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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Allylsulfanyl-5-thiocyanatomethylsulfanyl-[1,3,4]thiadiazole 56492-76-3 C7H7N3S4
    2-Allylsulfanyl-5-thiocyanatomethylsulfanyl-[1,3,4]thiadiazole
    —— (3R,5R)-(+)-5-(2-Ethyl-1,3-dithian-2-yl)-5-hydroxy-3-methyl-1-(((triethylsilyl)oxy)methyl)-3-((trimethylsilyl)oxy)cyclopentene 121888-14-0 C22H44O3S2Si2
    (3R,5R)-(+)-5-(2-Ethyl-1,3-dithian-2-yl)-5-hydroxy-3-methyl-1-(((triethylsilyl)oxy)methyl)-3-((trimethylsilyl)oxy)cyclopentene
    —— [LuI2(2-propanol)4]I 667419-69-4 C12H32I2LuO4*I
    [LuI2(2-propanol)4]I
    —— (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylthio)cyclohexane-1,2-diol 1,2-acetonide 82769-84-4 C26H33NO4S
    (1'S,1S,2S,3R,4R,6S)-2,6-dimethyl-3-<(((1'-phenylethyl)amino)carbonyl)oxy>-4-(phenylthio)cyclohexane-1,2-diol 1,2-acetonide
    —— 4-[1-(3,4-dimethoxyphenyl)ethyl]-2-phenyl-5-(phenylsulfanyl)thiazole 1253755-54-2 C25H23NO2S2
    4-[1-(3,4-dimethoxyphenyl)ethyl]-2-phenyl-5-(phenylsulfanyl)thiazole
    —— 2-diethylamino-4-methylsulfanyl-6,7-dihydro-oxazolo[3,2-<i>a</i>][1,3,5]triazinylium; chloride 69825-92-9 C10H17N4OS*Cl
    2-diethylamino-4-methylsulfanyl-6,7-dihydro-oxazolo[3,2-<i>a</i>][1,3,5]triazinylium; chloride
    —— 1-((6-chloro-1,3-benzodioxol-5-yl) methyl)-2-(alpha-hydroxy-(phenylmethyl))-4-((4-methoxyphenyl)thio)-1H-imidazole-5-carboxaldehyde 177845-46-4 C26H21ClN2O5S
    1-((6-chloro-1,3-benzodioxol-5-yl) methyl)-2-(alpha-hydroxy-(phenylmethyl))-4-((4-methoxyphenyl)thio)-1H-imidazole-5-carboxaldehyde
    —— (6-phenyl-1,4-dithia-spiro[4.5]dec-6-yl)-acetic acid 34219-59-5 C16H20O2S2
    (6-phenyl-1,4-dithia-spiro[4.5]dec-6-yl)-acetic acid
    —— 2-Isobutyl-2,3-dimethyl-3-phenyl-[1,3]thiaphosphinan-3-ium; iodide 51329-26-1 C16H26PS*I
    2-Isobutyl-2,3-dimethyl-3-phenyl-[1,3]thiaphosphinan-3-ium; iodide
    —— N-(3-Chloro-4-phenylsulfanyl-phenyl)-propionamide 32631-33-7 C15H14ClNOS
    N-(3-Chloro-4-phenylsulfanyl-phenyl)-propionamide
    —— 3-(2,2-Dimethyl-propyl)-cyclopropene 39647-70-6 C8H14
    3-(2,2-Dimethyl-propyl)-cyclopropene
    —— 35800-70-5 C9H18N2O2S2
    —— (2R)-2-[[6-amino-2-[[(3-chlorophenyl)methyl]thio]-4-pyrimidinyl]amino]-1-propanol 354582-95-9 C14H17ClN4OS
    (2R)-2-[[6-amino-2-[[(3-chlorophenyl)methyl]thio]-4-pyrimidinyl]amino]-1-propanol
    —— 4-chloro-5-thiophen-2-ylmethylsulfanyl-2<i>H</i>-pyridazin-3-one 5569-00-6 C9H7ClN2OS2
    4-chloro-5-thiophen-2-ylmethylsulfanyl-2<i>H</i>-pyridazin-3-one
    —— N-Phenyl-thiol-oxalimidsaeure-nitril-o-tolylester 22198-00-1 C15H12N2S
    N-Phenyl-thiol-oxalimidsaeure-nitril-o-tolylester
    —— 4-Mercapto-5-benzylthio-3-pyridazinon 21130-97-2 C11H10N2OS2
    4-Mercapto-5-benzylthio-3-pyridazinon
    —— 4-methyl-5-thiocyanato-2-<i>p</i>-tolylsulfanyl-thiazole 35534-82-8 C12H10N2S3
    4-methyl-5-thiocyanato-2-<i>p</i>-tolylsulfanyl-thiazole
    —— 2-Ethylthio-5-fluor-pyrimidin-6-carboxaldehyd 17011-84-6 C7H7FN2O2S
    2-Ethylthio-5-fluor-pyrimidin-6-carboxaldehyd
    —— Diphenyl-{2-[4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenylsulfanyl]-ethyl}-phosphane 798548-40-0 C26H30BO2PS
    Diphenyl-{2-[4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenylsulfanyl]-ethyl}-phosphane
    —— 1-(2,6-diisopropylphenyl)-3-[4-(pyridine-2-ylsulfanyl)-phenyl]-urea 1155798-83-6 C24H27N3OS
    1-(2,6-diisopropylphenyl)-3-[4-(pyridine-2-ylsulfanyl)-phenyl]-urea
    —— thiophosphoric acid <i>O</i>,<i>O</i>'-diethyl ester <i>S</i>-(5-ethylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-ylmethyl) ester 94504-01-5 C9H17N2O4PS3
    thiophosphoric acid <i>O</i>,<i>O</i>'-diethyl ester <i>S</i>-(5-ethylsulfanyl-2-oxo-[1,3,4]thiadiazol-3-ylmethyl) ester
    —— 2-Brompropyl-sulfenylchlorid 857193-48-7 C3H6BrClS
    2-Brompropyl-sulfenylchlorid
    —— [2-Methyl-1-morpholin-4-yl-prop-(E)-ylidene]-((1S,2S)-2-phenylsulfanyl-cyclohexyl)-amine 93740-74-0 C20H30N2OS
    [2-Methyl-1-morpholin-4-yl-prop-(E)-ylidene]-((1S,2S)-2-phenylsulfanyl-cyclohexyl)-amine
    —— 5,5-bis(phenylthio)-1-hexene 161145-63-7 C18H20S2
    5,5-bis(phenylthio)-1-hexene
    —— Methyltrimethylsilyldithioacetate 118657-36-6 C6H14S2Si
    Methyltrimethylsilyldithioacetate
    —— 2,7(6):3,6(7)-Bis[2-thioxo-1,3-dithiole-4,5-diylbisthiobis(ethane-1,2-diyl)dioxybis(ethane-1,2-diyl)dioxybis(ethane-1,2-diyl)bisthio]tetrathiafulvalene 205654-69-9 C36H48O8S18
    2,7(6):3,6(7)-Bis[2-thioxo-1,3-dithiole-4,5-diylbisthiobis(ethane-1,2-diyl)dioxybis(ethane-1,2-diyl)dioxybis(ethane-1,2-diyl)bisthio]tetrathiafulvalene
    —— (2Z,8E)-(5S,7S)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-9-(4-chloro-phenylsulfanyl)-3-phenylselanyl-nona-2,8-dienoic acid ethyl ester 138325-25-4 C35H53ClO4SSeSi2
    (2Z,8E)-(5S,7S)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-9-(4-chloro-phenylsulfanyl)-3-phenylselanyl-nona-2,8-dienoic acid ethyl ester
    —— but-2-yne;N,N-dimethylcarbamodithioate;niobium(3+) 205488-27-3 C13H24N3NbS6
    but-2-yne;N,N-dimethylcarbamodithioate;niobium(3+)
    —— 2-(2-Phenylmercapto-aethylamino)-aethanthiol 695806-12-3 C10H15NS2
    2-(2-Phenylmercapto-aethylamino)-aethanthiol
    —— N,N-diethylcarbamodithioate;hex-3-yne;niobium(3+) 205488-40-0 C21H40N3NbS6
    N,N-diethylcarbamodithioate;hex-3-yne;niobium(3+)
    —— <i>cis</i>-1-ethanesulfonyl-2-(nonane-1-sulfonyl)-ethene 30651-86-6 C13H26O4S2
    <i>cis</i>-1-ethanesulfonyl-2-(nonane-1-sulfonyl)-ethene
    —— N-Ethyl-thiopropionimidic acid methyl ester 39157-50-1 C6H13NS
    N-Ethyl-thiopropionimidic acid methyl ester
    —— {6-fluoro-2-methyl-3-[4-(pyrrolidine-1-carbonyl)phenylsulfanyl]indolizin-1-yl}acetic acid 1036713-48-0 C22H21FN2O3S
    {6-fluoro-2-methyl-3-[4-(pyrrolidine-1-carbonyl)phenylsulfanyl]indolizin-1-yl}acetic acid
    —— 2-Butyl-2-dimethylamino-dithiolan-1,3 22260-62-4 C9H19NS2
    2-Butyl-2-dimethylamino-dithiolan-1,3
    —— 2-Ethyl-3-n-propyl-2-thiacyclobuten-1.1-dioxid 33527-45-6 C8H14O2S
    2-Ethyl-3-n-propyl-2-thiacyclobuten-1.1-dioxid
    —— 2-(1-benzyl-but-2-ynylsulfanyl)-4,5-dihydro-thiazole 37125-78-3 C14H15NS2
    2-(1-benzyl-but-2-ynylsulfanyl)-4,5-dihydro-thiazole
    —— bis(O,O'-dimethyldithiophosphate)platinum(II) 66496-33-1 C4H12O4P2PtS4
    bis(O,O'-dimethyldithiophosphate)platinum(II)
    —— (4E)-5-(3-hydroxyoct-1-en-2-ylsulfinyl)undeca-1,4-dien-6-ol 77132-07-1 C19H34O3S
    (4E)-5-(3-hydroxyoct-1-en-2-ylsulfinyl)undeca-1,4-dien-6-ol
    —— 1-(p-chlorophenylthio)-1-nitrodecane 1402832-97-6 C16H24ClNO2S
    1-(p-chlorophenylthio)-1-nitrodecane
    —— 5,5-difluoro-3-iodo-5-phenylsulfanylpentanenitrile 1016166-37-2 C11H10F2INS
    5,5-difluoro-3-iodo-5-phenylsulfanylpentanenitrile
    —— 3-(bromomethyl)-2-cyclopropyl-6-fluoro-4,7-bis((4-isopropylphenyl)thio)quinoline 1202383-71-8 C31H31BrFNS2
    3-(bromomethyl)-2-cyclopropyl-6-fluoro-4,7-bis((4-isopropylphenyl)thio)quinoline
    —— ((2-cyclopropyl-6-fluoro-4,7-bis((3-methoxyphenyl)thio)quinolin-3-yl)methyl)diphenylphosphine oxide 1202383-51-4 C39H33FNO3PS2
    ((2-cyclopropyl-6-fluoro-4,7-bis((3-methoxyphenyl)thio)quinolin-3-yl)methyl)diphenylphosphine oxide
    —— Benzene, [(2-methoxy-1-phenyl-4-pentenyl)thio]-, (R*,R*)- 129732-84-9 C18H20OS
    Benzene, [(2-methoxy-1-phenyl-4-pentenyl)thio]-, (R*,R*)-
    —— 4-(6-Chloro-thieno[2,3-b]thiochromen-4-ylidene)-1-methyl-piperidine 13125-30-9 C17H16ClNS2
    4-(6-Chloro-thieno[2,3-b]thiochromen-4-ylidene)-1-methyl-piperidine
    —— 2-(O,O-Diethyl-phosphorothiolyl)-4,6-bis(isopropylxanthyl)-s-triazin 10158-80-2 C15H24N3O5PS5
    2-(O,O-Diethyl-phosphorothiolyl)-4,6-bis(isopropylxanthyl)-s-triazin
    —— 2-[[2-bromo-5-[[(3-bromophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol 333743-91-2 C15H14Br2N4OS2
    2-[[2-bromo-5-[[(3-bromophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-(2R)-1-propanol
    —— (R)-3-fluoro-4-{3-[(S)-2-oxo-3-(3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazin-6-yl)-oxazolidin-5-yl]-propylamino}-4,5-dihydro-pyrrolo[3,2,1-de][1,5]naphthyridin-7-one 1220977-57-0 C23H21FN6O4S
    (R)-3-fluoro-4-{3-[(S)-2-oxo-3-(3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazin-6-yl)-oxazolidin-5-yl]-propylamino}-4,5-dihydro-pyrrolo[3,2,1-de][1,5]naphthyridin-7-one
    —— Ethyl-[2-(2-phenylsulfanyl-ethanesulfonyl)-ethyl]-m-tolyl-amine 21814-47-1 C19H25NO2S2
    Ethyl-[2-(2-phenylsulfanyl-ethanesulfonyl)-ethyl]-m-tolyl-amine
    —— (Z)-4-ethyl-5-(phenylthio)-4-decene 661489-20-9 C18H28S
    (Z)-4-ethyl-5-(phenylthio)-4-decene
    —— Dithiocarbonic acid S-methyl ester S-(2-methyl-1-phenethyl-allyl) ester 74940-35-5 C14H18OS2
    Dithiocarbonic acid S-methyl ester S-(2-methyl-1-phenethyl-allyl) ester