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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-amino-3-[2-[2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethoxy]ethylsulfanyl]-1H-1,2,4-triazole-5-thione 273755-99-0 C8H14N8OS4
    4-amino-3-[2-[2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethoxy]ethylsulfanyl]-1H-1,2,4-triazole-5-thione
    —— 1,2-bis[(4-amino-5-mercapto-1,2,4-triazol-3-yl)mercaptomethyl]benzene 760177-52-4 C12H14N8S4
    1,2-bis[(4-amino-5-mercapto-1,2,4-triazol-3-yl)mercaptomethyl]benzene
    —— 1-(4-methylamino-2-methylsulfanyl-pyrimidin-5-yl)-ethanol 686758-79-2 C8H13N3OS
    1-(4-methylamino-2-methylsulfanyl-pyrimidin-5-yl)-ethanol
    —— (34)S-carbon disulfide 63440-46-0 CS2
    (34)S-carbon disulfide
    —— 4-amino-3-[2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethylsulfanyl]-1H-1,2,4-triazole-5-thione 226722-66-3 C6H10N8S4
    4-amino-3-[2-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)sulfanyl]ethylsulfanyl]-1H-1,2,4-triazole-5-thione
    —— 3-methoxy-6-(phenylthio)phenol 1350814-77-5 C13H12O2S
    3-methoxy-6-(phenylthio)phenol
    —— tris(di-n-butyldithiocarbamato)bismuth(III) complex 1000068-54-1 C27H54BiN3S6
    tris(di-n-butyldithiocarbamato)bismuth(III) complex
    —— 2-[3-chloro-2-(methylsulfanyl)phenyl]-1,3-dioxolane 1379324-65-8 C10H11ClO2S
    2-[3-chloro-2-(methylsulfanyl)phenyl]-1,3-dioxolane
    —— ((S)-2-p-Tolylsulfanyl-1-trimethylsilanyloxy-cyclohex-2-enyl)-acetic acid ethyl ester 220033-75-0 C20H30O3SSi
    ((S)-2-p-Tolylsulfanyl-1-trimethylsilanyloxy-cyclohex-2-enyl)-acetic acid ethyl ester
    —— 3-(phenylthio)-2-sulfolene 20583-25-9 C10H10O2S2
    3-(phenylthio)-2-sulfolene
    —— 2-(5-Hexenyl)-4-(phenylthio)-3-sulfolene 124243-69-2 C16H20O2S2
    2-(5-Hexenyl)-4-(phenylthio)-3-sulfolene
    —— ethyl hexen-5-yl sulfide 75199-72-3 C8H16S
    ethyl hexen-5-yl sulfide
    —— 2-Methyl-2-(5-hexenyl)-4-(phenylthio)-3-sulfolene 124243-71-6 C17H22O2S2
    2-Methyl-2-(5-hexenyl)-4-(phenylthio)-3-sulfolene
    —— (S)-2-hydroxy-(S)-3-phenylthiobutyric acid n-butyl ester 928122-08-1 C14H20O3S
    (S)-2-hydroxy-(S)-3-phenylthiobutyric acid n-butyl ester
    —— 1-Methyl-3-phenyl-2-oxa-6,10-dithiaspiro[4.5]decan-1-ol 188439-39-6 C14H18O2S2
    1-Methyl-3-phenyl-2-oxa-6,10-dithiaspiro[4.5]decan-1-ol
    —— Benzene, 1-fluoro-4-(hexylthio)- 61671-37-2 C12H17FS
    Benzene, 1-fluoro-4-(hexylthio)-
    —— Benzene, 1-fluoro-4-(nonylthio)- 61762-55-8 C15H23FS
    Benzene, 1-fluoro-4-(nonylthio)-
    —— (2-Ethyl-4-hydroxyphenyl) thiocyanate 6291-20-9 C9H9NOS
    (2-Ethyl-4-hydroxyphenyl) thiocyanate
    —— di(2-ethyl-4-hydroxyphenyl)sulphide 59376-90-8 C16H18O2S
    di(2-ethyl-4-hydroxyphenyl)sulphide
    —— Octan-2-yl thiohypochlorite 130900-99-1 C8H17ClS
    Octan-2-yl thiohypochlorite
    —— 4-[(4-chloro-phenylsulfanyl)-methanesulfonyl]-morpholine 55116-66-0 C11H14ClNO3S2
    4-[(4-chloro-phenylsulfanyl)-methanesulfonyl]-morpholine
    —— 2-(3-Chlor-4-fluorphenylthio)phenylessigsaeure 60810-67-5 C14H10ClFO2S
    2-(3-Chlor-4-fluorphenylthio)phenylessigsaeure
    —— ethyl 3-(4-methylamino-2-methanesulfanyl-pyrimidin-5-yl)acrylate 211244-86-9 C11H15N3O2S
    ethyl 3-(4-methylamino-2-methanesulfanyl-pyrimidin-5-yl)acrylate
    —— 2-phenylthio-1-phenylhept-1-ene 107014-82-4 C19H22S
    2-phenylthio-1-phenylhept-1-ene
    —— 5-ethyl-4-hydroxy-2-prop-2-enylsulfanyl-1H-pyrimidin-6-one 510717-74-5 C9H12N2O2S
    5-ethyl-4-hydroxy-2-prop-2-enylsulfanyl-1H-pyrimidin-6-one
    —— (2,4,5-Trichloro-phenylsulfanyl)-methanesulfonamide 55116-63-7 C7H6Cl3NO2S2
    (2,4,5-Trichloro-phenylsulfanyl)-methanesulfonamide
    —— tert-butyl [1-amino-3-(methylsulfonyl)propan-2-yl]carbamate 1429913-59-6 C9H20N2O4S
    tert-butyl [1-amino-3-(methylsulfonyl)propan-2-yl]carbamate
    —— 2-(2-cyclopentylsulfanyl-5-ethyl-6-oxo-1H-pyrimidin-4-yl)-2-phenylacetonitrile 936568-84-2 C19H21N3OS
    2-(2-cyclopentylsulfanyl-5-ethyl-6-oxo-1H-pyrimidin-4-yl)-2-phenylacetonitrile
    —— N-(2-Cyanoethyl)-N-propan-2-ylthiourea 59670-01-8 C7H13N3S
    N-(2-Cyanoethyl)-N-propan-2-ylthiourea
    —— 5-ethyl-2-ethylsulfanyl-4-hydroxy-1H-pyrimidin-6-one 1026930-95-9 C8H12N2O2S
    5-ethyl-2-ethylsulfanyl-4-hydroxy-1H-pyrimidin-6-one
    —— 2-cyclopentylsulfanyl-5-ethyl-4-hydroxy-1H-pyrimidin-6-one 1027309-66-5 C11H16N2O2S
    2-cyclopentylsulfanyl-5-ethyl-4-hydroxy-1H-pyrimidin-6-one
    —— 2-benzylsulfanyl-5-ethyl-4-hydroxy-1H-pyrimidin-6-one 1005310-51-9 C13H14N2O2S
    2-benzylsulfanyl-5-ethyl-4-hydroxy-1H-pyrimidin-6-one
    —— 5-ethyl-4-hydroxy-2-propan-2-ylsulfanyl-1H-pyrimidin-6-one 1027524-46-4 C9H14N2O2S
    5-ethyl-4-hydroxy-2-propan-2-ylsulfanyl-1H-pyrimidin-6-one
    —— 4-phenylsulfanylmethanesulfonyl-morpholine 55116-65-9 C11H15NO3S2
    4-phenylsulfanylmethanesulfonyl-morpholine
    —— 3-bromo-4-(phenylthio)phenol 1350814-75-3 C12H9BrOS
    3-bromo-4-(phenylthio)phenol
    —— 2-methylsulfanyl-thiobenzoic acid amide 52369-06-9 C8H9NS2
    2-methylsulfanyl-thiobenzoic acid amide
    —— [(4S,5S)-2-(2-methylsulfanylphenyl)-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methanol 160246-26-4 C17H17NO2S
    [(4S,5S)-2-(2-methylsulfanylphenyl)-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methanol
    —— [(4S,5S)-2-(2-methylsulfanylphenyl)-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methyl prop-2-enoate 197291-57-9 C20H19NO3S
    [(4S,5S)-2-(2-methylsulfanylphenyl)-5-phenyl-4,5-dihydro-1,3-oxazol-4-yl]methyl prop-2-enoate
    —— (4S)-4-Isopropyl-2-<2-(methylsulfanyl)phenyl>-4,5-dihydro-1,3-oxazole 154132-42-0 C13H17NOS
    (4S)-4-Isopropyl-2-<2-(methylsulfanyl)phenyl>-4,5-dihydro-1,3-oxazole
    —— 3-chloro-2-fluoro-5-(3-methylphenyl)thiopyridine 344781-89-1 C12H9ClFNS
    3-chloro-2-fluoro-5-(3-methylphenyl)thiopyridine
    —— 2-(3,4-Dichlorphenylthio)benzylalkohol 50900-36-2 C13H10Cl2OS
    2-(3,4-Dichlorphenylthio)benzylalkohol
    —— 3-chloro-5-(propylthio)pyridine 89265-37-2 C8H10ClNS
    3-chloro-5-(propylthio)pyridine
    —— (p-Tolylthio)-methansulfonamid 51619-94-4 C8H11NO2S2
    (p-Tolylthio)-methansulfonamid
    —— 2-(4-Chlor-3-fluorphenylthio)benzylalkohol 60810-60-8 C13H10ClFOS
    2-(4-Chlor-3-fluorphenylthio)benzylalkohol
    —— 2-amino-6-(4-methoxyphenylthio)-9-{2-[bis(ethyloxycarbonyloxymethoxy)phosphonomethoxy]-ethyl}-purine 1309973-12-3 C23H30N5O11PS
    2-amino-6-(4-methoxyphenylthio)-9-{2-[bis(ethyloxycarbonyloxymethoxy)phosphonomethoxy]-ethyl}-purine
    —— 2-(4-Chlor-3-fluorphenylthio)phenylessigsaeure 60810-66-4 C14H10ClFO2S
    2-(4-Chlor-3-fluorphenylthio)phenylessigsaeure
    —— 1-benzyl-2-methylthiopyrimidin-4-one 81560-05-6 C12H12N2OS
    1-benzyl-2-methylthiopyrimidin-4-one
    —— 4-(N,N'-bis(4-bromophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione 116088-25-6 C17H16Br2N6S2
    4-(N,N'-bis(4-bromophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione
    —— 2-benzo[1,3]dithiol-2-yl-cyclohexane-1,3-dione 59376-01-1 C13H12O2S2
    2-benzo[1,3]dithiol-2-yl-cyclohexane-1,3-dione
    —— (Z)-7-phenylsulfanyldodec-7-en-6-ol —— C8H9N2O2Pol
    (Z)-7-phenylsulfanyldodec-7-en-6-ol