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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[1-(4-Fluorophenyl)-4-[(4-methylphenyl)thio]butyl]acetamide 145878-80-4 C19H22FNOS
    N-[1-(4-Fluorophenyl)-4-[(4-methylphenyl)thio]butyl]acetamide
    —— 2-(4-methylphenyl)-1-(phenylthio)cyclobutene 144453-26-9 C17H16S
    2-(4-methylphenyl)-1-(phenylthio)cyclobutene
    —— 2-(1-Chloro-pentyl)-benzo[1,3]dithiole 161091-56-1 C12H15ClS2
    2-(1-Chloro-pentyl)-benzo[1,3]dithiole
    —— 1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-N'-ethylthiocarbamoylcarbothiohydrazide 153935-80-9 C7H13N7S3
    1-(5-amino-3-methylthio-1H-1,2,4-triazol-1-yl)-N'-ethylthiocarbamoylcarbothiohydrazide
    —— (2R,3S)-2-<(R)-(methylsulfinyl)methyl>-3-propyloxirane 145762-62-5 C7H14O2S
    (2R,3S)-2-<(R)-(methylsulfinyl)methyl>-3-propyloxirane
    —— (3Z,5E)-3-(methylsulfonyl)-3,5-octadiene 142868-76-6 C9H16O2S
    (3Z,5E)-3-(methylsulfonyl)-3,5-octadiene
    —— 5-Phenyl-1-(phenylthio)pent-1-yn-3-ol 166264-32-0 C17H16OS
    5-Phenyl-1-(phenylthio)pent-1-yn-3-ol
    —— (2S,3R)-2-Phenylsulfanylmethyl-3-vinyl-cycloheptanone 143008-50-8 C16H20OS
    (2S,3R)-2-Phenylsulfanylmethyl-3-vinyl-cycloheptanone
    —— 1-Cyclopropylmethyl-4-(4-fluoro-phenylsulfanylmethyl)-piperidine 135135-91-0 C16H22FNS
    1-Cyclopropylmethyl-4-(4-fluoro-phenylsulfanylmethyl)-piperidine
    —— (8Z,10E)-8-(methylsulfonyl)-8,10-octadecadiene 142895-73-6 C19H36O2S
    (8Z,10E)-8-(methylsulfonyl)-8,10-octadecadiene
    —— 2,2'-sulfonylbis<3-(dimethylamino)-(E,E)-N-(2,2-dimethoxyethyl)propenamide> 132417-43-7 C18H34N4O8S
    2,2'-sulfonylbis<3-(dimethylamino)-(E,E)-N-(2,2-dimethoxyethyl)propenamide>
    —— 4,5-Bis<(2'-bromoethyl)thio>-1,3-dithiole-2-thione 146581-69-3 C7H8Br2S5
    4,5-Bis<(2'-bromoethyl)thio>-1,3-dithiole-2-thione
    —— (2S)-1,1,2-Tris(p-tolylsulfenyl)propane 148252-28-2 C24H26S3
    (2S)-1,1,2-Tris(p-tolylsulfenyl)propane
    —— 2-ethyl-1-(phenylthio)cyclobutene 144453-22-5 C12H14S
    2-ethyl-1-(phenylthio)cyclobutene
    —— Phenol, 2-[(2-aminoethyl)thio]- 105608-90-0 C8H11NOS
    Phenol, 2-[(2-aminoethyl)thio]-
    —— (3'aS,7'aS)-3'a-hydroxy-7'a-methylspiro[1,3-dithiane-2,5'-3,4,6,7-tetrahydro-2H-indene]-1'-one 164298-16-2 C13H20O2S2
    (3'aS,7'aS)-3'a-hydroxy-7'a-methylspiro[1,3-dithiane-2,5'-3,4,6,7-tetrahydro-2H-indene]-1'-one
    —— 3-bromo-6-(4-chlorophenyl)-4-thiomethyl-2H-pyran-2-one 203171-92-0 C12H8BrClO2S
    3-bromo-6-(4-chlorophenyl)-4-thiomethyl-2H-pyran-2-one
    —— 2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[(1,2,4-oxadiazol-3-ylmethyl)thio]-4-pyrimidinol 666752-86-9 C17H17F2N5O3S2
    2-[[(2,3-difluorophenyl)methyl]thio]-6-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[(1,2,4-oxadiazol-3-ylmethyl)thio]-4-pyrimidinol
    —— 3-Butenyl 3-(ethylthio)propyl sulfide 143144-31-4 C9H18S2
    3-Butenyl 3-(ethylthio)propyl sulfide
    —— 1-[4-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-hexan-1-one 147089-48-3 C22H29NOS2
    1-[4-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-2-yl]-hexan-1-one
    —— 1-[5-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-3-yl]-hexan-1-one 147089-12-1 C22H29NOS2
    1-[5-(2-Pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrol-3-yl]-hexan-1-one
    —— 6-(4-Chloro-phenyl)-4-methylsulfanyl-pyran-2-one 203171-88-4 C12H9ClO2S
    6-(4-Chloro-phenyl)-4-methylsulfanyl-pyran-2-one
    —— 4-(benzylsulfanyl)-2-methylpyridine N-oxide 147149-90-4 C13H13NOS
    4-(benzylsulfanyl)-2-methylpyridine N-oxide
    —— (Z)-9-methyl-1,5-dithiacyclonon-8-ene 144227-18-9 C8H14S2
    (Z)-9-methyl-1,5-dithiacyclonon-8-ene
    —— ((3aR)-7t-Methoxy-2,2-dimethyl-(3ar,7at)-3a,4,7,7a-tetrahydro-6H-spiro<benzo<1,3>dioxole-5,2'-<1,3>dithian>-4t-yl)methanol 160651-54-7 C14H24O4S2
    ((3aR)-7t-Methoxy-2,2-dimethyl-(3ar,7at)-3a,4,7,7a-tetrahydro-6H-spiro<benzo<1,3>dioxole-5,2'-<1,3>dithian>-4t-yl)methanol
    —— (E)-4'-[4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thien-2-ylthio]acetophenone oxime 161509-83-7 C18H21NO3S2
    (E)-4'-[4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thien-2-ylthio]acetophenone oxime
    —— 3-(1-Methyl-cyclopropyl)-6-methylsulfanyl-[1,2,4,5]tetrazine 159801-89-5 C7H10N4S
    3-(1-Methyl-cyclopropyl)-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— [3-(4-aminophenylsulphanyl)phenyl]acetic acid 365250-53-9 C14H13NO2S
    [3-(4-aminophenylsulphanyl)phenyl]acetic acid
    —— 6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-ol 155996-12-6 C10H14OS2
    6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-ol
    —— N-methyl-2-(3-pyridyl)-1,3-oxathiane-2-carbothioamide 82081-63-8 C11H14N2OS2
    N-methyl-2-(3-pyridyl)-1,3-oxathiane-2-carbothioamide
    —— 4,4-dimethyl-5-phenylsulphenylcyclopent-2-enone 335343-28-7 C13H14OS
    4,4-dimethyl-5-phenylsulphenylcyclopent-2-enone
    —— 1-((S)-3-Azido-2-hydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one 208513-40-0 C9H13N5O2S
    1-((S)-3-Azido-2-hydroxy-propyl)-5-methyl-2-methylsulfanyl-1H-pyrimidin-4-one
    —— Methyl (2R,3R,4S)-<5-oxo-4-(phenylthio)-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>tetrahydrofuran-3-yl>acetate 162264-90-6 C31H36O5SSi
    Methyl (2R,3R,4S)-<5-oxo-4-(phenylthio)-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>tetrahydrofuran-3-yl>acetate
    —— 3-(Propane-1-sulfonyl)-cyclohexanone 185408-84-8 C9H16O3S
    3-(Propane-1-sulfonyl)-cyclohexanone
    —— 2,4-Bis-(2-p-tolyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-54-1 C32H25NS4
    2,4-Bis-(2-p-tolyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— 2,3-Dimethyl-5-methylsulfanyl-3,4-dihydro-2H-pyrrole 1027601-39-3 C7H13NS
    2,3-Dimethyl-5-methylsulfanyl-3,4-dihydro-2H-pyrrole
    —— (E)-(R)-4-hydroxy-1-methyl-2-butenyl phenyl sulfide 267668-20-2 C11H14OS
    (E)-(R)-4-hydroxy-1-methyl-2-butenyl phenyl sulfide
    —— 2-(2-Butoxyethylsulfanyl)phenol 210350-91-7 C12H18O2S
    2-(2-Butoxyethylsulfanyl)phenol
    —— (E)-(R)-4-bromo-1-methyl-2-butenyl phenyl sulfide 267668-21-3 C11H13BrS
    (E)-(R)-4-bromo-1-methyl-2-butenyl phenyl sulfide
    —— 5-Ethyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione 191472-47-6 C14H16N2O3S
    5-Ethyl-6-methylsulfanyl-1-phenylmethoxypyrimidine-2,4-dione
    —— N-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydro-1H-1λ<sup>6</sup>-thiophen-3-yl)-acetamide 192988-15-1 C12H13NO3S2
    N-(1,1-Dioxo-4-phenylsulfanyl-2,5-dihydro-1H-1λ<sup>6</sup>-thiophen-3-yl)-acetamide
    —— N-[(3,5-dimethoxy-2-phenylsulfanylphenyl)methyl]-N-(2-hydroxyethyl)formamide 212184-66-2 C18H21NO4S
    N-[(3,5-dimethoxy-2-phenylsulfanylphenyl)methyl]-N-(2-hydroxyethyl)formamide
    —— 3,7,11-Trichloro-1,9-dinitrobenzo[d][1,3,6,2]benzodioxathiaphosphocine 11-oxide 21386-24-3 C12H4Cl3N2O7PS
    3,7,11-Trichloro-1,9-dinitrobenzo[d][1,3,6,2]benzodioxathiaphosphocine 11-oxide
    —— 2,2-Dimethyl-propionic acid (E)-5-{4-methoxy-2-[(E)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester 211758-76-8 C35H44N2O4S
    2,2-Dimethyl-propionic acid (E)-5-{4-methoxy-2-[(E)-6-(4-methoxy-2-phenylsulfanylmethyl-pyridin-3-yl)-hex-3-enyl]-pyridin-3-yl}-pent-2-enyl ester
    —— 2-(Methylthio)-I+/--phenyl-5-oxazolemethanol 201017-91-6 C11H11NO2S
    2-(Methylthio)-I+/--phenyl-5-oxazolemethanol
    —— (5,6-Dimethyl-4-oxo-4H-thieno[2,3-d][1,3]oxazin-2-ylsulfanyl)-acetic acid methyl ester 207744-09-0 C11H11NO4S2
    (5,6-Dimethyl-4-oxo-4H-thieno[2,3-d][1,3]oxazin-2-ylsulfanyl)-acetic acid methyl ester
    —— 4-Chloro-2-[(4-chlorophenyl)thio]-5-thiazolecarboxaldehyde 199851-24-6 C10H5Cl2NOS2
    4-Chloro-2-[(4-chlorophenyl)thio]-5-thiazolecarboxaldehyde
    —— 2-(4-Hydroxy-phenyl)-2,3-dihydro-benzo[1,4]oxathiine-5,7-diol 342646-92-8 C14H12O4S
    2-(4-Hydroxy-phenyl)-2,3-dihydro-benzo[1,4]oxathiine-5,7-diol
    —— (3S,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one 118664-21-4 C16H19NOS
    (3S,4aS)-4a-Methyl-3-phenylsulfanyl-3,4,4a,5,6,7-hexahydro-1H-quinolin-2-one
    —— 3-Isopropylsulfanyl-5-piperidin-1-yl-[1,2,4]triazine 187099-37-2 C11H18N4S
    3-Isopropylsulfanyl-5-piperidin-1-yl-[1,2,4]triazine