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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 1-(4-chlorophenyl)cyclopentane-1-carboxylate —— C22H24ClNO3S
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 1-(4-chlorophenyl)cyclopentane-1-carboxylate
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C19H20N4OS3
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C17H18ClNOS2
    2-(2-chlorophenyl)sulfanyl-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(4-fluorophenyl)acetate —— C19H20FNO3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(4-fluorophenyl)acetate
    —— [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] adamantane-1-carboxylate —— C21H26ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] adamantane-1-carboxylate
    —— [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 2-(4-fluorophenyl)acetate —— C18H17ClFNO3S
    [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] 2-(4-fluorophenyl)acetate
    —— N-[(2R,4R)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide —— C19H21F2NO2S
    N-[(2R,4R)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide
    —— N-[(2R,4S)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide —— C19H21F2NO2S
    N-[(2R,4S)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide
    —— N-[(2S,4R)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide —— C19H21F2NO2S
    N-[(2S,4R)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide
    —— N-[(2S,4S)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide —— C19H21F2NO2S
    N-[(2S,4S)-4-(4-fluorophenyl)-4-hydroxybutan-2-yl]-3-(2-fluorophenyl)sulfanylpropanamide
    —— (3R)-3-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol —— C14H19F2NOS2
    (3R)-3-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol
    —— (2R)-3,3-dimethyl-N-(2-methyl-2-methylsulfonylpropyl)butan-2-amine —— C11H25NO2S
    (2R)-3,3-dimethyl-N-(2-methyl-2-methylsulfonylpropyl)butan-2-amine
    —— (3S)-3-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol —— C14H19F2NOS2
    (3S)-3-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol
    —— (2S)-3,3-dimethyl-N-(2-methyl-2-methylsulfonylpropyl)butan-2-amine —— C11H25NO2S
    (2S)-3,3-dimethyl-N-(2-methyl-2-methylsulfonylpropyl)butan-2-amine
    —— 5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C15H19N7S2
    5-[(1-butyltetrazol-5-yl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— (3R)-3-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol —— C14H19F2NOS2
    (3R)-3-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol
    —— (3S)-3-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol —— C14H19F2NOS2
    (3S)-3-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]thiolan-3-ol
    —— ethyl 2,5-dimethyl-4-[2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate —— C17H17N3O4S2
    ethyl 2,5-dimethyl-4-[2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1H-pyrrole-3-carboxylate
    —— (4R,6S)-6-methyl-N-[[1-(2-methylpropyl)imidazol-2-yl]methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C16H23N3S2
    (4R,6S)-6-methyl-N-[[1-(2-methylpropyl)imidazol-2-yl]methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (4S,6S)-6-methyl-N-[[1-(2-methylpropyl)imidazol-2-yl]methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C16H23N3S2
    (4S,6S)-6-methyl-N-[[1-(2-methylpropyl)imidazol-2-yl]methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (5S)-1-methyl-5-[[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one —— C14H20N2OS2
    (5S)-1-methyl-5-[[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one
    —— (5R)-5-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one —— C15H20F2N2OS
    (5R)-5-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one
    —— (5S)-1-methyl-5-[[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one —— C14H20N2OS2
    (5S)-1-methyl-5-[[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one
    —— (5R)-1-methyl-5-[[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one —— C14H20N2OS2
    (5R)-1-methyl-5-[[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one
    —— (5S)-5-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one —— C15H20F2N2OS
    (5S)-5-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one
    —— (5S)-5-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one —— C15H20F2N2OS
    (5S)-5-[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one
    —— (5R)-5-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one —— C15H20F2N2OS
    (5R)-5-[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]-1-methylpiperidin-2-one
    —— (5R)-1-methyl-5-[[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one —— C14H20N2OS2
    (5R)-1-methyl-5-[[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]amino]piperidin-2-one
    —— (1R)-N,N-dimethyl-N'-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine —— C16H24N4S2
    (1R)-N,N-dimethyl-N'-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine
    —— (1R)-N,N-dimethyl-N'-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine —— C16H24N4S2
    (1R)-N,N-dimethyl-N'-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine
    —— (1S)-N,N-dimethyl-N'-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine —— C16H24N4S2
    (1S)-N,N-dimethyl-N'-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine
    —— 4-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-N,N-dimethyloxan-4-amine —— C17H26F2N2OS
    4-[[[(1S)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-N,N-dimethyloxan-4-amine
    —— 4-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-N,N-dimethyloxan-4-amine —— C17H26F2N2OS
    4-[[[(1R)-1-[4-(difluoromethylsulfanyl)phenyl]ethyl]amino]methyl]-N,N-dimethyloxan-4-amine
    —— (1S)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(1-methylpyrazol-4-yl)ethanamine —— C14H18FN3S
    (1S)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(1-methylpyrazol-4-yl)ethanamine
    —— (1R)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(1-methylpyrazol-4-yl)ethanamine —— C14H18FN3S
    (1R)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(1-methylpyrazol-4-yl)ethanamine
    —— (1S)-N,N-dimethyl-N'-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine —— C16H24N4S2
    (1S)-N,N-dimethyl-N'-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-1-(1-methylpyrazol-4-yl)ethane-1,2-diamine
    —— (1R)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(oxan-4-yl)ethanamine —— C15H22FNOS
    (1R)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(oxan-4-yl)ethanamine
    —— N-benzyl-2-((2-oxo-1-(thiophen-2-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide —— C21H21N3O2S2
    N-benzyl-2-((2-oxo-1-(thiophen-2-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide
    —— 4-(ethylthio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C14H16N2OS2
    4-(ethylthio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 4-((2-chloro-6-fluorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C19H16ClFN2OS2
    4-((2-chloro-6-fluorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— (1S)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(oxan-4-yl)ethanamine —— C15H22FNOS
    (1S)-N-[2-(2-fluorophenyl)sulfanylethyl]-1-(oxan-4-yl)ethanamine
    —— 1-(furan-2-ylmethyl)-4-((3-methylbenzyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C20H20N2O2S
    1-(furan-2-ylmethyl)-4-((3-methylbenzyl)thio)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— 4-((4-chlorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C19H17ClN2OS2
    4-((4-chlorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— N-[[(2R)-oxolan-2-yl]methyl]-2-[[2-oxo-1-(thiophen-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide —— C19H23N3O3S2
    N-[[(2R)-oxolan-2-yl]methyl]-2-[[2-oxo-1-(thiophen-2-ylmethyl)-6,7-dihydro-5H-cyclopenta[d]pyrimidin-4-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-((2-oxo-1-(thiophen-2-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide —— C19H23N3O2S2
    N-cyclopentyl-2-((2-oxo-1-(thiophen-2-ylmethyl)-2,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-4-yl)thio)acetamide
    —— 4-((3-chlorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one —— C19H17ClN2OS2
    4-((3-chlorobenzyl)thio)-1-(thiophen-2-ylmethyl)-6,7-dihydro-1H-cyclopenta[d]pyrimidin-2(5H)-one
    —— N-(furan-2-ylmethyl)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C18H16F3N3O3S
    N-(furan-2-ylmethyl)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H10BrN3O2S
    (2S)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide —— C13H14BrN3O2S
    2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide
    —— (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C11H10BrN3O2S
    (2R)-2-[[5-(3-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide