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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-1,1,2-Tris(p-tolylsulfenyl)propane 148252-29-3 C24H26S3
    (2R)-1,1,2-Tris(p-tolylsulfenyl)propane
    —— 3-(1-methylethyl)-2-(phenylthio)-1,3-butadiene 144453-30-5 C13H16S
    3-(1-methylethyl)-2-(phenylthio)-1,3-butadiene
    —— (S<sub>2</sub>,R<sub>3</sub>)-2-hydroxy-3-[(4-methylphenyl)sulfenyl]-2-isopropylbutanamide 144694-85-9 C14H21NO2S
    (S<sub>2</sub>,R<sub>3</sub>)-2-hydroxy-3-[(4-methylphenyl)sulfenyl]-2-isopropylbutanamide
    —— (4R,5S)-4-methyl-5-phenyl-2-(phenylsulfanylmethyl)-4,5-dihydro-1,3-oxazole 144397-24-0 C17H17NOS
    (4R,5S)-4-methyl-5-phenyl-2-(phenylsulfanylmethyl)-4,5-dihydro-1,3-oxazole
    —— 2-Aminoethyl carbamimidothioate;hydrochloride 871-25-0 C3H9N3S*ClH
    2-Aminoethyl carbamimidothioate;hydrochloride
    —— tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane 1019753-79-7 C20H30OSSi
    tert-Butyl-dimethyl-((1R,2R)-2-methyl-5-phenylsulfanyl-cyclohepta-3,5-dienyloxy)-silane
    —— Cyclohexanecarboxamide, N-[2-[(4-hydroxyphenyl)thio]ethyl]- 332913-57-2 C15H21NO2S
    Cyclohexanecarboxamide, N-[2-[(4-hydroxyphenyl)thio]ethyl]-
    —— 3-(3-Pentylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine 131987-52-5 C13H21N3S2
    3-(3-Pentylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-3-[(4-methylphenyl)sulfenyl]-2-isopropylbutanamide 144694-86-0 C14H21NO2S
    (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-3-[(4-methylphenyl)sulfenyl]-2-isopropylbutanamide
    —— 2-(4-Bromo-phenylsulfanyl)-6-nitro-benzonitrile 168910-82-5 C13H7BrN2O2S
    2-(4-Bromo-phenylsulfanyl)-6-nitro-benzonitrile
    —— 3-Cyclohexyl-2-nitro-2-p-tolylsulfanyl-oxirane 168135-89-5 C15H19NO3S
    3-Cyclohexyl-2-nitro-2-p-tolylsulfanyl-oxirane
    —— N-[2-(4-chloro-2-nitrophenyl)sulfanyl-4,6-dimethylphenyl]formamide 160881-75-4 C15H13ClN2O3S
    N-[2-(4-chloro-2-nitrophenyl)sulfanyl-4,6-dimethylphenyl]formamide
    —— 3-(3-Methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine 131987-18-3 C9H13N3S2
    3-(3-Methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— (R)-5-(1,2-dihydroxyprop-2-yl)-2-(methylthio)thiazole 159615-85-7 C7H11NO2S2
    (R)-5-(1,2-dihydroxyprop-2-yl)-2-(methylthio)thiazole
    —— 2-(methylthio)-4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thiophene 161386-85-2 C11H16O2S2
    2-(methylthio)-4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thiophene
    —— (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-2-{[1-(4-methylphenyl)sulfenyl]ethyl}pentanamide 144694-84-8 C14H21NO2S
    (S<sub>2</sub>,S<sub>3</sub>)-2-hydroxy-2-{[1-(4-methylphenyl)sulfenyl]ethyl}pentanamide
    —— dimethyl-6-(phenylthio)thymine 144410-28-6 C13H14N2O2S
    dimethyl-6-(phenylthio)thymine
    —— 2-cyclohexyl-1-(phenylthio)cyclobutene 144453-24-7 C16H20S
    2-cyclohexyl-1-(phenylthio)cyclobutene
    —— 3-(2-tert-Butyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-29-0 C15H17NS2
    3-(2-tert-Butyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— 9-[(4-Chlorophenyl)thio]-8-cyclopropyl-6-fluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indole-1-acetic acid 476619-35-9 C22H19ClFNO2S
    9-[(4-Chlorophenyl)thio]-8-cyclopropyl-6-fluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indole-1-acetic acid
    —— N-(2-cyanoethyl)-2-methyl-5-(2-(pyridin-2-ylamino)thiazol-5-ylthio)benzamide 439574-47-7 C19H17N5OS2
    N-(2-cyanoethyl)-2-methyl-5-(2-(pyridin-2-ylamino)thiazol-5-ylthio)benzamide
    —— Benzenamine, 2-[(2-ethylhexyl)thio]- 515140-79-1 C14H23NS
    Benzenamine, 2-[(2-ethylhexyl)thio]-
    —— (2R,3S)-2-Methyl-3-sulfanyl-butan-1-ol 669070-05-7 C5H12OS
    (2R,3S)-2-Methyl-3-sulfanyl-butan-1-ol
    —— 2-amino-5-(4-chlorophenylethynyl)-4-(4-hydroxyphenylthio)pyrimidine 393856-42-3 C18H12ClN3OS
    2-amino-5-(4-chlorophenylethynyl)-4-(4-hydroxyphenylthio)pyrimidine
    —— (Z)-4,5,9-trithiadeca-1,6-diene 9-oxide 104324-40-5 C7H12OS3
    (Z)-4,5,9-trithiadeca-1,6-diene 9-oxide
    —— (S)-3-mercapto-3-methyl-hexan-1-ol 307964-33-6 C7H16OS
    (S)-3-mercapto-3-methyl-hexan-1-ol
    —— Bismuth;2-aminoethanethiolate 216101-72-3 C6H18BiN3S3
    Bismuth;2-aminoethanethiolate
    —— (Z)-2,3,7-trithiaocta-4-ene 7-oxide 104229-00-7 C5H10OS3
    (Z)-2,3,7-trithiaocta-4-ene 7-oxide
    —— 6-Vinyl-1,4-dithia-spiro[4.5]dec-6-ene-8-thiol 1028273-46-2 C10H14S3
    6-Vinyl-1,4-dithia-spiro[4.5]dec-6-ene-8-thiol
    —— 4-(2,3-dihydroxyprop-2-yl)-2-(methylthio)thiophene 161386-84-1 C8H12O2S2
    4-(2,3-dihydroxyprop-2-yl)-2-(methylthio)thiophene
    —— 3-{2-[(4-chlorophenyl)thio]phenyl}-N-[4-(methoxyamino)butyl]propanamide 710960-38-6 C20H25ClN2O2S
    3-{2-[(4-chlorophenyl)thio]phenyl}-N-[4-(methoxyamino)butyl]propanamide
    —— 2-Ethylsulfanyl-thioisonicotinamide 180791-04-2 C8H10N2S2
    2-Ethylsulfanyl-thioisonicotinamide
    —— (1Z,3E)-1-(methylsulfonyl)-1,3-pentadiene 142868-73-3 C6H10O2S
    (1Z,3E)-1-(methylsulfonyl)-1,3-pentadiene
    —— 4-Bromo-5-[(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methoxymethoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 157331-33-4 C23H27BrN2O6S
    4-Bromo-5-[(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methoxymethoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— (2S,3S)-3-Butyl-2-phenylsulfanylmethyl-cycloheptanone 143008-46-2 C18H26OS
    (2S,3S)-3-Butyl-2-phenylsulfanylmethyl-cycloheptanone
    —— 4-[5-(3,5-Dichloro-phenylsulfanyl)-1-isopropyl-3-methyl-1H-pyrazol-4-ylmethyl]-3-fluoro-pyridine 412326-23-9 C19H18Cl2FN3S
    4-[5-(3,5-Dichloro-phenylsulfanyl)-1-isopropyl-3-methyl-1H-pyrazol-4-ylmethyl]-3-fluoro-pyridine
    —— 5-Cyano-2-(4-fluorophenyl)-1-(4-methylthio-phenyl)-4-methylthio-1,6-dihydro-pyrimidin-6-one 613663-79-9 C19H14FN3OS2
    5-Cyano-2-(4-fluorophenyl)-1-(4-methylthio-phenyl)-4-methylthio-1,6-dihydro-pyrimidin-6-one
    —— 1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-N'-phenylthiocarbamoylcarbothiohydrazide 153935-78-5 C11H13N7S3
    1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-N'-phenylthiocarbamoylcarbothiohydrazide
    —— 2-methyl-7-phenyl-3,5,5-tris(phenylthio)heptan-2-ol 167366-75-8 C32H34OS3
    2-methyl-7-phenyl-3,5,5-tris(phenylthio)heptan-2-ol
    —— 1-(Phenylthio)pent-1-yn-3-ol 79894-60-3 C11H12OS
    1-(Phenylthio)pent-1-yn-3-ol
    —— 8-(thioacethoxy)-6-vinyl-1,4-dithiaspiro<4.5>dec-6-ene 155996-14-8 C12H16OS3
    8-(thioacethoxy)-6-vinyl-1,4-dithiaspiro<4.5>dec-6-ene
    —— 2-(1-methylethyl)-1-(phenylthio)cyclobutene 144453-23-6 C13H16S
    2-(1-methylethyl)-1-(phenylthio)cyclobutene
    —— (2S,3S)-3-Ethyl-2-phenylsulfanylmethyl-cycloheptanone 143008-48-4 C16H22OS
    (2S,3S)-3-Ethyl-2-phenylsulfanylmethyl-cycloheptanone
    —— (2S,3S)-3-Methyl-2-phenylsulfanylmethyl-cycloheptanone 143008-47-3 C15H20OS
    (2S,3S)-3-Methyl-2-phenylsulfanylmethyl-cycloheptanone
    —— (3-carboxy-2-pyridyl)-2-thiobenzothiazole 146724-10-9 C13H8N2O2S2
    (3-carboxy-2-pyridyl)-2-thiobenzothiazole
    —— methyl 6-phenyl-2,4,4-tris(phenylthio)hexanoate 1060646-10-7 C31H30O2S3
    methyl 6-phenyl-2,4,4-tris(phenylthio)hexanoate
    —— 4-Amino-3-(2,4-difluoro-phenylsulfanyl)-benzonitrile 119983-21-0 C13H8F2N2S
    4-Amino-3-(2,4-difluoro-phenylsulfanyl)-benzonitrile
    —— 3-(O-tert-butyldimethylsilyl)-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-xylofuranose 157555-90-3 C20H32O4SSi
    3-(O-tert-butyldimethylsilyl)-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-xylofuranose
    —— 2,4-Bis-[2-(4-chloro-phenyl)-benzo[1,3]dithiol-2-yl]-1H-pyrrole 147089-56-3 C30H19Cl2NS4
    2,4-Bis-[2-(4-chloro-phenyl)-benzo[1,3]dithiol-2-yl]-1H-pyrrole
    —— 2-[2-(4-Methylphenyl)sulfanylethylamino]-1-phenylethanol 133760-87-9 C17H21NOS
    2-[2-(4-Methylphenyl)sulfanylethylamino]-1-phenylethanol