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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4,4-dioxo-4λ<sup>6</sup>thia-heptanedioic acid diamide 13063-92-8 C6H12N2O4S
    4,4-dioxo-4λ<sup>6</sup>thia-heptanedioic acid diamide
    —— bis-(propane-1-sulfonyl)-methane 129136-24-9 C7H16O4S2
    bis-(propane-1-sulfonyl)-methane
    —— (phenylthiomethylene)cyclopentane 71221-44-8 C12H14S
    (phenylthiomethylene)cyclopentane
    —— 3-allylmercapto-6-isopropyl-4H-[1,2,4]triazin-5-one 925459-54-7 C9H13N3OS
    3-allylmercapto-6-isopropyl-4H-[1,2,4]triazin-5-one
    —— (5S)-5-methyl-3-[7-[(2S)-oxiran-2-yl]heptyl]-3-phenylsulfanyloxolan-2-one 184435-81-2 C20H28O3S
    (5S)-5-methyl-3-[7-[(2S)-oxiran-2-yl]heptyl]-3-phenylsulfanyloxolan-2-one
    —— 2-morpholin-4-ylimino-1-(4-phenylsulfanyl-phenyl)-ethanone 25561-45-9 C18H18N2O2S
    2-morpholin-4-ylimino-1-(4-phenylsulfanyl-phenyl)-ethanone
    —— oxo-(4-phenylsulfanyl-phenyl)-acetaldehyde 42069-43-2 C14H10O2S
    oxo-(4-phenylsulfanyl-phenyl)-acetaldehyde
    —— 1-[(2-bromo-5-fluorophenyl)sulfanyl]-N,N-dimethylformamide 147460-42-2 C9H9BrFNOS
    1-[(2-bromo-5-fluorophenyl)sulfanyl]-N,N-dimethylformamide
    —— 2,2-bis-(2-hydroxy-ethanesulfonyl)-propane 98433-55-7 C7H16O6S2
    2,2-bis-(2-hydroxy-ethanesulfonyl)-propane
    —— 2-chloroethyl butyl sulfone 59681-98-0 C6H13ClO2S
    2-chloroethyl butyl sulfone
    —— (Z,Z)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{[4-methoxy-2-(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine 211758-83-7 C36H50N2O3SSi
    (Z,Z)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{[4-methoxy-2-(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine
    —— 2,2-bis-(2-chloro-ethanesulfonyl)-propane 41123-60-8 C7H14Cl2O4S2
    2,2-bis-(2-chloro-ethanesulfonyl)-propane
    —— vinyl butyl sulfone 16841-53-5 C6H12O2S
    vinyl butyl sulfone
    —— (1-Methoxy-2-octyloxy-ethylsulfanyl)-benzene 92573-67-6 C17H28O2S
    (1-Methoxy-2-octyloxy-ethylsulfanyl)-benzene
    —— 2,2-bis-ethylenesulfonyl-propane 41123-56-2 C7H12O4S2
    2,2-bis-ethylenesulfonyl-propane
    —— 2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)-N-methylbenzamide 1005785-04-5 C18H17N5O2S
    2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)-N-methylbenzamide
    —— 2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)-N-(1,3-dimethyl-1H-pyrazol-5-yl)benzamide 1005787-57-4 C22H21N7O2S
    2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)-N-(1,3-dimethyl-1H-pyrazol-5-yl)benzamide
    —— 2-benzyl-2-(5-bromopentyl)-1,3-dithiane 108296-19-1 C16H23BrS2
    2-benzyl-2-(5-bromopentyl)-1,3-dithiane
    —— 1-difluoromethyl-4,5-dimethyl-2-(propylsulfonyl)cyclohexa-1,4-diene 389574-97-4 C12H18F2O2S
    1-difluoromethyl-4,5-dimethyl-2-(propylsulfonyl)cyclohexa-1,4-diene
    —— (4R)-4-[(tert-butoxycarbonyl)methylamino]-5-methylhexanethioamide 1174764-16-9 C13H26N2O2S
    (4R)-4-[(tert-butoxycarbonyl)methylamino]-5-methylhexanethioamide
    —— 5,6-diamino-2-[4,5-bis(decylthio)-1,3-dithio-2-ylidene]-benzo[d]-1,3-dithiole 1233730-95-4 C30H48N2S6
    5,6-diamino-2-[4,5-bis(decylthio)-1,3-dithio-2-ylidene]-benzo[d]-1,3-dithiole
    —— 3-{[(5-chloro-thiophen-3-yl)methyl]thio}-6-(2-phenylethyl)-1,2,4-triazin-5(2H)-one 824983-31-5 C16H14ClN3OS2
    3-{[(5-chloro-thiophen-3-yl)methyl]thio}-6-(2-phenylethyl)-1,2,4-triazin-5(2H)-one
    —— 1-methylthio-1,2-hexadiene 3488-34-4 C7H12S
    1-methylthio-1,2-hexadiene
    —— 3-dimethylcarbamoylthio-2-nitropyridine 152170-27-9 C8H9N3O3S
    3-dimethylcarbamoylthio-2-nitropyridine
    —— 1-<3-(phenylselanyl)propyl>-2-(phenylsulfanyl)-1H-benzimidazole 191542-43-5 C22H20N2SSe
    1-<3-(phenylselanyl)propyl>-2-(phenylsulfanyl)-1H-benzimidazole
    —— O-Methyl (Pentafluorosulfanyl)thiocarbamate 90597-99-2 C2H4F5NOS2
    O-Methyl (Pentafluorosulfanyl)thiocarbamate
    —— 2,2-dimethyl-6-[2-(5-methyl-5-methylcarbamoyl-hexyl)-[1,3]dithian-2-yl]-hexanoic acid methylamide 413628-25-8 C22H42N2O2S2
    2,2-dimethyl-6-[2-(5-methyl-5-methylcarbamoyl-hexyl)-[1,3]dithian-2-yl]-hexanoic acid methylamide
    —— 3-methylthiopropanal 54261-38-0 C4H8S
    3-methylthiopropanal
    —— ((E)-2-Nitro-propenylsulfanyl)-benzene 101933-31-7 C9H9NO2S
    ((E)-2-Nitro-propenylsulfanyl)-benzene
    —— 4-bromo-2,6-dimethylthioanisole 648906-19-8 C9H11BrS
    4-bromo-2,6-dimethylthioanisole
    —— 1-phenylsulfanyl-decan-4-one 62358-94-5 C16H24OS
    1-phenylsulfanyl-decan-4-one
    —— 2-((1H-tetrazol-5-yl)thio)acetamide 1619908-33-6 C3H5N5OS
    2-((1H-tetrazol-5-yl)thio)acetamide
    —— (2S,4R)-4,5-bis[[tert-butyl(diphenyl)silyl]oxy]-1-[2-[(2S)-2-methoxypent-4-enyl]-1,3-dithian-2-yl]pentan-2-ol 204448-39-5 C47H64O4S2Si2
    (2S,4R)-4,5-bis[[tert-butyl(diphenyl)silyl]oxy]-1-[2-[(2S)-2-methoxypent-4-enyl]-1,3-dithian-2-yl]pentan-2-ol
    —— 4-Benzo[1,3]dioxol-5-ylmethyl-2-bromo-1-methyl-5-phenylsulfanyl-1H-imidazole 181880-03-5 C18H15BrN2O2S
    4-Benzo[1,3]dioxol-5-ylmethyl-2-bromo-1-methyl-5-phenylsulfanyl-1H-imidazole
    —— 5-chloro-2-phenylsulfanyl-[3]pyridylamine 99852-32-1 C11H9ClN2S
    5-chloro-2-phenylsulfanyl-[3]pyridylamine
    —— 1-(tert-Butyldimethylsiloxy)-1-(phenylthio)ethene 136629-03-3 C14H22OSSi
    1-(tert-Butyldimethylsiloxy)-1-(phenylthio)ethene
    —— (2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-ol 193970-59-1 C22H32O4S2
    (2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-ol
    —— {5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazol-4-yl}-(4-methoxy-phenyl)-methanol 197151-44-3 C30H34N2O7S
    {5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazol-4-yl}-(4-methoxy-phenyl)-methanol
    —— S-Methylsulfenyl O-Ethyl Thiocarbonate 64231-91-0 C4H8O2S2
    S-Methylsulfenyl O-Ethyl Thiocarbonate
    —— N-cyano-N'-methyl-N'-trimethylsilylmethyl-S-methylisothiourea 137777-76-5 C8H17N3SSi
    N-cyano-N'-methyl-N'-trimethylsilylmethyl-S-methylisothiourea
    —— S-(2-Amino-3,4-dicarbamoylpyrrol-2-yl)thioessigsaeureethylester 120168-29-8 C10H14N4O4S
    S-(2-Amino-3,4-dicarbamoylpyrrol-2-yl)thioessigsaeureethylester
    —— (1S,4S,8R)-8-[(1R)-1-(phenylthiomethyl)-2-methylpropyl]-1-methylbicyclo[2.2.2]oct-5-en-2-one 583865-98-9 C20H26OS
    (1S,4S,8R)-8-[(1R)-1-(phenylthiomethyl)-2-methylpropyl]-1-methylbicyclo[2.2.2]oct-5-en-2-one
    —— 2-(Phenylsulfanyl)cyclobutane-1-carboxylic acid 88112-37-2 C11H12O2S
    2-(Phenylsulfanyl)cyclobutane-1-carboxylic acid
    —— 4-[3-(tert-butyldimethylsiloxy)-4-methoxybenzyl]-5-(4-methoxybenzyl)-1-methyl-2-phenylsulfanyl-1H-imidazole 443095-84-9 C32H40N2O3SSi
    4-[3-(tert-butyldimethylsiloxy)-4-methoxybenzyl]-5-(4-methoxybenzyl)-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 2,2'-bis[(S)-4-isopropyloxazolin-2-yl]diphenylsulfide 464181-03-1 C24H28N2O2S
    2,2'-bis[(S)-4-isopropyloxazolin-2-yl]diphenylsulfide
    —— 2-(S)-mercaptopropanol 16495-24-2 C3H8OS
    2-(S)-mercaptopropanol
    —— 5-tert-butyl-2,3-dihydrobenzo[b]thiophene-2,3-dione 1284213-64-4 C12H12O2S
    5-tert-butyl-2,3-dihydrobenzo[b]thiophene-2,3-dione
    —— 3-ethyl-2-(phenylthio)-1,3-butadiene 144453-29-2 C12H14S
    3-ethyl-2-(phenylthio)-1,3-butadiene
    —— N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridine)but-3-enamide 325737-00-6 C12H15NO2S
    N-(2-(methylsulfanyl)-5,6-dihydro-4H-furo[2,3-b]pyridine)but-3-enamide
    —— N-[(2S)-1-hydroxy-3-methylbutan-2-yl]ethanethioamide 1084771-95-8 C7H15NOS
    N-[(2S)-1-hydroxy-3-methylbutan-2-yl]ethanethioamide