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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-amino-3-ethoxycarbonylsulfanyl-6-methyl-4<i>H</i>-[1,2,4]triazin-5-one 24272-69-3 C7H10N4O3S
    4-amino-3-ethoxycarbonylsulfanyl-6-methyl-4<i>H</i>-[1,2,4]triazin-5-one
    —— 7-methyl-2,4-dioxo-1,2,3,4,5,8-hexahydro-pyrido[2,3-<i>d</i>]pyrimidine-6-carbonitrile 38346-01-9 C9H8N4O2
    7-methyl-2,4-dioxo-1,2,3,4,5,8-hexahydro-pyrido[2,3-<i>d</i>]pyrimidine-6-carbonitrile
    —— cis-1-Ethylsulfonyl-2-ethylthioethen 30647-70-2 C6H12O2S2
    cis-1-Ethylsulfonyl-2-ethylthioethen
    —— Dimethylester der 2,6-Bis-aethylendithiobicyclo<3.3.1>-nonan-3,7-dicarbonsaeure 26280-71-7 C17H24O4S4
    Dimethylester der 2,6-Bis-aethylendithiobicyclo<3.3.1>-nonan-3,7-dicarbonsaeure
    —— 11-Oxa-8,14-dithia-tricyclo[13.4.0.0<sup>2,7</sup>]nonadeca-1(15),2(7),3,5,16,18-hexaene 34226-74-9 C16H16OS2
    11-Oxa-8,14-dithia-tricyclo[13.4.0.0<sup>2,7</sup>]nonadeca-1(15),2(7),3,5,16,18-hexaene
    —— 1-Methylene-4-methylsulfanylmethylene-cyclohexane 36784-77-7 C9H14S
    1-Methylene-4-methylsulfanylmethylene-cyclohexane
    —— 3,5-Bis-[1-(4-methylsulfanyl-phenyl)-meth-(Z)-ylidene]-tetrahydro-thiopyran-4-one 83319-94-2 C21H20OS3
    3,5-Bis-[1-(4-methylsulfanyl-phenyl)-meth-(Z)-ylidene]-tetrahydro-thiopyran-4-one
    —— 3-[(4-chlorophenyl)thio]-5-iodo-1H-indazole 854018-70-5 C13H8ClIN2S
    3-[(4-chlorophenyl)thio]-5-iodo-1H-indazole
    —— O-ethyl S-(2,3,5,6-tetrafluorophenyl) carbonothioate 1567383-00-9 C9H6F4O2S
    O-ethyl S-(2,3,5,6-tetrafluorophenyl) carbonothioate
    —— <1-(phenylthio)ethylidene>-1-(trimethylsilyl)methylamine 103852-58-0 C12H19NSSi
    <1-(phenylthio)ethylidene>-1-(trimethylsilyl)methylamine
    —— 2-Chlor-aethyl-trithiochlorid 91571-74-3 C2H4Cl2S3
    2-Chlor-aethyl-trithiochlorid
    —— diethyl (p-chlorophenylthio)malonate 39133-62-5 C13H15ClO4S
    diethyl (p-chlorophenylthio)malonate
    —— (2-Nitro-5-(phenylthio)phenyl)bis(phenylthio)methane 93304-91-7 C25H19NO2S3
    (2-Nitro-5-(phenylthio)phenyl)bis(phenylthio)methane
    —— N-cyclohexylsulfinylamineglyoxaldicyclohexyliminenickel(0) 156882-15-4 C20H35N3NiOS
    N-cyclohexylsulfinylamineglyoxaldicyclohexyliminenickel(0)
    —— (E)-1-methyl-2-(2-(p-tolylthio)ethylidene)hydrazine-1-carboximidamide sulfate 105202-66-2 2C11H16N4S*H2O4S
    (E)-1-methyl-2-(2-(p-tolylthio)ethylidene)hydrazine-1-carboximidamide sulfate
    —— 3-dimethylcarbamoyloxy-1-methyl-5-propylsulfanyl-1<i>H</i>-[1,2,4]triazole 55150-85-1 C9H16N4O2S
    3-dimethylcarbamoyloxy-1-methyl-5-propylsulfanyl-1<i>H</i>-[1,2,4]triazole
    —— 2-Chlor-1.3-bis-ethylmercapto-butan 90224-53-6 C8H17ClS2
    2-Chlor-1.3-bis-ethylmercapto-butan
    —— Dimethyl-thiocarbamic acid S-[4-(1-propyl-nonyl)-phenyl] ester 29688-09-3 C21H35NOS
    Dimethyl-thiocarbamic acid S-[4-(1-propyl-nonyl)-phenyl] ester
    —— Dithiophosphoric acid S-[2,2-bis-(4-chloro-phenylsulfanyl)-ethyl] ester O,O'-diethyl ester 88784-26-3 C18H21Cl2O2PS4
    Dithiophosphoric acid S-[2,2-bis-(4-chloro-phenylsulfanyl)-ethyl] ester O,O'-diethyl ester
    —— 6-(4-Chlorphenylthio)-5-chlor-1,2,3-benzothiadiazol 23620-82-8 C12H6Cl2N2S2
    6-(4-Chlorphenylthio)-5-chlor-1,2,3-benzothiadiazol
    —— 2-amino-5-(2,4,5-trichloro-phenylsulfanyl)-3<i>H</i>-pyrimidin-4-one 90877-07-9 C10H6Cl3N3OS
    2-amino-5-(2,4,5-trichloro-phenylsulfanyl)-3<i>H</i>-pyrimidin-4-one
    —— 20429-51-0 C21H18N2S3Sn
    —— 2,3-bis(phenylthio)aniline 131195-88-5 C18H15NS2
    2,3-bis(phenylthio)aniline
    —— 6-[2-(4-Amino-phenyl)-ethyl]-3-(2-tert-butyl-5-methyl-thiophen-3-ylsulfanyl)-4-hydroxy-6-isopropyl-5,6-dihydro-pyran-2-one 261707-39-5 C25H33NO3S2
    6-[2-(4-Amino-phenyl)-ethyl]-3-(2-tert-butyl-5-methyl-thiophen-3-ylsulfanyl)-4-hydroxy-6-isopropyl-5,6-dihydro-pyran-2-one
    —— 1-Methylthio-4-phenylbuta-1,2-dien 31487-27-1 C11H12S
    1-Methylthio-4-phenylbuta-1,2-dien
    —— (Z)-N-(2-Ethoxycarbonylvinyl)dimethylsulfoximin 72760-44-2 C7H13NO3S
    (Z)-N-(2-Ethoxycarbonylvinyl)dimethylsulfoximin
    —— 6-(D-Gluco-1,2,3,4,5-pentahydroxy-pentyl)-2-methyl-3-methylmercapto-2,5-dihydro-1,2,4-triazinon-(5) 1195558-83-8 C10H17N3O6S
    6-(D-Gluco-1,2,3,4,5-pentahydroxy-pentyl)-2-methyl-3-methylmercapto-2,5-dihydro-1,2,4-triazinon-(5)
    —— Thio-tetradecansaeure-ethylthioester 27249-84-9 C16H32S2
    Thio-tetradecansaeure-ethylthioester
    —— 5-benzylsulfanyl-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester 32884-64-3 C16H19NO2S
    5-benzylsulfanyl-2,4-dimethyl-pyrrole-3-carboxylic acid ethyl ester
    —— 2-Methylmercapto-5-(2,5-dichlor-phenylmercapto)-pyrimidin-4-carbonsaeure 25818-47-7 C12H8Cl2N2O2S2
    2-Methylmercapto-5-(2,5-dichlor-phenylmercapto)-pyrimidin-4-carbonsaeure
    —— 2-(4-chloro-phenylsulfanyl)-4-methyl-5-thiocyanato-thiazole 35534-83-9 C11H7ClN2S3
    2-(4-chloro-phenylsulfanyl)-4-methyl-5-thiocyanato-thiazole
    —— 4,4-Dimethyl-2-thioacetyl-pentanal 99679-66-0 C9H16OS
    4,4-Dimethyl-2-thioacetyl-pentanal
    —— 2-((4-chlorophenyl)thio)benzo[d]oxazole 122899-26-7 C13H8ClNOS
    2-((4-chlorophenyl)thio)benzo[d]oxazole
    —— (S)-1-(2-(methoxymethyl)pyrrolidin-1-yl)-3-(4-((4-((5-methyl-1H-pyrazol-3-yl)amino)pyrrolo[2,1-f][1,2,4]triazin-2-yl)thio)phenyl)urea 1315588-42-1 C23H27N9O2S
    (S)-1-(2-(methoxymethyl)pyrrolidin-1-yl)-3-(4-((4-((5-methyl-1H-pyrazol-3-yl)amino)pyrrolo[2,1-f][1,2,4]triazin-2-yl)thio)phenyl)urea
    —— 4-Methyl-5-thioxo-hexan-3-one 99679-67-1 C7H12OS
    4-Methyl-5-thioxo-hexan-3-one
    —— (pyridin-2-ylthio)(tricyclohexyl-l5-phosphaneyl)gold 147998-59-2 C23H37AuNPS
    (pyridin-2-ylthio)(tricyclohexyl-l5-phosphaneyl)gold
    —— dimethyl 2-(2-((4-chlorophenyl)thio)-2-phenylethyl)malonate 1462945-64-7 C19H19ClO4S
    dimethyl 2-(2-((4-chlorophenyl)thio)-2-phenylethyl)malonate
    —— S-p-tolyl benzylcarbamothioate 51955-56-7 C15H15NOS
    S-p-tolyl benzylcarbamothioate
    —— (Z)-3-bromo-1,1,1-trifluoro-4-p-tolylsulfanyl-but-3-en-2-one 1259374-97-4 C11H8BrF3OS
    (Z)-3-bromo-1,1,1-trifluoro-4-p-tolylsulfanyl-but-3-en-2-one
    —— 74601-31-3 C18H17NO3S
    —— 6-(2-ethyl-5-nitro-1(3)<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine 4526-63-0 C10H9N7O2S
    6-(2-ethyl-5-nitro-1(3)<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine
    —— 4-[(4-methyl-6-oxo-5-propyl-1,6-dihydro-pyrimidin-2-ylsulfanyl)-acetyl]-morpholine 28994-71-0 C14H21N3O3S
    4-[(4-methyl-6-oxo-5-propyl-1,6-dihydro-pyrimidin-2-ylsulfanyl)-acetyl]-morpholine
    —— 4-Hydroxy-2-iso-propylmercapto-6-tert-butylpyrimidin 66698-65-5 C11H18N2OS
    4-Hydroxy-2-iso-propylmercapto-6-tert-butylpyrimidin
    —— 12-(3-piperidin-1-yl-propyl)-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine 6791-98-6 C22H28N2S
    12-(3-piperidin-1-yl-propyl)-11,12-dihydro-6<i>H</i>-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine
    —— tert-Butylsulfanyl-(ethoxy-ethyl-phosphinothioylsulfanyl)-acetic acid ethyl ester 60177-72-2 C12H25O3PS3
    tert-Butylsulfanyl-(ethoxy-ethyl-phosphinothioylsulfanyl)-acetic acid ethyl ester
    —— Aethyl-dithiophosphonsaeure-O-aethyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester 91953-97-8 C13H21OPS4
    Aethyl-dithiophosphonsaeure-O-aethyl-S-<2-(4-methylmercapto-phenylmercapto)-aethyl>-ester
    —— 1-(N-morpholino)-5-(phenylthioetheryl)-2,4-diphenylpentan-3-one 93595-17-6 C27H29NO2S
    1-(N-morpholino)-5-(phenylthioetheryl)-2,4-diphenylpentan-3-one
    —— [1-((Z)-2-Methoxy-1-methyl-vinyl)-nonylsulfanyl]-benzene 119046-81-0 C19H30OS
    [1-((Z)-2-Methoxy-1-methyl-vinyl)-nonylsulfanyl]-benzene
    —— 2-Diazo-1-[(S)-2-((Z)-3-phenylsulfanyl-propenyl)-pyrrolidin-1-yl]-ethanone 182891-46-9 C15H17N3OS
    2-Diazo-1-[(S)-2-((Z)-3-phenylsulfanyl-propenyl)-pyrrolidin-1-yl]-ethanone
    —— [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl] 1332700-21-6 C23H25ClPdS2Si
    [((3,5-bis(phenylthiomethyl)phenyl)trimethylsilane(-H)-C,S,S')PdCl]