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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethanethioic acid S-(methoxymethyl) ester 38634-58-1 C4H8O2S
    ethanethioic acid S-(methoxymethyl) ester
    —— 3-chloro-1,1-bis-ethanesulfonyl-propane 500779-49-7 C7H15ClO4S2
    3-chloro-1,1-bis-ethanesulfonyl-propane
    —— bis-(pentane-1-sulfonyl)-methane 18068-31-0 C11H24O4S2
    bis-(pentane-1-sulfonyl)-methane
    —— 3-((4R,5R)-2,2-Dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-propan-1-ol 864948-21-0 C14H20O3S
    3-((4R,5R)-2,2-Dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-propan-1-ol
    —— (S)-3-[4-(3-hydroxy-butylsulfanyl)-2-methyl-phenyl]-propionic acid methyl ester 847346-76-3 C15H22O3S
    (S)-3-[4-(3-hydroxy-butylsulfanyl)-2-methyl-phenyl]-propionic acid methyl ester
    —— (E)-methyl hex-1-enyl sulfoxide 71559-68-7 C7H14OS
    (E)-methyl hex-1-enyl sulfoxide
    —— 3-((p-chlorophenyl)thio)cyclohexanone 64924-10-3 C12H13ClOS
    3-((p-chlorophenyl)thio)cyclohexanone
    —— 1-(tetrahydropyran-2-yl)-3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one 116992-68-8 C13H17N3O3S
    1-(tetrahydropyran-2-yl)-3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one
    —— 2,3-Dihydrobenzothiophene-3-carboxylic acid 19156-56-0 C9H8O2S
    2,3-Dihydrobenzothiophene-3-carboxylic acid
    —— 3-ethyl-1,1,1-tris(methylthio)heptane 480425-00-1 C12H26S3
    3-ethyl-1,1,1-tris(methylthio)heptane
    —— 2-bromo-1,1-difluoro-4,8-dimethyl-1-methylthiononane 480425-08-9 C12H23BrF2S
    2-bromo-1,1-difluoro-4,8-dimethyl-1-methylthiononane
    —— 5,10-Dithia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3,6,8-trien-2-one 120079-27-8 C8H6N2OS2
    5,10-Dithia-1,8-diazatricyclo[7.3.0.03,7]dodeca-3,6,8-trien-2-one
    —— 8-chloro-2,3-dihydro-5H-thiazolo<3,2-a>thieno<3,4-d>pyrimidin-5-one 126636-81-5 C8H5ClN2OS2
    8-chloro-2,3-dihydro-5H-thiazolo<3,2-a>thieno<3,4-d>pyrimidin-5-one
    —— Gwxjcyvgwmmndx-uhfffaoysa- 120079-34-7 C9H8N2OS2
    Gwxjcyvgwmmndx-uhfffaoysa-
    —— 3,4,7,8-Tetrakis(trifluormethyl)-1,2,5,6-tetrathiocin 651-38-7 C8F12S4
    3,4,7,8-Tetrakis(trifluormethyl)-1,2,5,6-tetrathiocin
    —— N-(6-(2-(2-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-54-0 C20H16N4OS2
    N-(6-(2-(2-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(phenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-35-7 C19H14N4OS2
    N-(6-(2-(phenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(3-methoxyphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-61-9 C20H16N4O2S2
    N-(6-(2-(3-methoxyphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(3-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112980-30-9 C19H13FN4OS2
    N-(6-(2-(3-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(4-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-56-2 C20H16N4OS2
    N-(6-(2-(4-methylphenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(4-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-43-7 C19H13FN4OS2
    N-(6-(2-(4-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— N-(6-(2-(2-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide 1112979-37-9 C19H13FN4OS2
    N-(6-(2-(2-fluorophenylthio)pyrimidin-4-yl)benzo[d]thiazol-2-yl)acetamide
    —— 3-ethyl-1-propyl-1<i>H</i>,8<i>H</i>-pyrimido[5,4-<i>b</i>][1,4]thiazine-2,4,7-trione 3950-00-3 C11H15N3O3S
    3-ethyl-1-propyl-1<i>H</i>,8<i>H</i>-pyrimido[5,4-<i>b</i>][1,4]thiazine-2,4,7-trione
    —— n-butyl [(3-nitropyridin-2-yl)sulfanyl]acetate 1378234-14-0 C11H14N2O4S
    n-butyl [(3-nitropyridin-2-yl)sulfanyl]acetate
    —— 3-allylthiosulfanyl-6-homopiperidinylaminopyridazine 1221438-73-8 C13H20N4S
    3-allylthiosulfanyl-6-homopiperidinylaminopyridazine
    —— (6-amino-3-ethyl-2,4-dioxo-1-propyl-1,2,3,4-tetrahydro-pyrimidin-5-ylsulfanyl)-acetic acid 91194-51-3 C11H17N3O4S
    (6-amino-3-ethyl-2,4-dioxo-1-propyl-1,2,3,4-tetrahydro-pyrimidin-5-ylsulfanyl)-acetic acid
    —— 4,5-Bis[2-[tert-butyl(diphenyl)silyl]oxyethylsulfanyl]-1,3-dithiol-2-one 160409-45-0 C39H46O3S4Si2
    4,5-Bis[2-[tert-butyl(diphenyl)silyl]oxyethylsulfanyl]-1,3-dithiol-2-one
    —— (S)-3-Phenyl-2-phenylsulfanyl-propan-1-ol 143359-30-2 C15H16OS
    (S)-3-Phenyl-2-phenylsulfanyl-propan-1-ol
    —— (2R<sup>*</sup>,3R<sup>*</sup>)-1,4-di-O-isopropylidene-3-phenylthio-1,2,4-butanetriol —— C13H18O3S
    (2R<sup>*</sup>,3R<sup>*</sup>)-1,4-di-O-isopropylidene-3-phenylthio-1,2,4-butanetriol
    —— (2Z,7S)-7-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-2-methyl-5,5-(trimethylenedithio)-2-octenal 156261-87-9 C34H52O3S2Si2
    (2Z,7S)-7-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-2-methyl-5,5-(trimethylenedithio)-2-octenal
    —— 2-(Propylsulfonyl)ethanamine 771583-65-4 C5H13NO2S
    2-(Propylsulfonyl)ethanamine
    —— N-[4-[[4-ethyl-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-76-5 C19H20N6OS2
    N-[4-[[4-ethyl-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— bis-propoxythiocarbonyl-disulfane 3750-28-5 C8H14O2S4
    bis-propoxythiocarbonyl-disulfane
    —— N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)cyclopropanecarboxamide 1402546-06-8 C21H25N7O3S
    N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)cyclopropanecarboxamide
    —— 9-(3-aminopropyl)-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine 1402546-54-6 C17H21N7O2S
    9-(3-aminopropyl)-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine
    —— N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)pivalamide 1402546-08-0 C22H29N7O3S
    N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)pivalamide
    —— N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)cyclopropanesulfonamide 1402546-10-4 C20H25N7O4S2
    N-(3-(6-amino-8-(6-(dimethylamino)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)propyl)cyclopropanesulfonamide
    —— 2-Phenylsulfanylethyl 3-hydroxy-2-methylidenebutanoate 124919-75-1 C13H16O3S
    2-Phenylsulfanylethyl 3-hydroxy-2-methylidenebutanoate
    —— 3-methyl-3-[(methylthio)methoxy]cyclopent-1-ene-1-carbonitrile 615265-48-0 C9H13NOS
    3-methyl-3-[(methylthio)methoxy]cyclopent-1-ene-1-carbonitrile
    —— 3,6-bis(methylthio)-4-ethyl-5-methyl-1,2-diazine 112740-81-5 C9H14N2S2
    3,6-bis(methylthio)-4-ethyl-5-methyl-1,2-diazine
    —— 3,6-bis(methythio)-4-(n-hexyl)-1,2-diazine 112740-83-7 C12H20N2S2
    3,6-bis(methythio)-4-(n-hexyl)-1,2-diazine
    —— 2-phenylsulfanylethyl (3S)-3-hydroxy-2-methylidenebutanoate 124990-55-2 C13H16O3S
    2-phenylsulfanylethyl (3S)-3-hydroxy-2-methylidenebutanoate
    —— 1-((1-n-dodecyl-1H-imidazol-2-yl)methyl)-2-(4-fluorobenzylthio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-4(5H)-one 1417527-04-8 C30H41FN4OS
    1-((1-n-dodecyl-1H-imidazol-2-yl)methyl)-2-(4-fluorobenzylthio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-4(5H)-one
    —— 3,5-bis(methylthio)-1,2,4-triazine 5102-66-9 C5H7N3S2
    3,5-bis(methylthio)-1,2,4-triazine
    —— 3-ethoxy-5-methylsulfanyl-[1,2,4]triazine 98197-19-4 C6H9N3OS
    3-ethoxy-5-methylsulfanyl-[1,2,4]triazine
    —— 3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>prop-1-ene 169560-24-1 C17H22S
    3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>prop-1-ene
    —— N,N-dimethyl-6-(methylthio)-1,2,4,5-tetrazin-3-amine 876-09-5 C5H9N5S
    N,N-dimethyl-6-(methylthio)-1,2,4,5-tetrazin-3-amine
    —— 3-hydrazino-6-methylsulfanyl-[1,2,4,5]tetrazine 64499-90-7 C3H6N6S
    3-hydrazino-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— 1-Methyl-3,6-bis(methylsulfanyl)-4-(6-methylsulfanyl-1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazine 136506-22-4 C8H12N8S3
    1-Methyl-3,6-bis(methylsulfanyl)-4-(6-methylsulfanyl-1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazine
    —— 3-Amino-6-methylthio-1,2,4,5-tetrazin 64499-91-8 C3H5N5S
    3-Amino-6-methylthio-1,2,4,5-tetrazin