,4-oxadiazole 1404052-43-2 C13H9BrN4OS
    2-[(2-bromobenzyl)thio]-5-(pyrazin-2-yl)-1,3,4-oxadiazole
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole 1404052-47-6 C13H9ClN4OS
    2-[(4-Chlorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole
    —— [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 1,3-oxazole-5-carboxylate 1403457-39-5 C15H11N3O5S
    [6-[(4-Methylpyrimidin-2-yl)sulfanylmethyl]-4-oxopyran-3-yl] 1,3-oxazole-5-carboxylate
    —— 1-[4-[2-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]ethyl]piperidin-1-yl]propane-1,2-dione 1396789-92-6 C22H23BrN6O4S
    1-[4-[2-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]ethyl]piperidin-1-yl]propane-1,2-dione
    —— 2-[(3-Bromophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole 1404052-45-4 C13H9BrN4OS
    2-[(3-Bromophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole
    —— (Z)-[(2-methylpropan-2-yl)oxycarbonyl-propan-2-ylamino]-(2-methylsulfonylethoxyimino)-oxidoazanium 1404220-35-4 C11H23N3O6S
    (Z)-[(2-methylpropan-2-yl)oxycarbonyl-propan-2-ylamino]-(2-methylsulfonylethoxyimino)-oxidoazanium
    —— 2-[(3-Chlorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole 1404052-44-3 C13H9ClN4OS
    2-[(3-Chlorophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole
    —— 2-[(2,6-difluorobenzyl)thio]-5-(pyrazin-2-yl)-1,3,4-oxadiazole 1404052-50-1 C13H8F2N4OS
    2-[(2,6-difluorobenzyl)thio]-5-(pyrazin-2-yl)-1,3,4-oxadiazole
    —— 4-[(4-Bromophenyl)Sulfanyl]Phthalonitrile 1415344-05-6 C14H7BrN2S
    4-[(4-Bromophenyl)Sulfanyl]Phthalonitrile
    —— 2-[(4-Bromophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole 1404052-48-7 C13H9BrN4OS
    2-[(4-Bromophenyl)methylsulfanyl]-5-pyrazin-2-yl-1,3,4-oxadiazole