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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-3-[(1-methylpyrazol-4-yl)methyl]-1-(2-phenylsulfanylethyl)pyrrolidine-2,5-dione —— C17H19N3O2S
    (3R)-3-[(1-methylpyrazol-4-yl)methyl]-1-(2-phenylsulfanylethyl)pyrrolidine-2,5-dione
    —— (2R)-3-methyl-2-[4-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]piperazin-1-yl]butanenitrile —— C18H23N5O3S
    (2R)-3-methyl-2-[4-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]piperazin-1-yl]butanenitrile
    —— N-(furan-2-ylmethyl)-5-[(2R)-hex-5-en-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine —— C13H17N3OS2
    N-(furan-2-ylmethyl)-5-[(2R)-hex-5-en-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide —— C20H21ClN4OS
    2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide
    —— methyl (2S,3S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate —— C14H17N3O2S
    methyl (2S,3S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate
    —— 4-[[5-(diethoxymethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-[(1R)-1-methoxyethyl]-1,3-thiazole —— C15H24N4O3S2
    4-[[5-(diethoxymethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-[(1R)-1-methoxyethyl]-1,3-thiazole
    —— 3-[(2S)-hex-5-en-2-yl]sulfanyl-4-methyl-5-propan-2-yl-1,2,4-triazole —— C12H21N3S
    3-[(2S)-hex-5-en-2-yl]sulfanyl-4-methyl-5-propan-2-yl-1,2,4-triazole
    —— (2S)-3-methyl-2-[4-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]piperazin-1-yl]butanenitrile —— C18H23N5O3S
    (2S)-3-methyl-2-[4-[2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]piperazin-1-yl]butanenitrile
    —— methyl (2S,3R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate —— C14H17N3O2S
    methyl (2S,3R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate
    —— 2-[(2S)-hept-6-en-2-yl]sulfanyl-4-(trifluoromethyl)pyrimidine —— C12H15F3N2S
    2-[(2S)-hept-6-en-2-yl]sulfanyl-4-(trifluoromethyl)pyrimidine
    —— 3-[(2R)-hex-5-en-2-yl]sulfanyl-4-methyl-5-propan-2-yl-1,2,4-triazole —— C12H21N3S
    3-[(2R)-hex-5-en-2-yl]sulfanyl-4-methyl-5-propan-2-yl-1,2,4-triazole
    —— N-ethyl-5-[2-[(1S,5R)-8-oxa-3-azabicyclo[3.2.1]octan-3-yl]ethylsulfanyl]-1,3,4-thiadiazol-2-amine —— C12H20N4OS2
    N-ethyl-5-[2-[(1S,5R)-8-oxa-3-azabicyclo[3.2.1]octan-3-yl]ethylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[(2R)-hept-6-en-2-yl]sulfanyl-4-(trifluoromethyl)pyrimidine —— C12H15F3N2S
    2-[(2R)-hept-6-en-2-yl]sulfanyl-4-(trifluoromethyl)pyrimidine
    —— (1S,5R)-3-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-8-oxa-3-azabicyclo[3.2.1]octane —— C17H23NO3S
    (1S,5R)-3-[2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)ethyl]-8-oxa-3-azabicyclo[3.2.1]octane
    —— 2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate —— C17H20N2O5S2
    2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate
    —— methyl (2R,3S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate —— C14H17N3O2S
    methyl (2R,3S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate
    —— N-(furan-2-ylmethyl)-5-[(2S)-hex-5-en-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine —— C13H17N3OS2
    N-(furan-2-ylmethyl)-5-[(2S)-hex-5-en-2-yl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 4-[[5-(diethoxymethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-[(1S)-1-methoxyethyl]-1,3-thiazole —— C15H24N4O3S2
    4-[[5-(diethoxymethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-[(1S)-1-methoxyethyl]-1,3-thiazole
    —— 2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate —— C17H20N2O5S2
    2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate
    —— methyl (2R,3R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate —— C14H17N3O2S
    methyl (2R,3R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylbutanoate
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate —— C19H19N3O2S2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethyl 2-phenylacetate
    —— 3-[(2-methylpyrazol-3-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C16H24N6OS
    3-[(2-methylpyrazol-3-yl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— 3-[(2-methylpyrazol-3-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C16H24N6OS
    3-[(2-methylpyrazol-3-yl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— methyl (2S)-4-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]oxypentanoate —— C11H18N4O4S
    methyl (2S)-4-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]oxypentanoate
    —— 1-[(2S,5S)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone —— C15H21NOS
    1-[(2S,5S)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— [(3R)-3-methoxybutyl] 2-(1-methyltetrazol-5-yl)sulfanylacetate —— C9H16N4O3S
    [(3R)-3-methoxybutyl] 2-(1-methyltetrazol-5-yl)sulfanylacetate
    —— 1-[(2S,5R)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone —— C15H21NOS
    1-[(2S,5R)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— methyl (2R)-4-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]oxypentanoate —— C11H18N4O4S
    methyl (2R)-4-methyl-2-[2-(1-methyltetrazol-5-yl)sulfanylacetyl]oxypentanoate
    —— 2-Methyl-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,3,4-thiadiazole —— C8H10N4S2
    2-Methyl-5-[(1-methylimidazol-2-yl)sulfanylmethyl]-1,3,4-thiadiazole
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] cyclopentanecarboxylate —— C22H25NO3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] cyclopentanecarboxylate
    —— 1-[(2R,5S)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone —— C15H21NOS
    1-[(2R,5S)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— [(3S)-3-methoxybutyl] 2-(1-methyltetrazol-5-yl)sulfanylacetate —— C9H16N4O3S
    [(3S)-3-methoxybutyl] 2-(1-methyltetrazol-5-yl)sulfanylacetate
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] cyclopentanecarboxylate —— C20H21NO3S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] cyclopentanecarboxylate
    —— 1-methyl-N-[(3R)-2-methylpentan-3-yl]-3-methylsulfanylpyrazole-4-carboxamide —— C12H21N3OS
    1-methyl-N-[(3R)-2-methylpentan-3-yl]-3-methylsulfanylpyrazole-4-carboxamide
    —— [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-cyanobenzoate —— C24H20N2O3S
    [2-[4-(2,5-Dimethylphenyl)sulfanylanilino]-2-oxoethyl] 4-cyanobenzoate
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C17H19N3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [4-[(2S)-2-hydroxybutyl]piperazin-1-yl]-(1-methyl-3-methylsulfanylpyrazol-4-yl)methanone —— C14H24N4O2S
    [4-[(2S)-2-hydroxybutyl]piperazin-1-yl]-(1-methyl-3-methylsulfanylpyrazol-4-yl)methanone
    —— [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate —— C17H15FN2O3S2
    [(1R)-1-(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)ethyl] 3-(4-fluorophenyl)sulfanylpropanoate
    —— 1-methyl-N-[(3S)-2-methylpentan-3-yl]-3-methylsulfanylpyrazole-4-carboxamide —— C12H21N3OS
    1-methyl-N-[(3S)-2-methylpentan-3-yl]-3-methylsulfanylpyrazole-4-carboxamide
    —— 1-[(2R,5R)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone —— C15H21NOS
    1-[(2R,5R)-2-ethyl-5-methylpyrrolidin-1-yl]-2-phenylsulfanylethanone
    —— [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C17H20FNO5S2
    [2-[cyclopropyl-[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [4-[(2R)-2-hydroxybutyl]piperazin-1-yl]-(1-methyl-3-methylsulfanylpyrazol-4-yl)methanone —— C14H24N4O2S
    [4-[(2R)-2-hydroxybutyl]piperazin-1-yl]-(1-methyl-3-methylsulfanylpyrazol-4-yl)methanone
    —— tert-butyl N-[(1S)-1-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)-3-methylsulfanylpropyl]carbamate —— C13H23N3O3S2
    tert-butyl N-[(1S)-1-(5-ethylsulfanyl-1,3,4-oxadiazol-2-yl)-3-methylsulfanylpropyl]carbamate
    —— [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 2-phenylsulfanylacetate —— C15H15N3O5S
    [2-(6-Amino-1-methyl-2,4-dioxopyrimidin-5-yl)-2-oxoethyl] 2-phenylsulfanylacetate
    —— 6-Amino-5-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione —— C15H17N3O3S
    6-Amino-5-[2-(3,4-dimethylphenyl)sulfanylacetyl]-1-methylpyrimidine-2,4-dione
    —— (2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C21H23FN4OS
    (2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— (2R)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C13H14N4S
    (2R)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C13H14N4S
    (2S)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— 2-[(1S)-1-(5-methyl-1,3-oxazol-2-yl)ethyl]sulfanylpyridine-4-carbonitrile —— C12H11N3OS
    2-[(1S)-1-(5-methyl-1,3-oxazol-2-yl)ethyl]sulfanylpyridine-4-carbonitrile
    —— (2S)-N-(1-adamantyl)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C23H30N4OS
    (2S)-N-(1-adamantyl)-2-[(5-benzyl-4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide