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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-(1-methylpiperidin-2-yl)ethylthio)pyrimidine-4,6-diamine 1292254-83-1 C12H21N5S
    2-(2-(1-methylpiperidin-2-yl)ethylthio)pyrimidine-4,6-diamine
    —— 2-(4-fluorobenzylthio)pyrimidine-4,6-diamine 340808-48-2 C11H11FN4S
    2-(4-fluorobenzylthio)pyrimidine-4,6-diamine
    —— 2-(2-chlorobenzylthio)pyrimidine-4,6-diamine 370842-89-0 C11H11ClN4S
    2-(2-chlorobenzylthio)pyrimidine-4,6-diamine
    —— 4,6-diamino-2-propylthiopyrimidine 84890-69-7 C7H12N4S
    4,6-diamino-2-propylthiopyrimidine
    —— 2-(3-methylbenzylthio)pyrimidine-4,6-diamine 639003-72-8 C12H14N4S
    2-(3-methylbenzylthio)pyrimidine-4,6-diamine
    —— 2-[[(2,3-Difluorophenyl)methyl]thio]-4,6-pyrimidinediamine 354582-88-0 C11H10F2N4S
    2-[[(2,3-Difluorophenyl)methyl]thio]-4,6-pyrimidinediamine
    —— 2-(2-morpholinoethylthio)pyrimidine-4,6-diamine 333422-35-8 C10H17N5OS
    2-(2-morpholinoethylthio)pyrimidine-4,6-diamine
    —— 2H-1,3,5-Thiadiazin-6-amine, 2,4-diethyl-3,4-dihydro- 634604-28-7 C7H15N3S
    2H-1,3,5-Thiadiazin-6-amine, 2,4-diethyl-3,4-dihydro-
    —— 2-chloromethylsulfanyl-pyrimidine-4,6-diamine 250597-66-1 C5H7ClN4S
    2-chloromethylsulfanyl-pyrimidine-4,6-diamine
    —— 2-(3-fluorobenzylthio)pyrimidine-4,6-diamine 664999-73-9 C11H11FN4S
    2-(3-fluorobenzylthio)pyrimidine-4,6-diamine
    —— 2-(3-phenylpropylthio)pyrimidine-4,6-diamine 1003768-26-0 C13H16N4S
    2-(3-phenylpropylthio)pyrimidine-4,6-diamine
    —— 2-((2-(bis(4-methoxybenzyl)amino)-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diamine 1268273-17-1 C26H29N7O4S
    2-((2-(bis(4-methoxybenzyl)amino)-4,6-dimethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diamine
    —— 2-(butylthio)pyrimidine-4,6-diamine 73000-28-9 C8H14N4S
    2-(butylthio)pyrimidine-4,6-diamine
    —— 2-((2-(bis(4-methoxybenzyl)amino)-4,6-diethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diamine 1268273-27-3 C28H33N7O4S
    2-((2-(bis(4-methoxybenzyl)amino)-4,6-diethoxypyrimidin-5-yl)thio)pyrimidine-4,6-diamine
    —— 2-(2-Phenylsulfanylcyclopentyl)-1,3-dioxolane 137846-58-3 C14H18O2S
    2-(2-Phenylsulfanylcyclopentyl)-1,3-dioxolane
    —— 7-(3-Ethynylanilino)-2-methylsulfanyl-[1,3]thiazolo[4,5-b]pyridine-6-carbonitrile 905435-01-0 C16H10N4S2
    7-(3-Ethynylanilino)-2-methylsulfanyl-[1,3]thiazolo[4,5-b]pyridine-6-carbonitrile
    —— S,S-dimethyl-N-(1,3-dimethyl-1,3,2-diazaborolidin-2-yl)-sulfoimine 77936-60-8 C6H16BN3OS
    S,S-dimethyl-N-(1,3-dimethyl-1,3,2-diazaborolidin-2-yl)-sulfoimine
    —— 2-Methyl-1,3-dithiolane-2-carbonyl chloride 126338-59-8 C5H7ClOS2
    2-Methyl-1,3-dithiolane-2-carbonyl chloride
    —— 1-Phenylthio-2-(1'-hydroxypentyl)cyclopenten 56561-15-0 C16H22OS
    1-Phenylthio-2-(1'-hydroxypentyl)cyclopenten
    —— ethyl 2-(4-methylthiophenylthio)benzoate 86490-29-1 C16H16O2S2
    ethyl 2-(4-methylthiophenylthio)benzoate
    —— 1-Phenyl-N-phenyl-2-phenylsulfanylethylamine 193537-12-1 C20H19NS
    1-Phenyl-N-phenyl-2-phenylsulfanylethylamine
    —— N,N-Diethyl 4-N,N-Dimethylamino-2-[3-(N,N-dimethylamino)-phenylthio]benzamide 705964-32-5 C21H29N3OS
    N,N-Diethyl 4-N,N-Dimethylamino-2-[3-(N,N-dimethylamino)-phenylthio]benzamide
    —— cyclohexyl methyl sulfoxide 56051-02-6 C7H14OS
    cyclohexyl methyl sulfoxide
    —— 4-nitro-2-(o-tolylthio)aniline 1418195-43-3 C13H12N2O2S
    4-nitro-2-(o-tolylthio)aniline
    —— 3-Methyl-2-(methylsulfanyl)-6-phenyl-4H-thiopyran-4-one 113544-19-7 C13H12OS2
    3-Methyl-2-(methylsulfanyl)-6-phenyl-4H-thiopyran-4-one
    —— 1-(2-Hydroxy-ethyl)-3-(3-methyl-cyclopent-1-enylmethyl)-thiourea 455256-18-5 C10H18N2OS
    1-(2-Hydroxy-ethyl)-3-(3-methyl-cyclopent-1-enylmethyl)-thiourea
    —— N-Isopropyl-3-phenylsulfanylpropylamine 223113-77-7 C12H19NS
    N-Isopropyl-3-phenylsulfanylpropylamine
    —— 2-(Benzylsulfanyl)-6-phenyl-4H-thiopyran-4-one 113544-17-5 C18H14OS2
    2-(Benzylsulfanyl)-6-phenyl-4H-thiopyran-4-one
    —— S-o-tolyl dimethylcarbamothioate 7305-14-8 C10H13NOS
    S-o-tolyl dimethylcarbamothioate
    —— N,N-dimethyl-2-(4'-methyl-2'-nitrophenylthio)-5-fluoro-benzamide 951172-89-7 C16H15FN2O3S
    N,N-dimethyl-2-(4'-methyl-2'-nitrophenylthio)-5-fluoro-benzamide
    —— 2-(4-bromo-phenylsulfanyl)-<i>N</i>-methoxy-acetamide 15909-42-9 C9H10BrNO2S
    2-(4-bromo-phenylsulfanyl)-<i>N</i>-methoxy-acetamide
    —— 3-Methylthio-1-cyclohexene 34046-61-2 C7H12S
    3-Methylthio-1-cyclohexene
    —— 4-(2-Hydroxyethylthio)-6,7-dihydro-5H-pyrido<2,3-b>pyrimido<4,5-d>azepine 138768-87-3 C13H14N4OS
    4-(2-Hydroxyethylthio)-6,7-dihydro-5H-pyrido<2,3-b>pyrimido<4,5-d>azepine
    —— α-(4-Methylphenyl)-thiomethyl-acrylsaeure 61020-47-1 C11H12O2S
    α-(4-Methylphenyl)-thiomethyl-acrylsaeure
    —— 3,3-dimethyl-5-thiocyanatohept-1-en-6-yne 491584-21-5 C10H13NS
    3,3-dimethyl-5-thiocyanatohept-1-en-6-yne
    —— 1-phenylthio-4-(2-tetrahydropyranyloxy)-2-pentyne 184674-08-6 C16H20O2S
    1-phenylthio-4-(2-tetrahydropyranyloxy)-2-pentyne
    —— 2-(phenylthiomethyl)propenoic acid 87531-39-3 C10H10O2S
    2-(phenylthiomethyl)propenoic acid
    —— 4-((3,4-difluorophenyl)thio)butanoic acid 1097802-42-0 C10H10F2O2S
    4-((3,4-difluorophenyl)thio)butanoic acid
    —— N,N-dimethyl-2-(4'-methyl-2'-nitrophenylthio)-5-bromo-benzamide 1005412-85-0 C16H15BrN2O3S
    N,N-dimethyl-2-(4'-methyl-2'-nitrophenylthio)-5-bromo-benzamide
    —— [2-(4-Methoxyphenyl)sulfanylphenyl]methanamine 127905-94-6 C14H15NOS
    [2-(4-Methoxyphenyl)sulfanylphenyl]methanamine
    —— O-Methyl-2-(4-methoxyphenylthio)benzohydroxamic acid 89114-61-4 C15H15NO3S
    O-Methyl-2-(4-methoxyphenylthio)benzohydroxamic acid
    —— 6-Isopropyl-2-methylsulfanyl-nicotinonitrile 647011-49-2 C10H12N2S
    6-Isopropyl-2-methylsulfanyl-nicotinonitrile
    —— methyl 5-((3,5-dichloropyridin-4-yl)thio)-4-nitrothiophene-2-carboxylate 1247820-24-1 C11H6Cl2N2O4S2
    methyl 5-((3,5-dichloropyridin-4-yl)thio)-4-nitrothiophene-2-carboxylate
    —— 6-Isobutyl-2-methylsulfanyl-nicotinonitrile 647011-48-1 C11H14N2S
    6-Isobutyl-2-methylsulfanyl-nicotinonitrile
    —— N-{2-[(4-methoxyphenyl)sulfanyl]benzyl}-N,N-dipropylamine 127906-10-9 C20H27NOS
    N-{2-[(4-methoxyphenyl)sulfanyl]benzyl}-N,N-dipropylamine
    —— 4-[2-(Diethylaminomethyl)phenyl]sulfanylphenol 127906-56-3 C17H21NOS
    4-[2-(Diethylaminomethyl)phenyl]sulfanylphenol
    —— 4-[2-(Aminomethyl)phenyl]sulfanylphenol 127906-45-0 C13H13NOS
    4-[2-(Aminomethyl)phenyl]sulfanylphenol
    —— N-{2-[(4-methoxyphenyl)sulfanyl]benzyl}-N,N-dimethylamine 127905-73-1 C16H19NOS
    N-{2-[(4-methoxyphenyl)sulfanyl]benzyl}-N,N-dimethylamine
    —— 2-(p-Chlorophenylthio)-succinic anhydride 61607-29-2 C10H7ClO3S
    2-(p-Chlorophenylthio)-succinic anhydride
    —— 4-[2-[(Dipropylamino)methyl]phenyl]sulfanylphenol 127906-59-6 C19H25NOS
    4-[2-[(Dipropylamino)methyl]phenyl]sulfanylphenol