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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl 2-methyl-3-sulfonyltridecanoate 294201-72-2 C14H28O4S
    methyl 2-methyl-3-sulfonyltridecanoate
    —— N-[(3-Chloro-phenyl)-p-tolylsulfanyl-methyl]-formamide 1027905-74-3 C15H14ClNOS
    N-[(3-Chloro-phenyl)-p-tolylsulfanyl-methyl]-formamide
    —— 7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decane-7-carbonitrile 178207-74-4 C16H19NO2S
    7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decane-7-carbonitrile
    —— 2-<(2,4-diacetylaminophenyl)thio>benzothiazole 219649-10-2 C17H15N3O2S2
    2-<(2,4-diacetylaminophenyl)thio>benzothiazole
    —— (2R,3S,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolane-3-carboxylic acid 180267-08-7 C25H38O4S
    (2R,3S,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolane-3-carboxylic acid
    —— 4-Ethylsulfanyl-6-phenyl-thieno[2,3-c]furan 181868-55-3 C14H12OS2
    4-Ethylsulfanyl-6-phenyl-thieno[2,3-c]furan
    —— 3-(5-Methyl-2-methylsulfanyl-pyrimidin-4-yloxy)-propan-1-ol 190069-96-6 C9H14N2O2S
    3-(5-Methyl-2-methylsulfanyl-pyrimidin-4-yloxy)-propan-1-ol
    —— 4-Bromo-5-[(tert-butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 197151-42-1 C27H37BrN2O5SSi
    4-Bromo-5-[(tert-butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— (E,E)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{4-methoxy-2-[(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine 211758-75-7 C36H50N2O3SSi
    (E,E)-3-[5-(tert-butyldimethylsiloxy)pent-3-en-1-yl]-2-(6-{4-methoxy-2-[(phenylsulfanyl)methyl]pyridyn-3-yl}hex-3-en-1-yl)-4-methoxypyridine
    —— 2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylic acid tert-butyl ester 188014-45-1 C47H81NO2S6
    2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-[1,3]dithiolo[4,5-c]pyrrole-5-carboxylic acid tert-butyl ester
    —— [(4-(2-cyanoethyl)phenyl)thio]acetic acid 340131-08-0 C11H11NO2S
    [(4-(2-cyanoethyl)phenyl)thio]acetic acid
    —— ethyl [(4-(2-cyanoethyl)phenyl)thio]acetate 340131-06-8 C13H15NO2S
    ethyl [(4-(2-cyanoethyl)phenyl)thio]acetate
    —— (2R)-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propane-1,2-diol 153607-82-0 C11H22O4S2
    (2R)-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propane-1,2-diol
    —— 1,3-Dimethyl-5-[3-(2-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione 310405-11-9 C17H18N2O3S
    1,3-Dimethyl-5-[3-(2-methyl-benzyloxy)-prop-2-ynylsulfanyl]-1H-pyrimidine-2,4-dione
    —— 5-Ethyl-1-(2-methoxyethoxy)-6-methylsulfanylpyrimidine-2,4-dione 191472-49-8 C10H16N2O4S
    5-Ethyl-1-(2-methoxyethoxy)-6-methylsulfanylpyrimidine-2,4-dione
    —— 6-Methylsulfanyl-5-propan-2-yl-1-propoxypyrimidine-2,4-dione 191472-36-3 C11H18N2O3S
    6-Methylsulfanyl-5-propan-2-yl-1-propoxypyrimidine-2,4-dione
    —— tert-Butyl-dimethyl-(3,3,4,6,7-pentamethyl-2,3-dihydro-benzo[b]thiophen-5-yloxy)-silane 205182-92-9 C19H32OSSi
    tert-Butyl-dimethyl-(3,3,4,6,7-pentamethyl-2,3-dihydro-benzo[b]thiophen-5-yloxy)-silane
    —— 4-[2-(5-methyl-2-methylsulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)ethyl]isoxazole-3-carboxylic acid ethyl ester 190070-36-1 C14H17N3O4S
    4-[2-(5-methyl-2-methylsulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)ethyl]isoxazole-3-carboxylic acid ethyl ester
    —— [(3aR,4S,7aS)-1-[(E,2R)-5-tert-butylsulfonylpent-4-en-2-yl]-7a-methyl-3,3a,4,5,6,7-hexahydroinden-4-yl]oxy-triethylsilane 250384-97-5 C25H46O3SSi
    [(3aR,4S,7aS)-1-[(E,2R)-5-tert-butylsulfonylpent-4-en-2-yl]-7a-methyl-3,3a,4,5,6,7-hexahydroinden-4-yl]oxy-triethylsilane
    —— (2R,6S,7S,9R,14R,15R)-14-<(S)-(tert-Butyldimethylsilyloxy)phenylmethyl>-15-hydroxymethyl-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecane 244155-76-8 C40H54O6S2Si
    (2R,6S,7S,9R,14R,15R)-14-<(S)-(tert-Butyldimethylsilyloxy)phenylmethyl>-15-hydroxymethyl-2,9-bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecane
    —— 2,2-bis(methylthio)-1-cyclobutanemethanol 294868-55-6 C7H14OS2
    2,2-bis(methylthio)-1-cyclobutanemethanol
    —— (2S,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid methyl ester 95190-82-2 C11H14O3S
    (2S,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid methyl ester
    —— 2-azido-1,3-benzodithiol-4-carboxyic acid methyl ester 311311-02-1 C9H7N3O2S2
    2-azido-1,3-benzodithiol-4-carboxyic acid methyl ester
    —— 4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-one 172978-85-7 C20H22OS
    4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-one
    —— 2-Methylsulfanyl-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-1-ylium 105580-78-7 C6H7S5
    2-Methylsulfanyl-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-1-ylium
    —— 4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-ol 1027295-76-6 C20H24OS
    4-Phenyl-6-phenylsulfanylmethyl-hept-6-en-2-ol
    —— 2-Chloro-5-(trifluoromethylthio)aniline 933674-81-8 C7H5ClF3NS
    2-Chloro-5-(trifluoromethylthio)aniline
    —— Ethyl 3-(4-bromophenylthio)-2-cyano-3-(methylthio)acrylate —— C13H12BrNO2S2
    Ethyl 3-(4-bromophenylthio)-2-cyano-3-(methylthio)acrylate
    —— Ethyl 3-(4-chlorophenylthio)-2-cyano-3-(methylthio)acrylate —— C13H12ClNO2S2
    Ethyl 3-(4-chlorophenylthio)-2-cyano-3-(methylthio)acrylate
    —— Triethyl-{(3aR,4S,7aS)-1-[(E)-(R)-4-fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-silane 250385-03-6 C25H45FO3SSi
    Triethyl-{(3aR,4S,7aS)-1-[(E)-(R)-4-fluoro-1-methyl-4-(2-methyl-propane-2-sulfonyl)-but-3-enyl]-7a-methyl-3a,4,5,6,7,7a-hexahydro-3H-inden-4-yloxy}-silane
    —— 4-Amino-3-allylthio-5-methyl-4H-1,2,4-triazole 341520-10-3 C6H10N4S
    4-Amino-3-allylthio-5-methyl-4H-1,2,4-triazole
    —— 2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole 188014-44-0 C42H73NS6
    2-(4,5-Bis-hexadecylsulfanyl-[1,3]dithiol-2-ylidene)-4,6-dimethyl-5H-[1,3]dithiolo[4,5-c]pyrrole
    —— 2-Oct-2-ynylsulfanylphenol 217187-39-8 C14H18OS
    2-Oct-2-ynylsulfanylphenol
    —— (1S)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine 350678-28-3 C16H19NS
    (1S)-1-phenyl-N-(2-phenylsulfanylethyl)ethanamine
    —— 1-(2,5-Dimethyl-phenylsulfanyl)-2,5-dimethyl-4-methylsulfanyl-benzene 175548-63-7 C17H20S2
    1-(2,5-Dimethyl-phenylsulfanyl)-2,5-dimethyl-4-methylsulfanyl-benzene
    —— 2-Butylsulfanyl-thioisonicotinamide 180791-06-4 C10H14N2S2
    2-Butylsulfanyl-thioisonicotinamide
    —— N-[(1R)-1-phenylethyl]-N-(2-phenylsulfanylethyl)formamide 350678-31-8 C17H19NOS
    N-[(1R)-1-phenylethyl]-N-(2-phenylsulfanylethyl)formamide
    —— [(2R,3R,3aR,9aR)-2-(2,4-Dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-3-phenylsulfanyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-acetic acid tert-butyl ester 185556-93-8 C33H52N2O8SSi2
    [(2R,3R,3aR,9aR)-2-(2,4-Dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-5,5,7,7-tetraisopropyl-3-phenylsulfanyl-tetrahydro-1,4,6,8-tetraoxa-5,7-disila-cyclopentacycloocten-3-yl]-acetic acid tert-butyl ester
    —— 5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-yl 2,2-dimethylpropanoate 211758-67-7 C35H44N2O4S
    5-[4-methoxy-2-[(E)-6-[4-methoxy-2-(phenylsulfanylmethyl)pyridin-3-yl]hex-3-enyl]pyridin-3-yl]pent-1-en-3-yl 2,2-dimethylpropanoate
    —— (2Z,4Z,6Z)-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trienal ethyl acetal 213456-92-9 C33H38O2S3
    (2Z,4Z,6Z)-8,8-dimethyl-2,4-bis(phenylthio)nona-1,4,6-trienal ethyl acetal
    —— 3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone 220008-41-3 C23H36O2S2Si
    3-{2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-[1,3]dithian-2-yl}-cyclohexanone
    —— dimethyl(2-methylprop-2-enyl)[1-phenyl-3,3-bis(phenylthio)propoxy]silane 332188-29-1 C27H32OS2Si
    dimethyl(2-methylprop-2-enyl)[1-phenyl-3,3-bis(phenylthio)propoxy]silane
    —— [2R-(1E,2α,3α,5β)]-[[[3,5-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-[(phenylthio)methyl]cyclohexylidene]methyl]thio]benzene 331732-45-7 C32H50O2S2Si2
    [2R-(1E,2α,3α,5β)]-[[[3,5-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-[(phenylthio)methyl]cyclohexylidene]methyl]thio]benzene
    —— 2-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane 332048-52-9 C12H22OS2
    2-(3,3-dimethylbutanoyl)-2-ethyl-1,3-dithiane
    —— 2-methyl-4(5)-methylthioimidazole 205311-55-3 C5H8N2S
    2-methyl-4(5)-methylthioimidazole
    —— 2-Ethylsulfanyl-isonicotinonitrile 180790-91-4 C8H8N2S
    2-Ethylsulfanyl-isonicotinonitrile
    —— 3-(3-Hydroxy-propyl)-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one 190069-94-4 C9H14N2O2S
    3-(3-Hydroxy-propyl)-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one
    —— 8-Oxa-1,4-dithiaspiro[4.5]decan-6-amine 205234-27-1 C7H13NOS2
    8-Oxa-1,4-dithiaspiro[4.5]decan-6-amine
    —— 6-acetoxy-4-(phenylthio)oct-2-yne 333347-52-7 C16H20O2S
    6-acetoxy-4-(phenylthio)oct-2-yne
    —— 1-Isocyanato-4-phenylsulfanylmethyl-benzene 1027150-33-9 C14H11NOS
    1-Isocyanato-4-phenylsulfanylmethyl-benzene