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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Piperidin-4-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428565-98-3 C17H16F3N5S
    3-Piperidin-4-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— 3-(Oxan-4-yl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428565-96-1 C17H15F3N4OS
    3-(Oxan-4-yl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— (3R)-3-ethyl-4-{2-(methylsulfanyl)-6-[1-(methylsulfonyl)cyclopropyl]pyrimidin-4-yl}morpholine 1426154-34-8 C15H23N3O3S2
    (3R)-3-ethyl-4-{2-(methylsulfanyl)-6-[1-(methylsulfonyl)cyclopropyl]pyrimidin-4-yl}morpholine
    —— (3R)-3-ethyl-4-{2-(methylsulfanyl)-6-[(methylsulfonyl)methyl]pyrimidin-4-yl}morpholine 1426154-33-7 C13H21N3O3S2
    (3R)-3-ethyl-4-{2-(methylsulfanyl)-6-[(methylsulfonyl)methyl]pyrimidin-4-yl}morpholine
    —— N-(4-{4-[(5-methoxypyrazin-2-yl)thio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide 1439936-51-2 C22H19N5O2S2
    N-(4-{4-[(5-methoxypyrazin-2-yl)thio]-2,6-dimethylphenyl}thiazol-2-yl)isonicotinamide
    —— S-(Chloromethyl) 1-butanesulfonothioate 16008-31-4 C5H11ClO2S2
    S-(Chloromethyl) 1-butanesulfonothioate
    —— Methylenebisbutanethiolsulfonate 16008-32-5 C9H20O4S4
    Methylenebisbutanethiolsulfonate
    —— 1-(4-Hydroxybutyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one 1040750-74-0 C15H17N5O2S
    1-(4-Hydroxybutyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one
    —— 1-[(Z)-4-hydroxybut-2-enyl]-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one 1200346-05-9 C15H15N5O2S
    1-[(Z)-4-hydroxybut-2-enyl]-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one
    —— 1-(2-Hydroxyethyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one 1210311-65-1 C13H13N5O2S
    1-(2-Hydroxyethyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one
    —— 1-(2-Hydroxyethoxymethyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one 1210311-54-8 C14H15N5O3S
    1-(2-Hydroxyethoxymethyl)-7-methylsulfanyl-3-phenyl-[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-one
    —— (3'aS,6'aR)-6-[(4-chlorophenyl)sulfanylmethyl]-6-methyl-spiro[1,2,4-trioxane-3,5'-1,3,3a,4,6,6a-hexahydropentalene]-2'-one 1227742-53-1 C18H21ClO4S
    (3'aS,6'aR)-6-[(4-chlorophenyl)sulfanylmethyl]-6-methyl-spiro[1,2,4-trioxane-3,5'-1,3,3a,4,6,6a-hexahydropentalene]-2'-one
    —— 7-Methyl-1,4-dithia-7-azaspiro<4.4>nonane-6,8-dione 73142-82-2 C7H9NO2S2
    7-Methyl-1,4-dithia-7-azaspiro<4.4>nonane-6,8-dione
    —— Bis(thiophen-2-ylsulfanyl)methanethione 1431702-29-2 C9H6S5
    Bis(thiophen-2-ylsulfanyl)methanethione
    —— (S)-4,4-difluoro-3-phenylsulfanyl-tridecanal 1452840-98-0 C19H28F2OS
    (S)-4,4-difluoro-3-phenylsulfanyl-tridecanal
    —— (3R,4R)-4-methyl-3-phenylsulfanylcyclohexan-1-one 1402414-69-0 C13H16OS
    (3R,4R)-4-methyl-3-phenylsulfanylcyclohexan-1-one
    —— 3-(3-((3,5-dichlorophenyl)thio)-6-methyl-1H-indol-2-yl)-N-hexylpropanamide 1429474-20-3 C24H28Cl2N2OS
    3-(3-((3,5-dichlorophenyl)thio)-6-methyl-1H-indol-2-yl)-N-hexylpropanamide
    —— 2-(1-(2-fluorobenzyl)-5-(oxazol-2-yl)-1H-pyrazol-3-yl)-5-(pyridin-2-ylthio)pyrimidin-4-ol 1446359-09-6 C22H15FN6O2S
    2-(1-(2-fluorobenzyl)-5-(oxazol-2-yl)-1H-pyrazol-3-yl)-5-(pyridin-2-ylthio)pyrimidin-4-ol
    —— (2R,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]pentadecane-2,4-diol 1428636-22-9 C27H46O3S2
    (2R,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]pentadecane-2,4-diol
    —— 7-methylsulfonyl-1,1-dioxo-N-phenyl-1lambda6,4,2-benzodithiazin-3-amine 1429321-56-1 C14H12N2O4S3
    7-methylsulfonyl-1,1-dioxo-N-phenyl-1lambda6,4,2-benzodithiazin-3-amine
    —— 3-(3-((3,5-dichlorophenyl)thio)-6-methyl-1H-indol-2-yl)propanamide 1429474-19-0 C18H16Cl2N2OS
    3-(3-((3,5-dichlorophenyl)thio)-6-methyl-1H-indol-2-yl)propanamide
    —— (R)-2-[2-Amino-5-(2-fluorophenylmethylthio)-thiazolo[4,5-d]pyrimidin-7-ylamino]-4-methyl-pentan-1-ol 463953-93-7 C18H22FN5OS2
    (R)-2-[2-Amino-5-(2-fluorophenylmethylthio)-thiazolo[4,5-d]pyrimidin-7-ylamino]-4-methyl-pentan-1-ol
    —— (2R)-2-[[2-amino-5-[(2-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol 463953-95-9 C18H22BrN5OS2
    (2R)-2-[[2-amino-5-[(2-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol
    —— (2R)-2-[[2-amino-5-[(4-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol 463953-97-1 C18H22BrN5OS2
    (2R)-2-[[2-amino-5-[(4-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol
    —— 2-[(2-Benzylsulfanylphenyl)iminomethyl]phenolate;cobalt(3+);nitrate 1428183-32-7 C40H32CoN2O2S2*NO3
    2-[(2-Benzylsulfanylphenyl)iminomethyl]phenolate;cobalt(3+);nitrate
    —— 2-(Piperidin-3-ylthio)pyridine hydrochloride 1198287-05-6 C10H15ClN2S
    2-(Piperidin-3-ylthio)pyridine hydrochloride
    —— 2-((Pyrrolidin-2-ylmethyl)thio)pyridine hydrochloride 1421002-29-0 C10H15ClN2S
    2-((Pyrrolidin-2-ylmethyl)thio)pyridine hydrochloride
    —— 3-Methyl-6-(piperidin-4-ylthio)pyridazine hydrochloride 1177283-45-2 C10H16ClN3S
    3-Methyl-6-(piperidin-4-ylthio)pyridazine hydrochloride
    —— (R)-2-(methylthio)-4-(pyrrolidin-3-ylthio)pyrimidine hydrochloride 1421025-23-1 C9H14ClN3S2
    (R)-2-(methylthio)-4-(pyrrolidin-3-ylthio)pyrimidine hydrochloride
    —— Sodium;[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]-(quinolin-8-ylmethylsulfanyl)phosphinate 1428964-51-5 C24H22N2O3PS2*Na
    Sodium;[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]-(quinolin-8-ylmethylsulfanyl)phosphinate
    —— Sodium;[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]-propylsulfanylphosphinate 1428964-53-7 C17H21NO3PS2*Na
    Sodium;[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]-propylsulfanylphosphinate
    —— Sodium;benzylsulfanyl-[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]phosphinate 1428964-52-6 C21H21NO3PS2*Na
    Sodium;benzylsulfanyl-[[2-[2-(hydroxymethyl)phenyl]sulfanylphenyl]methylamino]phosphinate
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-(1-phenylcyclopropyl)benzamide 1439553-76-0 C32H30N6OS
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-(1-phenylcyclopropyl)benzamide
    —— 3,3,3-Trifluoropropyl p-tolyl sulfide 1447671-85-3 C10H11F3S
    3,3,3-Trifluoropropyl p-tolyl sulfide
    —— S-(5-bromo-2-fluorophenyl)dimethylthiocarbamate 1431329-19-9 C9H9BrFNOS
    S-(5-bromo-2-fluorophenyl)dimethylthiocarbamate
    —— 8-(Mesitylthio)-9-(pent-4-yn-1-yl)-9H-purin-6-amine 1454619-17-0 C19H21N5S
    8-(Mesitylthio)-9-(pent-4-yn-1-yl)-9H-purin-6-amine
    —— Methyl 2-[(3-aminophenyl)thio]isonicotinate 1415719-19-5 C13H12N2O2S
    Methyl 2-[(3-aminophenyl)thio]isonicotinate
    —— 7-bromo-2-[4'-(tert-butylthio)phenyl]-1,8-dihydroazulene-1,1-dicarbonitrile 1430198-67-6 C22H19BrN2S
    7-bromo-2-[4'-(tert-butylthio)phenyl]-1,8-dihydroazulene-1,1-dicarbonitrile
    —— 2-[4'-(tert-butylthio)phenyl]-1,8a-dihydroazulene-1,1-dicarbonitrile 1430198-66-5 C22H20N2S
    2-[4'-(tert-butylthio)phenyl]-1,8a-dihydroazulene-1,1-dicarbonitrile
    —— 2-[4'-(tert-butylthio)phenyl]-7,8-dibromo-1,7,8,8a-tetrahydroazulene-1,1-dicarbonitrile 1445756-38-6 C22H20Br2N2S
    2-[4'-(tert-butylthio)phenyl]-7,8-dibromo-1,7,8,8a-tetrahydroazulene-1,1-dicarbonitrile
    —— (3R)-1-(5-chloro-6-ethyl-2-quinazolin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine 1275606-95-5 C20H20ClN7S
    (3R)-1-(5-chloro-6-ethyl-2-quinazolin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine
    —— 6-[[4-[(3R)-3-aminopyrrolidin-1-yl]-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]sulfanyl]-2,3-dihydroisoindol-1-one 1275604-51-7 C20H21ClN6OS
    6-[[4-[(3R)-3-aminopyrrolidin-1-yl]-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]sulfanyl]-2,3-dihydroisoindol-1-one
    —— 5-[[4-[(3R)-3-aminopyrrolidin-1-yl]-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]sulfanyl]-1,2-dihydropyrazolo[3,4-b]pyridin-3-one 1275607-19-6 C18H19ClN8OS
    5-[[4-[(3R)-3-aminopyrrolidin-1-yl]-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-yl]sulfanyl]-1,2-dihydropyrazolo[3,4-b]pyridin-3-one
    —— (3R)-1-(5-chloro-6-ethyl-2-pyrimidin-5-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine 1275604-75-5 C16H18ClN7S
    (3R)-1-(5-chloro-6-ethyl-2-pyrimidin-5-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine
    —— (3R)-1-[5-chloro-6-ethyl-2-(1,5-naphthyridin-3-ylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl]pyrrolidin-3-amine 1275604-90-4 C20H20ClN7S
    (3R)-1-[5-chloro-6-ethyl-2-(1,5-naphthyridin-3-ylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl]pyrrolidin-3-amine
    —— (3R)-1-[5-chloro-6-ethyl-2-(1-oxidoquinolin-1-ium-7-yl)sulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl]pyrrolidin-3-amine 1275606-44-4 C21H21ClN6OS
    (3R)-1-[5-chloro-6-ethyl-2-(1-oxidoquinolin-1-ium-7-yl)sulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl]pyrrolidin-3-amine
    —— (3R)-1-(5-chloro-6-ethyl-2-quinolin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine 1275606-42-2 C21H21ClN6S
    (3R)-1-(5-chloro-6-ethyl-2-quinolin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)pyrrolidin-3-amine
    —— (2R,3R,4S)-3-acetamido-4-[[N'-(2-phenylsulfanylethyl)carbamimidoyl]amino]-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid 1442563-31-6 C20H28N4O7S
    (2R,3R,4S)-3-acetamido-4-[[N'-(2-phenylsulfanylethyl)carbamimidoyl]amino]-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid
    —— (2R,3R,4S)-3-acetamido-4-[[amino-[(2-phenylsulfanylacetyl)amino]methylidene]amino]-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid 1442563-14-5 C20H26N4O8S
    (2R,3R,4S)-3-acetamido-4-[[amino-[(2-phenylsulfanylacetyl)amino]methylidene]amino]-2-[(1R,2R)-1,2,3-trihydroxypropyl]-3,4-dihydro-2H-pyran-6-carboxylic acid
    —— bis(2-hexylsulfonylethyl) diselenide 1448046-95-4 C16H34O4S2Se2
    bis(2-hexylsulfonylethyl) diselenide