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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-5-(3-Nitro-4-(m-tolylthio)benzylidene)-2-thioxothiazolidin-4-one 22 1489285-15-5 C17H12N2O3S3
    (Z)-5-(3-Nitro-4-(m-tolylthio)benzylidene)-2-thioxothiazolidin-4-one 22
    —— (Z)-5-(4-((4-Ethylphenyl)thio)-3-nitrobenzylidene)-2-thioxothiazolidin-4-one 17 1489285-04-2 C18H14N2O3S3
    (Z)-5-(4-((4-Ethylphenyl)thio)-3-nitrobenzylidene)-2-thioxothiazolidin-4-one 17
    —— (Z)-5-(3-Fluoro-4-(o-tolylthio)benzylidene)-2-thioxothiazolidin-4-one 29 1489285-28-0 C17H12FNOS3
    (Z)-5-(3-Fluoro-4-(o-tolylthio)benzylidene)-2-thioxothiazolidin-4-one 29
    —— (Z)-2-Thioxo-5-(4-(p-tolylthio)benzylidene)thiazolidin-4-one 11 1489284-91-4 C17H13NOS3
    (Z)-2-Thioxo-5-(4-(p-tolylthio)benzylidene)thiazolidin-4-one 11
    —— Dasb hydrochloride C-11 296774-17-9 C16H18ClN3S
    Dasb hydrochloride C-11
    —— 4-chloro-N-[2-methyl-5-(6-methyl-1,3-dioxo-2-propan-2-ylpyrrolo[3,4-c]pyridin-4-yl)sulfanylphenyl]benzenesulfonamide 1531587-79-7 C24H22ClN3O4S2
    4-chloro-N-[2-methyl-5-(6-methyl-1,3-dioxo-2-propan-2-ylpyrrolo[3,4-c]pyridin-4-yl)sulfanylphenyl]benzenesulfonamide
    —— 4-chloro-N-[3-(6-methyl-1,3-dioxo-2-propan-2-ylpyrrolo[3,4-c]pyridin-4-yl)sulfanylphenyl]benzenesulfonamide 1531587-78-6 C23H20ClN3O4S2
    4-chloro-N-[3-(6-methyl-1,3-dioxo-2-propan-2-ylpyrrolo[3,4-c]pyridin-4-yl)sulfanylphenyl]benzenesulfonamide
    —— 4-(3-Amino-4-methylphenyl)sulfanyl-6-methyl-2-propan-2-ylpyrrolo[3,4-c]pyridine-1,3-dione 1531587-77-5 C18H19N3O2S
    4-(3-Amino-4-methylphenyl)sulfanyl-6-methyl-2-propan-2-ylpyrrolo[3,4-c]pyridine-1,3-dione
    —— [6-(4'-Bromophenylsulfanyl)-4-(trifluoromethyl)-pyridin-2-ylsulfanyl]acetic acid 1053657-67-2 C14H9BrF3NO2S2
    [6-(4'-Bromophenylsulfanyl)-4-(trifluoromethyl)-pyridin-2-ylsulfanyl]acetic acid
    —— 2-Chloro-6-(2'-chloroethylsulfanyl)-4-(trifluoromethyl)pyridine 1053657-72-9 C8H6Cl2F3NS
    2-Chloro-6-(2'-chloroethylsulfanyl)-4-(trifluoromethyl)pyridine
    —— 2-(2,4-Diaminophenyl)sulfanylethanol;hydrochloride 81029-01-8 C8H13ClN2OS
    2-(2,4-Diaminophenyl)sulfanylethanol;hydrochloride
    —— 1-Methyl-sulfinyl-hexen-(1) 89975-66-6 C7H14OS
    1-Methyl-sulfinyl-hexen-(1)
    —— (6-Morpholin-4'-yl-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide 1053657-62-7 C12H15F3N4O2S
    (6-Morpholin-4'-yl-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide
    —— 2-(2-Furanylthio)-3-methylpyrazine 1121585-03-2 C9H8N2OS
    2-(2-Furanylthio)-3-methylpyrazine
    —— U0126 ethanol salt —— C20H22N6OS2
    U0126 ethanol salt
    —— 2-thiazolesulfonyl azide 1030824-60-2 C3H2N4O2S2
    2-thiazolesulfonyl azide
    —— 6-[(5-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]-1,2,4-triazine-3,5(2H,4H)-dione 1018047-62-5 C6H6N6O2S
    6-[(5-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]-1,2,4-triazine-3,5(2H,4H)-dione
    —— (Z)-2-butylthio-3-(1-cyclohexenyl)-2-hexen-4-yne 87253-45-0 C16H24S
    (Z)-2-butylthio-3-(1-cyclohexenyl)-2-hexen-4-yne
    —— 5-methoxy-2-methylthio-3-(β-nitrovinyl)thiophene 95412-01-4 C8H9NO3S2
    5-methoxy-2-methylthio-3-(β-nitrovinyl)thiophene
    —— Copper(1+) 2-(ethylsulfanyl)benzen-1-ide 192625-62-0 C8H9CuS
    Copper(1+) 2-(ethylsulfanyl)benzen-1-ide
    —— [(3-Bromobutyl)sulfanyl]benzene 1394041-75-8 C10H13BrS
    [(3-Bromobutyl)sulfanyl]benzene
    —— Hexakis(thiourea)dicopper dichloride 15489-72-2 C6H24Cl2Cu2N12S6
    Hexakis(thiourea)dicopper dichloride
    —— 1,2-Dichloropropane;1,3-dichloroprop-1-ene;methylimino(sulfanylidene)methane 8066-01-1 C8H13Cl4NS
    1,2-Dichloropropane;1,3-dichloroprop-1-ene;methylimino(sulfanylidene)methane
    —— 2-[2-Hydroxy-5-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-4-(2,4,4-trimethylpentan-2-yl)phenol;nickel;propan-2-ol —— C31H50NiO3S
    2-[2-Hydroxy-5-(2,4,4-trimethylpentan-2-yl)phenyl]sulfanyl-4-(2,4,4-trimethylpentan-2-yl)phenol;nickel;propan-2-ol
    —— Magnesium;2-[2-oxido-5-(4,6,8-trimethylnonan-2-yl)phenyl]sulfanyl-4-(4,6,8-trimethylnonan-2-yl)phenolate —— C36H56MgO2S
    Magnesium;2-[2-oxido-5-(4,6,8-trimethylnonan-2-yl)phenyl]sulfanyl-4-(4,6,8-trimethylnonan-2-yl)phenolate
    —— 2-[(4-Amino-2-chlorophenyl)thio]ethanol 22133-44-4 C8H10ClNOS
    2-[(4-Amino-2-chlorophenyl)thio]ethanol
    —— 3-[[11-ethyl-12-(4-hydroxyphenyl)-6H-benzo[c][1]benzothiocin-3-yl]oxy]propane-1,2-diol 85864-54-6 C26H26O4S
    3-[[11-ethyl-12-(4-hydroxyphenyl)-6H-benzo[c][1]benzothiocin-3-yl]oxy]propane-1,2-diol
    —— 4-(11-ethyl-3-prop-2-enoxy-6H-benzo[c][1]benzothiocin-12-yl)phenol 85850-88-0 C26H24O2S
    4-(11-ethyl-3-prop-2-enoxy-6H-benzo[c][1]benzothiocin-12-yl)phenol
    —— 1-[N-(dimethylamino)-N'-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-1,2-bis(4-fluorophenyl)-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine 132658-70-9 C26H28F2N12O2S2
    1-[N-(dimethylamino)-N'-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)carbamimidoyl]-1,2-bis(4-fluorophenyl)-3-(6-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazin-4-yl)guanidine
    —— N'-methyl-N-[C-methyl-N-(trimethylazaniumyl)carbonimidoyl]carbamimidothioate 77510-02-2 C7H16N4S
    N'-methyl-N-[C-methyl-N-(trimethylazaniumyl)carbonimidoyl]carbamimidothioate
    —— N'-cyclohexyl-N-[C-methyl-N-(trimethylazaniumyl)carbonimidoyl]carbamimidothioate 77510-03-3 C12H24N4S
    N'-cyclohexyl-N-[C-methyl-N-(trimethylazaniumyl)carbonimidoyl]carbamimidothioate
    —— (p-Chlorphenylthio)essigsaeure-octylester 15446-24-9 C16H23ClO2S
    (p-Chlorphenylthio)essigsaeure-octylester
    —— 9-thiatribenzo[c,g,j]cycloundeca-1(E/Z),3,5(Z/E),7,10-pentaene 28890-84-8 C22H16S
    9-thiatribenzo[c,g,j]cycloundeca-1(E/Z),3,5(Z/E),7,10-pentaene
    —— Benzenemethanol, 2-(ethylthio)-6-fluoro-I+/--methyl-, (I+/-S)- 1344913-02-5 C10H13FOS
    Benzenemethanol, 2-(ethylthio)-6-fluoro-I+/--methyl-, (I+/-S)-
    —— 2-Pyrrolidinepropanol, 1-[(2,3-dihydrobenzo[b]thien-2-yl)methyl]- 1500245-14-6 C16H23NOS
    2-Pyrrolidinepropanol, 1-[(2,3-dihydrobenzo[b]thien-2-yl)methyl]-
    —— Acetic acid, 2-[[4-fluoro-2-[(1R)-1-hydroxyethyl]phenyl]thio]-, methyl ester 1344958-88-8 C11H13FO3S
    Acetic acid, 2-[[4-fluoro-2-[(1R)-1-hydroxyethyl]phenyl]thio]-, methyl ester
    —— 1H-Indole-2,3-dione, 5-chloro-6-[(1-methyl-1H-tetrazol-5-yl)thio]- 1521854-25-0 C10H6ClN5O2S
    1H-Indole-2,3-dione, 5-chloro-6-[(1-methyl-1H-tetrazol-5-yl)thio]-
    —— 3-Propylsulfonyl-2,2-dimethylpropionsaeure 59358-18-8 C8H16O4S
    3-Propylsulfonyl-2,2-dimethylpropionsaeure
    —— N-Methyl-5-[[5-phenyl-2-(1-piperidinylmethyl)thieno[2,3-d]pyrimidin-4-yl]thio]-1,3,4-thiadiazol-2-amine 1031130-69-4 C21H22N6S3
    N-Methyl-5-[[5-phenyl-2-(1-piperidinylmethyl)thieno[2,3-d]pyrimidin-4-yl]thio]-1,3,4-thiadiazol-2-amine
    —— 3-(2-amino-5-bromophenyl)sulfanyl-N,N-dimethylpropanamide 1219728-51-4 C11H15BrN2OS
    3-(2-amino-5-bromophenyl)sulfanyl-N,N-dimethylpropanamide
    —— methyl 3-(p-tolylthio)acrylate 1277172-77-6 C11H12O2S
    methyl 3-(p-tolylthio)acrylate
    —— 2-Amino-6-(4-trifluoromethyl-phenylsulfanyl)-benzonitrile 168910-70-1 C14H9F3N2S
    2-Amino-6-(4-trifluoromethyl-phenylsulfanyl)-benzonitrile
    —— 1-Methanesulfonyl-2-methylpropan-2-amine 409095-78-9 C5H13NO2S
    1-Methanesulfonyl-2-methylpropan-2-amine
    —— 6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-one 155996-46-6 C10H12OS2
    6-vinyl-1,4-dithiaspiro<4.5>dec-6-en-8-one
    —— 4-(2-propynylthio)-2-vinyl-2-cyclohexen-1-one dimethylene dithioketal 155996-18-2 C13H16S3
    4-(2-propynylthio)-2-vinyl-2-cyclohexen-1-one dimethylene dithioketal
    —— 4-phenylthio-1H-1,2,3-triazole 150366-90-8 C8H7N3S
    4-phenylthio-1H-1,2,3-triazole
    —— (1Z,3E)-1-(methylsulfonyl)-1,3-hexadiene 142868-74-4 C7H12O2S
    (1Z,3E)-1-(methylsulfonyl)-1,3-hexadiene
    —— 2-Amino-6-[4-(1,1-dimethyl-propyl)-phenylsulfanyl]-benzonitrile 168910-65-4 C18H20N2S
    2-Amino-6-[4-(1,1-dimethyl-propyl)-phenylsulfanyl]-benzonitrile
    —— N-methyl-4'-<<4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thien-2-yl>thio>acetanilide 171285-77-1 C19H23NO3S2
    N-methyl-4'-<<4-(2,2,4-trimethyl-1,3-dioxolan-4-yl)thien-2-yl>thio>acetanilide
    —— 6-(4-chlorophenylsulfanyl)-2-(phenylacetamido)-9H-purine 1026560-19-9 C19H14ClN5OS
    6-(4-chlorophenylsulfanyl)-2-(phenylacetamido)-9H-purine