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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3S,4R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-4-phenyl-3-phenylsulfanyloxolan-2-one 144728-54-1 C33H34O3SSi
    (3S,4R,5S)-5-[[tert-butyl(diphenyl)silyl]oxymethyl]-4-phenyl-3-phenylsulfanyloxolan-2-one
    —— (2R)-3-methyl-[(2-methylprop-2-enyl)thio]butan-1-ol 216376-35-1 C9H18OS
    (2R)-3-methyl-[(2-methylprop-2-enyl)thio]butan-1-ol
    —— Agn-PC-0nfkdq 188969-07-5 C22H26S5
    Agn-PC-0nfkdq
    —— α-fluoro-α-[2-(4-phenylthiazolyl)thio]acetonitrile 493046-83-6 C11H7FN2S2
    α-fluoro-α-[2-(4-phenylthiazolyl)thio]acetonitrile
    —— O-[(1S,2R)-1-[(4R)-2,2-ditert-butyl-1,3,2-dioxasilinan-4-yl]-3-hydroxy-2-methylpropyl] methylsulfanylmethanethioate 213742-02-0 C17H34O4S2Si
    O-[(1S,2R)-1-[(4R)-2,2-ditert-butyl-1,3,2-dioxasilinan-4-yl]-3-hydroxy-2-methylpropyl] methylsulfanylmethanethioate
    —— (R)-2-Methyl-5-phenylsulfanyl-2-vinyl-pentanoic acid ethyl ester 185039-11-6 C16H22O2S
    (R)-2-Methyl-5-phenylsulfanyl-2-vinyl-pentanoic acid ethyl ester
    —— 1-[(Phenylthio)methyl]cyclopropanamine 437985-45-0 C10H13NS
    1-[(Phenylthio)methyl]cyclopropanamine
    —— 1-[1-(4-methylthio-phenyl)-ethyl]-biguanide 779308-02-0 C11H17N5S
    1-[1-(4-methylthio-phenyl)-ethyl]-biguanide
    —— 1-(2-Benzylsulfanyl-benzyl)-5-hydroxy-pyrrolidin-2-one 226088-34-2 C18H19NO2S
    1-(2-Benzylsulfanyl-benzyl)-5-hydroxy-pyrrolidin-2-one
    —— (Z)-2-(phenylthio)but-2-ene 35347-59-2 C10H12S
    (Z)-2-(phenylthio)but-2-ene
    —— tert-Butyl-dimethyl-[1-((1R,2R)-1-oxo-2-propyl-1λ<sup>4</sup>-[1,3]dithiolan-2-yl)-vinyloxy]-silane 1026527-34-3 C14H28O2S2Si
    tert-Butyl-dimethyl-[1-((1R,2R)-1-oxo-2-propyl-1λ<sup>4</sup>-[1,3]dithiolan-2-yl)-vinyloxy]-silane
    —— [(4S,5S)-5-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-methanol 169899-79-0 C16H24O3S
    [(4S,5S)-5-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-methanol
    —— S-(2-chloro-4-fluoro-5-aminophenyl)dimethylthiocarbamate 105586-18-3 C9H10ClFN2OS
    S-(2-chloro-4-fluoro-5-aminophenyl)dimethylthiocarbamate
    —— (3R,4R)-1-Phenylsulfanyl-non-8-ene-3,4-diol 180693-00-9 C15H22O2S
    (3R,4R)-1-Phenylsulfanyl-non-8-ene-3,4-diol
    —— (Z)-1-(tributylstannyl)-1-[(trifluoromethyl)sulfonyl]oct-1-ene 176312-45-1 C21H41F3O2SSn
    (Z)-1-(tributylstannyl)-1-[(trifluoromethyl)sulfonyl]oct-1-ene
    —— 4-Methyl-2-phenylsulfanyl-pent-3-enal 115205-39-5 C12H14OS
    4-Methyl-2-phenylsulfanyl-pent-3-enal
    —— (3R,3aR,6R,8aR,4'S)-3-(2',2'-dimethyl-1',3'-dioxan-4'-yl)-8-methoxy-8a-trifluoroacetoxymethyl-7-phenylthio-1,2,3,6-tetrahydro03a,6-epoxyazulene 256343-66-5 C25H27F3O6S
    (3R,3aR,6R,8aR,4'S)-3-(2',2'-dimethyl-1',3'-dioxan-4'-yl)-8-methoxy-8a-trifluoroacetoxymethyl-7-phenylthio-1,2,3,6-tetrahydro03a,6-epoxyazulene
    —— 1-p-Tolylsulfanyl-decan-2-one 126882-45-9 C17H26OS
    1-p-Tolylsulfanyl-decan-2-one
    —— 1,1,1-trifluoromethyl-3-chloropropane-2-thiol 95356-47-1 C3H4ClF3S
    1,1,1-trifluoromethyl-3-chloropropane-2-thiol
    —— 1,1,1-trifluoro-3-phenyl-3-phenylthio-2-propanone 177747-66-9 C15H11F3OS
    1,1,1-trifluoro-3-phenyl-3-phenylthio-2-propanone
    —— 1,1,2,2,3,3,5,5-Octamethyl-4,6-bis(phenylsulfanyl)-1,2,3,5-tetrasilinane 253589-50-3 C22H36S2Si4
    1,1,2,2,3,3,5,5-Octamethyl-4,6-bis(phenylsulfanyl)-1,2,3,5-tetrasilinane
    —— (1E,4Z,6Z)-6-cyano-1-ethoxy-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trien-3-ol 403719-66-4 C26H29NO2S2
    (1E,4Z,6Z)-6-cyano-1-ethoxy-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trien-3-ol
    —— N-[(2-bromophenyl)methyl]-2-methylsulfinyl-N-(2-phenylsulfanylcyclohexen-1-yl)acetamide 205446-78-2 C22H24BrNO2S2
    N-[(2-bromophenyl)methyl]-2-methylsulfinyl-N-(2-phenylsulfanylcyclohexen-1-yl)acetamide
    —— 5,6-dihydro-1,3-dithiolo<4,5-b><1,4>oxathiin-2-thione 175844-46-9 C5H4OS4
    5,6-dihydro-1,3-dithiolo<4,5-b><1,4>oxathiin-2-thione
    —— 5,6-dihydro-1,4-dithiin 605671-62-3 C6H10OS2
    5,6-dihydro-1,4-dithiin
    —— 2-trifluoromethyl-3-(1,3-dithianyl)-7-methyl-1,6,8-nonatriene 160089-09-8 C14H19F3S2
    2-trifluoromethyl-3-(1,3-dithianyl)-7-methyl-1,6,8-nonatriene
    —— (+/-)-1-(dimethylcarbamoyloxy)-2,2,4-trimethyl-3-phenylthiomethyl-1-vinyl-3-cyclohexene 162708-84-1 C21H29NO2S
    (+/-)-1-(dimethylcarbamoyloxy)-2,2,4-trimethyl-3-phenylthiomethyl-1-vinyl-3-cyclohexene
    —— dihydromirabazole C 155158-73-9 C18H26N4S4
    dihydromirabazole C
    —— 3-[2-[(8Z,11Z)-heptadeca-8,11-dienyl]-1,3-dithian-2-yl]propane-1,2-diol 160030-62-6 C24H44O2S2
    3-[2-[(8Z,11Z)-heptadeca-8,11-dienyl]-1,3-dithian-2-yl]propane-1,2-diol
    —— (E)-11-(2-hexyl-1,3-dithiolan-2-yl)undec-4-enoyl chloride 172331-01-0 C20H35ClOS2
    (E)-11-(2-hexyl-1,3-dithiolan-2-yl)undec-4-enoyl chloride
    —— (1R,2S)-2-methylcyclopropanecarbothioic acid {1-hydroxymethyl-5-[(1S,2R,1'S,2'S)-2'-((3R)-3-methoxyhex-5-enyl)-2'-methylbicyclopropyl-2-yl]pent-2-enyl}amide 431982-23-9 C25H41NO2S
    (1R,2S)-2-methylcyclopropanecarbothioic acid {1-hydroxymethyl-5-[(1S,2R,1'S,2'S)-2'-((3R)-3-methoxyhex-5-enyl)-2'-methylbicyclopropyl-2-yl]pent-2-enyl}amide
    —— 4-Bromo-5-[(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 171780-62-4 C22H25BrN2O5S
    4-Bromo-5-[(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 3-amino-3-cyano-2-(methylthio)-Δ<sup>1</sup>-pyrroline 61254-36-2 C7H9N3OS
    3-amino-3-cyano-2-(methylthio)-Δ<sup>1</sup>-pyrroline
    —— 3-p-fluoro(phenylthio)-2-nonenal 167223-45-2 C15H19FOS
    3-p-fluoro(phenylthio)-2-nonenal
    —— (2R,4R)-2-methyl-4-(phenylsulfanylmethyl)pentane-1,5-diol 191660-23-8 C13H20O2S
    (2R,4R)-2-methyl-4-(phenylsulfanylmethyl)pentane-1,5-diol
    —— (R)-2-Formyl-2-methyl-5-phenylsulfanyl-pentanoic acid ethyl ester 185039-10-5 C15H20O3S
    (R)-2-Formyl-2-methyl-5-phenylsulfanyl-pentanoic acid ethyl ester
    —— 8-amino-4-dimethylaminopyrimido[4,5-b]-1,4-benzothiazepine 874120-42-0 C13H13N5S
    8-amino-4-dimethylaminopyrimido[4,5-b]-1,4-benzothiazepine
    —— 1-methyl-3-phenylsulfanyl-2-pyrrolidinone 59953-50-3 C11H13NOS
    1-methyl-3-phenylsulfanyl-2-pyrrolidinone
    —— MESNET 668470-70-0 C18H21NOS
    MESNET
    —— (4S,5S)-4-Methoxymethyl-5-(4-methylsulfanyl-phenyl)-2-phenyl-4,5-dihydro-oxazole 290810-34-3 C18H19NO2S
    (4S,5S)-4-Methoxymethyl-5-(4-methylsulfanyl-phenyl)-2-phenyl-4,5-dihydro-oxazole
    —— 3-(p-chlorophenylthio)butan-1-ol 55010-10-1 C10H13ClOS
    3-(p-chlorophenylthio)butan-1-ol
    —— 3-methylsulfanyl-6-(2,3,5-trichlorophenyl)-4H-1,2,4-triazin-5-one 597559-60-9 C10H6Cl3N3OS
    3-methylsulfanyl-6-(2,3,5-trichlorophenyl)-4H-1,2,4-triazin-5-one
    —— Ethanol, 2-(pentylsulfinyl)- 343269-32-9 C7H16O2S
    Ethanol, 2-(pentylsulfinyl)-
    —— 2-Hydroxy-1-{2-[2-(4-hydroxy-phenyl)-ethyl]-[1,3]dithian-2-yl}-heptadecan-4-one 443957-50-4 C29H48O3S2
    2-Hydroxy-1-{2-[2-(4-hydroxy-phenyl)-ethyl]-[1,3]dithian-2-yl}-heptadecan-4-one
    —— Pyrimidine, 1,4,5,6-tetrahydro-2-[4-[(4-methoxyphenyl)thio]phenyl]- 677343-17-8 C17H18N2OS
    Pyrimidine, 1,4,5,6-tetrahydro-2-[4-[(4-methoxyphenyl)thio]phenyl]-
    —— O-ethyl (2-methyl-4-oxopentan-2-yl)sulfanylmethanethioate 2048-96-6 C9H16O2S2
    O-ethyl (2-methyl-4-oxopentan-2-yl)sulfanylmethanethioate
    —— 6-amino-3-methyl-2-methylsulfanyl-5-nitro-3<i>H</i>-pyrimidin-4-one 31469-60-0 C6H8N4O3S
    6-amino-3-methyl-2-methylsulfanyl-5-nitro-3<i>H</i>-pyrimidin-4-one
    —— N,N-dimethyl-2-(2'-aminophenylthio)benzamide 860778-48-9 C15H16N2OS
    N,N-dimethyl-2-(2'-aminophenylthio)benzamide
    —— (R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1-(2-ethyl-[1,3]dithian-2-yl)-butan-2-ol 287172-98-9 C17H36O2S2Si
    (R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1-(2-ethyl-[1,3]dithian-2-yl)-butan-2-ol
    —— 1-phenylsulphenyl-2-methylsulphenyl-5,5-dimethylcyclopenta-1,3-diene 335343-26-5 C14H16S2
    1-phenylsulphenyl-2-methylsulphenyl-5,5-dimethylcyclopenta-1,3-diene