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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[(3R)-3,5-dicyano-4,4-dimethyl-2-oxo-1,3-dihydropyridin-6-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C20H22N4O2S2
    2-[[(3R)-3,5-dicyano-4,4-dimethyl-2-oxo-1,3-dihydropyridin-6-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 1-Thiophen-2-ylsulfonyl-2,3-dihydropyrido[2,3-b][1,4]thiazine —— C11H10N2O2S3
    1-Thiophen-2-ylsulfonyl-2,3-dihydropyrido[2,3-b][1,4]thiazine
    —— (2S)-N-cyclopropyl-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C21H24N4OS2
    (2S)-N-cyclopropyl-2-[[4-(2-phenylethyl)-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-phenylpropyl)acetamide —— C19H18FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-phenylpropyl)acetamide
    —— 2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C21H18FN3O3S
    2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— ethyl N-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate —— C13H12FN3O4S
    ethyl N-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]carbamate
    —— 2-[(2-Bromophenyl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole —— C15H10BrFN2OS
    2-[(2-Bromophenyl)methylsulfanyl]-5-(4-fluorophenyl)-1,3,4-oxadiazole
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide —— C18H22FN3O2S
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C20H20FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H20FN3O2S
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide —— C18H22FN3O2S
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]propanamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide —— C19H18FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-phenylpropyl]acetamide
    —— (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]propanamide —— C18H22FN3O2S
    (2R)-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]propanamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide —— C12H12FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-Ethyl-7-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C11H12N6OS2
    2-Ethyl-7-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— 1-(4-Methylpiperazin-4-ium-1-yl)-2-(5-nitropyridin-2-yl)sulfanylethanone —— C12H17N4O3S+
    1-(4-Methylpiperazin-4-ium-1-yl)-2-(5-nitropyridin-2-yl)sulfanylethanone
    —— 7-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C17H17N3O3S2
    7-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanylmethyl)-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— ethyl (2Z)-2-[3-[2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C18H19N3O4S2
    ethyl (2Z)-2-[3-[2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— {2-Ethyl-5-oxo-5H-[1,3,4]thiadiazolo[3,2-A]pyrimidin-7-YL}methyl 2-(phenylsulfanyl)acetate —— C16H15N3O3S2
    {2-Ethyl-5-oxo-5H-[1,3,4]thiadiazolo[3,2-A]pyrimidin-7-YL}methyl 2-(phenylsulfanyl)acetate
    —— ethyl (2Z)-2-[3-[2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C18H19N3O4S2
    ethyl (2Z)-2-[3-[2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— N-[2-(4-chlorophenyl)sulfanylethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14ClN3OS3
    N-[2-(4-chlorophenyl)sulfanylethyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-(2,3,5,6-tetramethylphenyl)sulfanyl-N-(2-thiophen-2-ylethyl)acetamide —— C18H23NOS2
    2-(2,3,5,6-tetramethylphenyl)sulfanyl-N-(2-thiophen-2-ylethyl)acetamide
    —— [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C18H19N3O4S2
    [2-(2,5-Dimethylthiophen-3-yl)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide —— C12H14ClN5OS2
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-chlorophenyl)sulfanylethyl]acetamide
    —— 2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C19H19N3O2S2
    2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— (5-Methyl-1,2-oxazol-3-yl)methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H16N4O4S
    (5-Methyl-1,2-oxazol-3-yl)methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] cyclopropanecarboxylate —— C14H17NO3S
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] cyclopropanecarboxylate
    —— (1R,2S)-N-(2-bromoprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C10H18BrNO2S
    (1R,2S)-N-(2-bromoprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— (1S,2S)-N-(2-bromoprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C10H18BrNO2S
    (1S,2S)-N-(2-bromoprop-2-enyl)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H23NO3S2
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— 2-[(5-Methyl-1,2-oxazol-3-yl)methylsulfanyl]-5-(2-methylphenyl)-1,3,4-oxadiazole —— C14H13N3O2S
    2-[(5-Methyl-1,2-oxazol-3-yl)methylsulfanyl]-5-(2-methylphenyl)-1,3,4-oxadiazole
    —— [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] cyclopropanecarboxylate —— C14H16ClNO3S
    [2-[2-(4-Chlorophenyl)sulfanylethylamino]-2-oxoethyl] cyclopropanecarboxylate
    —— 2-(4-fluorophenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C18H13FN4O2S
    2-(4-fluorophenyl)-5-[(1R)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— [2-[2-(4-methylphenyl)sulfanylethylamino]-2-oxoethyl] (1R,5S)-9-oxobicyclo[3.3.1]nonane-3-carboxylate —— C21H27NO4S
    [2-[2-(4-methylphenyl)sulfanylethylamino]-2-oxoethyl] (1R,5S)-9-oxobicyclo[3.3.1]nonane-3-carboxylate
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide —— C15H19N5O2S2
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-(2-phenylsulfanylethyl)acetamide —— C18H21NOS2
    2-(2,4-dimethylphenyl)sulfanyl-N-(2-phenylsulfanylethyl)acetamide
    —— [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] 4-[(1R)-1-hydroxyethyl]-3,5-dimethyl-1H-pyrrole-2-carboxylate —— C19H24N2O4S
    [2-oxo-2-(2-phenylsulfanylethylamino)ethyl] 4-[(1R)-1-hydroxyethyl]-3,5-dimethyl-1H-pyrrole-2-carboxylate
    —— 2-[[4-(4-Chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C16H13ClN2OS4
    2-[[4-(4-Chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C21H23N3O2S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(3,4-dimethylphenyl)acetate —— C20H23NO3S
    [2-Oxo-2-(2-phenylsulfanylethylamino)ethyl] 2-(3,4-dimethylphenyl)acetate
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C20H23NO3S2
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— 2-(4-fluorophenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole —— C18H13FN4O2S
    2-(4-fluorophenyl)-5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-2-ethanimidoyl-4-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C13H13N5O2S2
    (2R)-2-ethanimidoyl-4-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— 2-phenyl-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole —— C16H13N5OS2
    2-phenyl-5-[(1R)-1-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethyl]-1,3,4-oxadiazole
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 1-(4-chlorophenyl)cyclopropane-1-carboxylate —— C21H22ClNO3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 1-(4-chlorophenyl)cyclopropane-1-carboxylate
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide —— C14H19N5OS2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-benzylsulfanylethyl)acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)acetamide —— C15H19N5O2S
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(cyclohexen-1-yl)-N-(furan-2-ylmethyl)acetamide
    —— N-(2-benzylsulfanylethyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C16H18N2O2S2
    N-(2-benzylsulfanylethyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-(2-benzylsulfanylethyl)-2-(4-bromophenyl)sulfanylacetamide —— C17H18BrNOS2
    N-(2-benzylsulfanylethyl)-2-(4-bromophenyl)sulfanylacetamide
    —— N-[(2,4-dimethylphenyl)methyl]-N-methyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S
    N-[(2,4-dimethylphenyl)methyl]-N-methyl-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide