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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H20N4O4S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-Oxo-2-(propylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H20N4O4S
    [2-Oxo-2-(propylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C18H23N5O4S
    [2-[[(2R)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C16H14ClF2NOS
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C16H21N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— (2S)-N-(6-methylsulfanylpyridin-3-yl)-2-phenylpropane-1-sulfonamide —— C15H18N2O2S2
    (2S)-N-(6-methylsulfanylpyridin-3-yl)-2-phenylpropane-1-sulfonamide
    —— [2-(5-Chlorothiophen-2-yl)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H14ClN3O4S2
    [2-(5-Chlorothiophen-2-yl)-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C18H23N5O4S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylacetamide —— C14H20N4OS3
    N-(1-cyanocyclohexyl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methylacetamide
    —— [(3R)-2-oxooxolan-3-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H15N3O5S
    [(3R)-2-oxooxolan-3-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide —— C19H21F2NOS
    (2R)-2-(3,4-difluorophenyl)sulfanyl-N-[(2S)-4-phenylbutan-2-yl]propanamide
    —— (2R)-N-(6-methylsulfanylpyridin-3-yl)-2-phenylpropane-1-sulfonamide —— C15H18N2O2S2
    (2R)-N-(6-methylsulfanylpyridin-3-yl)-2-phenylpropane-1-sulfonamide
    —— 1-[(2S)-butan-2-yl]-N-(4-methylsulfanyl-1H-pyrazol-5-yl)imidazole-4-sulfonamide —— C11H17N5O2S2
    1-[(2S)-butan-2-yl]-N-(4-methylsulfanyl-1H-pyrazol-5-yl)imidazole-4-sulfonamide
    —— 1-[(2R)-butan-2-yl]-N-(4-methylsulfanyl-1H-pyrazol-5-yl)imidazole-4-sulfonamide —— C11H17N5O2S2
    1-[(2R)-butan-2-yl]-N-(4-methylsulfanyl-1H-pyrazol-5-yl)imidazole-4-sulfonamide
    —— 2-(3,4-Difluorophenyl)sulfanyl-1-[2,5-dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]ethanone —— C19H17F2NOS2
    2-(3,4-Difluorophenyl)sulfanyl-1-[2,5-dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]ethanone
    —— N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C19H19F2NO3S2
    N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C19H19F2NO3S2
    N-benzyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(3,4-Difluorophenyl)sulfanyl-1-[1-[2-(4-fluorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]ethanone —— C22H20F3NOS
    2-(3,4-Difluorophenyl)sulfanyl-1-[1-[2-(4-fluorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-(3,4-difluorophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C18H19F2NOS
    2-(3,4-difluorophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— N-[(4-chlorophenyl)methyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C15H12ClF2NOS
    N-[(4-chlorophenyl)methyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide —— C20H15F2NOS2
    2-(3,4-difluorophenyl)sulfanyl-N-(2-phenylsulfanylphenyl)acetamide
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C14H14F2N2OS
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide —— C20H25F2NOS
    N-[(1R)-1-(1-adamantyl)ethyl]-2-(3,4-difluorophenyl)sulfanylacetamide
    —— 2-(3,4-difluorophenyl)sulfanyl-1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone —— C22H18F2N2O2S
    2-(3,4-difluorophenyl)sulfanyl-1-[(3R)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]ethanone
    —— (2S)-2-(3,4-difluorophenyl)sulfanylpropanamide —— C9H9F2NOS
    (2S)-2-(3,4-difluorophenyl)sulfanylpropanamide
    —— [(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]-[(1R,2S)-2-(1H-1,2,4-triazol-5-yl)cyclopropyl]methanone —— C17H20N4OS
    [(3R)-3-(phenylsulfanylmethyl)pyrrolidin-1-yl]-[(1R,2S)-2-(1H-1,2,4-triazol-5-yl)cyclopropyl]methanone
    —— (2R)-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C15H17N3O2S2
    (2R)-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C15H17N3O2S2
    (2S)-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— N-[(1S)-1-cyclopropylethyl]-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]acetamide —— C14H19N3O2S
    N-[(1S)-1-cyclopropylethyl]-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]acetamide —— C14H19N3O2S
    N-[(1R)-1-cyclopropylethyl]-2-[(4-oxo-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-2-yl)sulfanyl]acetamide
    —— 4-[(4-Chlorophenyl)methyl]-5-(2-phenylethylsulfanyl)-1,2,4-triazol-3-amine —— C17H17ClN4S
    4-[(4-Chlorophenyl)methyl]-5-(2-phenylethylsulfanyl)-1,2,4-triazol-3-amine
    —— 2-(3-amino-5-benzylsulfanyl-1,2,4-triazol-4-yl)-N-[(1R)-1-phenylethyl]acetamide —— C19H21N5OS
    2-(3-amino-5-benzylsulfanyl-1,2,4-triazol-4-yl)-N-[(1R)-1-phenylethyl]acetamide
    —— ethyl 2-[[5-[(1S,2R)-2-methyl-1-[(2-methylpropan-2-yl)oxycarbonylamino]butyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C16H27N3O5S
    ethyl 2-[[5-[(1S,2R)-2-methyl-1-[(2-methylpropan-2-yl)oxycarbonylamino]butyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— (2R)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2S)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide —— C19H28FNO2S
    (2R)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2S)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide
    —— (2R)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2R)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide —— C19H28FNO2S
    (2R)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2R)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide
    —— 3-Imino-6-methyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one —— C6H6N4OS
    3-Imino-6-methyl-[1,3]thiazolo[3,2-b][1,2,4]triazin-7-one
    —— (2S)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2R)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide —— C19H28FNO2S
    (2S)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2R)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide
    —— (2S)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2S)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide —— C19H28FNO2S
    (2S)-3-(4-fluorophenyl)sulfanyl-N-[[1-[(2S)-4-hydroxybutan-2-yl]cyclobutyl]methyl]-2-methylpropanamide
    —— methyl (2R)-2-[(5-amino-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-2,3-dihydrofuran-4-carboxylate —— C13H18N4O3S
    methyl (2R)-2-[(5-amino-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-2,3-dihydrofuran-4-carboxylate
    —— 3-[(4-Methylphenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-amine —— C13H18N4S
    3-[(4-Methylphenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-amine
    —— methyl (2S)-2-[(5-amino-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-2,3-dihydrofuran-4-carboxylate —— C13H18N4O3S
    methyl (2S)-2-[(5-amino-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-5-methyl-2,3-dihydrofuran-4-carboxylate
    —— 2-[(4-amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C14H19N5OS
    2-[(4-amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 3-(2-Phenylethylsulfanyl)-5-propyl-1,2,4-triazol-4-amine —— C13H18N4S
    3-(2-Phenylethylsulfanyl)-5-propyl-1,2,4-triazol-4-amine
    —— 2-[(4-amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylacetamide —— C13H17N5OS
    2-[(4-amino-5-ethyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylacetamide
    —— 2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylacetamide —— C15H21N5OS
    2-[(4-amino-5-butyl-1,2,4-triazol-3-yl)sulfanyl]-N-benzylacetamide
    —— 3-[(2-Bromophenyl)methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine —— C11H13BrN4S
    3-[(2-Bromophenyl)methylsulfanyl]-5-ethyl-1,2,4-triazol-4-amine
    —— 3-[(2-Methylphenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-amine —— C13H18N4S
    3-[(2-Methylphenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-amine
    —— 5-[(4-chlorophenyl)methyl]-2-ethylsulfanyl-4-methyl-1H-pyrimidin-6-one —— C14H15ClN2OS
    5-[(4-chlorophenyl)methyl]-2-ethylsulfanyl-4-methyl-1H-pyrimidin-6-one
    —— 3-Ethyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine —— C12H16N4S
    3-Ethyl-5-[(2-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— phenyl N-benzyl-3,4,4-trichloro-2-nitrobut-3-enimidothioate —— C17H13Cl3N2O2S
    phenyl N-benzyl-3,4,4-trichloro-2-nitrobut-3-enimidothioate