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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Ethyl 1-(2-methoxyethyl)-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate 226397-50-8 C23H29NO5S2
    Ethyl 1-(2-methoxyethyl)-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate
    —— Ethyl 1-ethyl-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate 869063-74-1 C22H27NO4S2
    Ethyl 1-ethyl-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate
    —— α-(Methylsulfinyl)-acetamide 81442-38-8 C3H7NO2S
    α-(Methylsulfinyl)-acetamide
    —— ethyl 4-chloro-4-(4-chlorophenylthio)butanoate 146564-01-4 C12H14Cl2O2S
    ethyl 4-chloro-4-(4-chlorophenylthio)butanoate
    —— Ethyl 1-methyl-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate 226397-44-0 C21H25NO4S2
    Ethyl 1-methyl-4-(4-phenylsulfanylphenyl)sulfonylpiperidine-4-carboxylate
    —— 3-methylsulfanyl-aniline; hydrochloride 94855-95-5 C7H9NS*ClH
    3-methylsulfanyl-aniline; hydrochloride
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-[4-(2-hydroxy-ethyl)-piperazin-1-yl]-ethyl ester 37071-64-0 C23H29N3O3S
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-[4-(2-hydroxy-ethyl)-piperazin-1-yl]-ethyl ester
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbonyl chloride 37075-14-2 C15H12ClNOS
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbonyl chloride
    —— 4-[4-(tert-Butyl-dimethyl-silanyloxy)-butoxy]-5-methyl-2-methylsulfanyl-pyrimidine 190070-00-9 C16H30N2O2SSi
    4-[4-(tert-Butyl-dimethyl-silanyloxy)-butoxy]-5-methyl-2-methylsulfanyl-pyrimidine
    —— 3-[4-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one 190069-98-8 C16H30N2O2SSi
    3-[4-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5-methyl-2-methylsulfanyl-3H-pyrimidin-4-one
    —— 2-phenylsulfanyl-ethanesulfonic acid amide 96852-83-4 C8H11NO2S2
    2-phenylsulfanyl-ethanesulfonic acid amide
    —— (S)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 507480-44-6 C21H34O3SSi
    (S)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-butyl]-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one
    —— (R,S)-(E)-4(4H)-[(2,3-epoxypropyl)oxyimino]-7-methyl-2,3-dihydrothiopyrano[2,3-b]pyridine 309728-79-8 C12H14N2O2S
    (R,S)-(E)-4(4H)-[(2,3-epoxypropyl)oxyimino]-7-methyl-2,3-dihydrothiopyrano[2,3-b]pyridine
    —— 8-phenylthio-1,4-dioxaspiro[4,5]decane 124941-13-5 C14H18O2S
    8-phenylthio-1,4-dioxaspiro[4,5]decane
    —— (E)-4(4H)-hydroxyimino-7-methyl-2,3-dihydrothiopyrano[2,3-b]pyridine 309728-78-7 C9H10N2OS
    (E)-4(4H)-hydroxyimino-7-methyl-2,3-dihydrothiopyrano[2,3-b]pyridine
    —— 3-(6-Methyl-pyridin-2-ylsulfanyl)-propionic acid ethyl ester 309728-92-5 C11H15NO2S
    3-(6-Methyl-pyridin-2-ylsulfanyl)-propionic acid ethyl ester
    —— dimethyl-3,3 isothiocyanato-2 butene-1 97040-52-3 C7H11NS
    dimethyl-3,3 isothiocyanato-2 butene-1
    —— 2-(Benzylsulfanyl)-3-(hydroxymethyl)-1-phenylpyridin-1-ium bromide 77155-90-9 C19H18BrNOS
    2-(Benzylsulfanyl)-3-(hydroxymethyl)-1-phenylpyridin-1-ium bromide
    —— 2-[2-(1H-Imidazol-4-yl)-ethylsulfanyl]-1-methyl-pyridinium; chloride 87577-76-2 C11H14N3S*Cl
    2-[2-(1H-Imidazol-4-yl)-ethylsulfanyl]-1-methyl-pyridinium; chloride
    —— 3-chloro-5,5-dimethyl-2-cyclohexene-1-thione 73705-07-4 C8H11ClS
    3-chloro-5,5-dimethyl-2-cyclohexene-1-thione
    —— 3-Methoxy-5,5-dimethyl-2-cyclohexene-1-thione 70134-09-7 C9H14OS
    3-Methoxy-5,5-dimethyl-2-cyclohexene-1-thione
    —— 2-(4-chloropyridin-2-yl)-5-methylthio-1,3,4-thiadiazole 1192456-32-8 C8H6ClN3S2
    2-(4-chloropyridin-2-yl)-5-methylthio-1,3,4-thiadiazole
    —— trispiro<tris(3'-cyano-5',5'-dimethyl-2'-cyclohexene)-1',2;1',4;1',6-(1,3,5-trithiane)> 79515-88-1 C27H33N3S3
    trispiro<tris(3'-cyano-5',5'-dimethyl-2'-cyclohexene)-1',2;1',4;1',6-(1,3,5-trithiane)>
    —— 2-{2-[(4-Chlorophenyl)sulfanyl]ethyl}pyridine--hydrogen chloride (1/1) 87577-95-5 C13H13Cl2NS
    2-{2-[(4-Chlorophenyl)sulfanyl]ethyl}pyridine--hydrogen chloride (1/1)
    —— 1,4-diisothiocyanatobut-2-yne 296801-41-7 C6H4N2S2
    1,4-diisothiocyanatobut-2-yne
    —— 2,4,6-trichloro-5-ethylthio-pyrimidine 70958-40-6 C6H5Cl3N2S
    2,4,6-trichloro-5-ethylthio-pyrimidine
    —— dithiocarbonic acid <i>S</i>-ethyl ester-<i>O</i>-butyl ester 59864-58-3 C7H14OS2
    dithiocarbonic acid <i>S</i>-ethyl ester-<i>O</i>-butyl ester
    —— (E)-3-phenylthio-2-methylpropen-1-al 382150-12-1 C10H10OS
    (E)-3-phenylthio-2-methylpropen-1-al
    —— 1-[4-(Dimethylamino)pyridin-1-ium-1-yl]-3-phenylsulfanylpropan-2-ol;perchlorate 94821-48-4 C16H21N2OS*ClO4
    1-[4-(Dimethylamino)pyridin-1-ium-1-yl]-3-phenylsulfanylpropan-2-ol;perchlorate
    —— 4-Chloro-5-(methylsulfanyl)-2,6-bis[(propan-2-yl)oxy]pyrimidine 96104-38-0 C11H17ClN2O2S
    4-Chloro-5-(methylsulfanyl)-2,6-bis[(propan-2-yl)oxy]pyrimidine
    —— 1-Methyl-2-{[(5-methyl-1H-imidazol-4-yl)methyl]sulfanyl}-1H-imidazole 77148-56-2 C9H12N4S
    1-Methyl-2-{[(5-methyl-1H-imidazol-4-yl)methyl]sulfanyl}-1H-imidazole
    —— 2-Benzylthio-3-(diethoxy)methyl-1-phenylpyridinium chloride 77148-80-2 C23H26NO2S*Cl
    2-Benzylthio-3-(diethoxy)methyl-1-phenylpyridinium chloride
    —— Cmvitxbjhdsakr-uhfffaoysa- 342883-66-3 C6H7NS
    Cmvitxbjhdsakr-uhfffaoysa-
    —— methyl xanthate, anion 47997-58-0 C2H3OS2
    methyl xanthate, anion
    —— ethyl [(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)thio]acetate 131537-32-1 C11H11N3O3S
    ethyl [(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)thio]acetate
    —— 2-{[(1H-Imidazol-5-yl)methyl]sulfanyl}-1H-imidazole 87577-98-8 C7H8N4S
    2-{[(1H-Imidazol-5-yl)methyl]sulfanyl}-1H-imidazole
    —— 1-cyclopentyl-4,5-dihydro-3-ethyl-7-methylthio-1H-pyrazolo[3,4-c]pyridine 185954-44-3 C14H21N3S
    1-cyclopentyl-4,5-dihydro-3-ethyl-7-methylthio-1H-pyrazolo[3,4-c]pyridine
    —— 3-isothiocyanatooct-4-yne 17620-81-4 C9H13NS
    3-isothiocyanatooct-4-yne
    —— 4-[(3-Chlorophenyl)methylsulfanyl]pyridine;hydrochloride 77148-90-4 C12H11Cl2NS
    4-[(3-Chlorophenyl)methylsulfanyl]pyridine;hydrochloride
    —— 2-methylsulfanyl-5-(tetrazol-5-yl)-1,3,4-thiadiazole 325732-47-6 C4H4N6S2
    2-methylsulfanyl-5-(tetrazol-5-yl)-1,3,4-thiadiazole
    —— 1-Methyl-2-[(1-methylpyridin-1-ium-2-yl)sulfanylmethylsulfanyl]pyridin-1-ium;diiodide 77037-67-3 C13H16I2N2S2
    1-Methyl-2-[(1-methylpyridin-1-ium-2-yl)sulfanylmethylsulfanyl]pyridin-1-ium;diiodide
    —— 4-{[(1H-Imidazol-5-yl)methyl]sulfanyl}-1-methylpyridin-1-ium chloride 87577-97-7 C10H12ClN3S
    4-{[(1H-Imidazol-5-yl)methyl]sulfanyl}-1-methylpyridin-1-ium chloride
    —— 4-(allylthio)aniline 19284-79-8 C9H11NS
    4-(allylthio)aniline
    —— 4-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}pyridine 77148-59-5 C10H11N3S
    4-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}pyridine
    —— N-(2-p-Tolylthioethyl)anilin 42330-82-5 C15H17NS
    N-(2-p-Tolylthioethyl)anilin
    —— 6-Pyridin-3-yl-2,3-dihydro-imidazo[2,1-b]thiazole 96911-31-8 C10H9N3S
    6-Pyridin-3-yl-2,3-dihydro-imidazo[2,1-b]thiazole
    —— Octyl 2,3,5-trichlorophenyl sulfide 89165-38-8 C14H19Cl3S
    Octyl 2,3,5-trichlorophenyl sulfide
    —— 3-ethoxycarbonyl-6-phenyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine 127045-31-2 C13H12N4O2S
    3-ethoxycarbonyl-6-phenyl-5H-1,2,3-triazolo<5,1-b><1,3,4>thiadiazine
    —— 1,3-Diphenyl-2-<2-chlor-phenyl>-isothioharnstoff 13659-07-9 C19H15ClN2S
    1,3-Diphenyl-2-<2-chlor-phenyl>-isothioharnstoff
    —— 2,4-dibromo-1,3-dithietane 1,1,3,3-tetraoxide 98181-91-0 C2H2Br2O4S2
    2,4-dibromo-1,3-dithietane 1,1,3,3-tetraoxide