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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(4-amino-phenylsulfanyl)-propionic acid 30086-23-8 C9H11NO2S
    3-(4-amino-phenylsulfanyl)-propionic acid
    —— 2,2,2-trifluoro-N-[2-[4-[[3-(aminocarbonyl)-4-nitrophenyl]thio]phenyl]ethyl]acetamide 870104-61-3 C17H14F3N3O4S
    2,2,2-trifluoro-N-[2-[4-[[3-(aminocarbonyl)-4-nitrophenyl]thio]phenyl]ethyl]acetamide
    —— (1-Chloro-cyclohexylsulfanyl)-benzene 89423-43-8 C12H15ClS
    (1-Chloro-cyclohexylsulfanyl)-benzene
    —— (S)-3-hydroxy-N,N,14-trimethylpentadecanethioamide 1402050-26-3 C18H37NOS
    (S)-3-hydroxy-N,N,14-trimethylpentadecanethioamide
    —— 2-(3-hydroxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine 263390-95-0 C19H18N2O2S
    2-(3-hydroxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine
    —— 2-[1-(cyclopentyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene 1356910-92-3 C18H18OS2
    2-[1-(cyclopentyloxy)-3-(phenylthio)-2-propyn-1-yl]thiophene
    —— 3-[(S-pivaloyloxymethyl-4-thiothymin-1-ylacetyl)amino]propyne 161098-28-8 C16H21N3O4S
    3-[(S-pivaloyloxymethyl-4-thiothymin-1-ylacetyl)amino]propyne
    —— 3-(ethylthio)-2,1-benzisothiazole 67943-94-6 C9H9NS2
    3-(ethylthio)-2,1-benzisothiazole
    —— (2S,3S,4R,6S)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol 338387-38-5 C19H32O3SSi
    (2S,3S,4R,6S)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol
    —— 2-(3-cyclopentyloxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine 263391-00-0 C24H26N2O2S
    2-(3-cyclopentyloxyphenylthio)-3-[3-(pyridin-4-yl)propoxy]pyridine
    —— 1-phenyl-5-(phenylthio)oct-7-en-4-one 1589514-37-3 C20H22OS
    1-phenyl-5-(phenylthio)oct-7-en-4-one
    —— Acetic acid, (phenylthio)(triphenylarsoranylidene)-, ethyl ester 518035-71-7 C28H25AsO2S
    Acetic acid, (phenylthio)(triphenylarsoranylidene)-, ethyl ester
    —— p-methylphenyl phenyldithioacetate 378791-48-1 C15H14S2
    p-methylphenyl phenyldithioacetate
    —— 2-(butylthio)-4-(5-phenylpent-1-ynyl)oxazole 1268685-56-8 C18H21NOS
    2-(butylthio)-4-(5-phenylpent-1-ynyl)oxazole
    —— 2-fluoro-N-methoxymethyl-4-(trifluoromethylthio)-aniline 935440-18-9 C9H9F4NOS
    2-fluoro-N-methoxymethyl-4-(trifluoromethylthio)-aniline
    —— p-bromophenyl propanedithioate 340814-59-7 C9H9BrS2
    p-bromophenyl propanedithioate
    —— but-2-ene-1,4-dithiol 6725-69-5 C4H8S2
    but-2-ene-1,4-dithiol
    —— p-chlorophenyl phenyldithioacetate 378791-49-2 C14H11ClS2
    p-chlorophenyl phenyldithioacetate
    —— 1-Methyl-2-pivalyloxymethylthioimidazole 80693-27-2 C10H16N2O2S
    1-Methyl-2-pivalyloxymethylthioimidazole
    —— 4-bis(phenylthio)methoxy-2-methylbut-1-ene 746638-51-7 C18H20OS2
    4-bis(phenylthio)methoxy-2-methylbut-1-ene
    —— 6-(4-fluorophenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-57-6 C24H17FO2S
    6-(4-fluorophenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 4-(4-methylsulfanylphenyl)-3,6-diphenylpyran-2-one 742699-51-0 C24H18O2S
    4-(4-methylsulfanylphenyl)-3,6-diphenylpyran-2-one
    —— 6-(4-methylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-52-1 C25H20O2S
    6-(4-methylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 6-(4-ethylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one 742699-53-2 C26H22O2S
    6-(4-ethylphenyl)-4-(4-methylsulfanylphenyl)-3-phenylpyran-2-one
    —— 4-(allylthio)-1-phenylpyrimidin-2(1H)-one 917081-61-9 C13H12N2OS
    4-(allylthio)-1-phenylpyrimidin-2(1H)-one
    —— 6-(4-methylsulfanylphenyl)-3,4-diphenylpyran-2-one 742699-50-9 C24H18O2S
    6-(4-methylsulfanylphenyl)-3,4-diphenylpyran-2-one
    —— 2-(1-phenylsulfonyl-1H-indol-3-yl)thio-1H-indole 916611-30-8 C22H16N2O2S2
    2-(1-phenylsulfonyl-1H-indol-3-yl)thio-1H-indole
    —— Propanoic acid, 2,2-dimethyl-, ((3-(4-pyridinyl)-1,2,4-oxadiazol-5-yl)thio)methyl ester 345631-80-3 C13H15N3O3S
    Propanoic acid, 2,2-dimethyl-, ((3-(4-pyridinyl)-1,2,4-oxadiazol-5-yl)thio)methyl ester
    —— Propanoic acid, 2,2-dimethyl-, ((3-pyrazinyl-1,2,4-oxadiazol-5-yl)thio)methyl ester 345631-82-5 C12H14N4O3S
    Propanoic acid, 2,2-dimethyl-, ((3-pyrazinyl-1,2,4-oxadiazol-5-yl)thio)methyl ester
    —— 2-[[4-(chloromethyl)-2-nitrophenyl]thio]-N,N-dimethylbenzenemethanamine 627488-92-0 C16H17ClN2O2S
    2-[[4-(chloromethyl)-2-nitrophenyl]thio]-N,N-dimethylbenzenemethanamine
    —— (4-Bromophenyl)-[2-(4-methylphenyl)sulfanylquinolin-1-ium-1-yl]azanide 467435-34-3 C22H17BrN2S
    (4-Bromophenyl)-[2-(4-methylphenyl)sulfanylquinolin-1-ium-1-yl]azanide
    —— 2-(p-fluorophenylthiaoxy)acetyl chloride 70932-09-1 C8H6ClFOS
    2-(p-fluorophenylthiaoxy)acetyl chloride
    —— 5,5-bis(phenylthio)-1-pentanol 83711-12-0 C17H20OS2
    5,5-bis(phenylthio)-1-pentanol
    —— 5,5-bis(phenylthio)pentyl 3-phenylpropanoate 263565-64-6 C26H28O2S2
    5,5-bis(phenylthio)pentyl 3-phenylpropanoate
    —— 2-(p-tolylthio)terephthalonitrile 51762-76-6 C15H10N2S
    2-(p-tolylthio)terephthalonitrile
    —— 2,5-Bis-phenylsulfanyl-benzene-1,4-dicarbaldehyde 954149-19-0 C20H14O2S2
    2,5-Bis-phenylsulfanyl-benzene-1,4-dicarbaldehyde
    —— [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene 93233-72-8 C11H14OS
    [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene
    —— p-methoxyphenylthioterephthalonitrile 51798-25-5 C15H10N2OS
    p-methoxyphenylthioterephthalonitrile
    —— 2-(phenylethylthio)pyrimidine-4,6-diamine 412919-37-0 C12H14N4S
    2-(phenylethylthio)pyrimidine-4,6-diamine
    —— 2-(cyclopentylthio)pyrimidine-4,6-diamine 1099593-11-9 C9H14N4S
    2-(cyclopentylthio)pyrimidine-4,6-diamine
    —— 1-methyl-(2-(3-2-tetrahydropyranyloxy)propylthio)imidazole 193002-07-2 C12H20N2O2S
    1-methyl-(2-(3-2-tetrahydropyranyloxy)propylthio)imidazole
    —— 2-[(4-methyl-2-nitrophenyl)thio]-N,N-dimethylbenzamide 411208-40-7 C16H16N2O3S
    2-[(4-methyl-2-nitrophenyl)thio]-N,N-dimethylbenzamide
    —— 2-({3-[(2,4-difluorophenyl)thio]propyl}oxy)tetrahydro-2H-pyran 915771-67-4 C14H18F2O2S
    2-({3-[(2,4-difluorophenyl)thio]propyl}oxy)tetrahydro-2H-pyran
    —— phenylthioterephthalonitrile 51762-73-3 C14H8N2S
    phenylthioterephthalonitrile
    —— 2-(cyclobutylmethylthio)pyrimidine-4,6-diamine 1372793-56-0 C9H14N4S
    2-(cyclobutylmethylthio)pyrimidine-4,6-diamine
    —— 3-hydroxy-5-[(5-nitrothiazol-2-yl)mercapto]-4-[2-(trifluoromethyl) phenyl]-1,2,4-triazole 186371-11-9 C12H6F3N5O3S2
    3-hydroxy-5-[(5-nitrothiazol-2-yl)mercapto]-4-[2-(trifluoromethyl) phenyl]-1,2,4-triazole
    —— p-Chlorophenylthioterephthalonitrile 51762-74-4 C14H7ClN2S
    p-Chlorophenylthioterephthalonitrile
    —— 2-(2-fluorobenzylthio)pyrimidine-4,6-diamine 639003-52-4 C11H11FN4S
    2-(2-fluorobenzylthio)pyrimidine-4,6-diamine
    —— 2-(hexylthio)pyrimidine-4,6-diamine 1247673-99-9 C10H18N4S
    2-(hexylthio)pyrimidine-4,6-diamine
    —— 2-(2-methylbenzylthio)pyrimidine-4,6-diamine 710966-68-0 C12H14N4S
    2-(2-methylbenzylthio)pyrimidine-4,6-diamine