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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— n-hexyl 1,2-diethylcyclohexyl sulphoxide 52636-43-8 C16H32OS
    n-hexyl 1,2-diethylcyclohexyl sulphoxide
    —— n-hexyl 1,2-diethylcyclohexyl sulphide 52636-55-2 C16H32S
    n-hexyl 1,2-diethylcyclohexyl sulphide
    —— 4-(4-phenylthio)benzyl-7-oxo-4,7-dihydropyrazolo[1,5-a]pyrimidine 189018-63-1 C19H15N3OS
    4-(4-phenylthio)benzyl-7-oxo-4,7-dihydropyrazolo[1,5-a]pyrimidine
    —— N'-[2,3,4,5-tetrafluoro-6-(propylthio)phenyl]benzamidine 685872-06-4 C16H14F4N2S
    N'-[2,3,4,5-tetrafluoro-6-(propylthio)phenyl]benzamidine
    —— 3,4,5,6-tetrafluoro-2-(propylthio)aniline 685872-15-5 C9H9F4NS
    3,4,5,6-tetrafluoro-2-(propylthio)aniline
    —— (E)-4-hydroxy-3-(phenylthio)pent-3-en-2-one 28195-10-0 C11H12O2S
    (E)-4-hydroxy-3-(phenylthio)pent-3-en-2-one
    —— 2-methyl-6-[3-(phenylthio)prop-1-yn-1-yl]pyridine 851855-84-0 C15H13NS
    2-methyl-6-[3-(phenylthio)prop-1-yn-1-yl]pyridine
    —— N-(1,1-Dimethyl-3-oxobutyl)-2-oxocyclopentan-1-carbothioamid 62242-25-5 C12H19NO2S
    N-(1,1-Dimethyl-3-oxobutyl)-2-oxocyclopentan-1-carbothioamid
    —— tert-butyl (3-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}-1-cyclopropylpropyl)carbamate 958023-87-5 C23H27BrN6O4S
    tert-butyl (3-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-9H-purin-9-yl}-1-cyclopropylpropyl)carbamate
    —— 2-(6-methyl-4-pyrimidinylthio)-cyclohexanone 89991-27-5 C11H14N2OS
    2-(6-methyl-4-pyrimidinylthio)-cyclohexanone
    —— 5-methyl-2-methylthio-6-(2'-pyrazinyl)-4H-1,3-thiazin-4-one 119707-33-4 C10H9N3OS2
    5-methyl-2-methylthio-6-(2'-pyrazinyl)-4H-1,3-thiazin-4-one
    —— (3-cyano-5-nitro-2-pyridyl) N,N-diethylcarbamodithioate 909256-21-9 C11H12N4O2S2
    (3-cyano-5-nitro-2-pyridyl) N,N-diethylcarbamodithioate
    —— 1,1,1-trifluoro-2-[2-(1-phenyl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-thiazol-5-yl]-butan-2-ol 944924-38-3 C23H17F3N4OS2
    1,1,1-trifluoro-2-[2-(1-phenyl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-thiazol-5-yl]-butan-2-ol
    —— (S)-(2,3-dihydroxypropyl) phenyl sulfide 97798-48-6 C9H12O2S
    (S)-(2,3-dihydroxypropyl) phenyl sulfide
    —— tert-butyl (3-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-3H-purin-3-yl}-1-cyclopropylpropyl)carbamate 958023-88-6 C23H27BrN6O4S
    tert-butyl (3-{6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)thio]-3H-purin-3-yl}-1-cyclopropylpropyl)carbamate
    —— N-{3-[6-amino-8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-purin-9-yl]-1-cyclopropyl-propyl}-acetamide 1156466-69-1 C20H21BrN6O3S
    N-{3-[6-amino-8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-purin-9-yl]-1-cyclopropyl-propyl}-acetamide
    —— 5-cyano-4-(N,N-dimethylaminomethyleneamino)-2-methylthiopyrimidine 103970-37-2 C9H11N5S
    5-cyano-4-(N,N-dimethylaminomethyleneamino)-2-methylthiopyrimidine
    —— 4-amino-2-methylthiopyrimidine-5-carboxamide oxime 82302-14-5 C6H9N5OS
    4-amino-2-methylthiopyrimidine-5-carboxamide oxime
    —— N-{3-[6-acetylamino-8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-purin-9-yl]-1-cyclopropyl-propyl}-acetamide 1156466-70-4 C22H23BrN6O4S
    N-{3-[6-acetylamino-8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-purin-9-yl]-1-cyclopropyl-propyl}-acetamide
    —— (1S,2S)-Propylenepisulfoxid 21386-27-6 C3H6OS
    (1S,2S)-Propylenepisulfoxid
    —— Acetic acid, 2,2'-[(1-methylethylidene)bis(sulfonyl)]bis-, dimethyl ester 61713-33-5 C9H16O8S2
    Acetic acid, 2,2'-[(1-methylethylidene)bis(sulfonyl)]bis-, dimethyl ester
    —— 2-<2-(phenylthio)ethyl>-1,3-dioxolane 56161-48-9 C11H14O2S
    2-<2-(phenylthio)ethyl>-1,3-dioxolane
    —— 4-[(4-Hydroxyphenyl)sulfanyl-phenylmethyl]sulfanylphenol 216497-94-8 C19H16O2S2
    4-[(4-Hydroxyphenyl)sulfanyl-phenylmethyl]sulfanylphenol
    —— N,N-diethyl-S-isopropyloxycarbonyl dithiocarbamate 38235-21-1 C9H17NO2S2
    N,N-diethyl-S-isopropyloxycarbonyl dithiocarbamate
    —— (E)-2-<2-(phenylthio)ethenyl>-1,3-dioxolane 105621-12-3 C11H12O2S
    (E)-2-<2-(phenylthio)ethenyl>-1,3-dioxolane
    —— 1,2,2,5,5-pentamethyl-4-(methylthio)-3-imidazoline 23758-02-3 C9H18N2S
    1,2,2,5,5-pentamethyl-4-(methylthio)-3-imidazoline
    —— gallium(III) diethyldithiocarbamate 16037-72-2 C15H30GaN3S6
    gallium(III) diethyldithiocarbamate
    —— 2-(5-Phenylthiocyclopent-1-enyl)but-2-en 64894-33-3 C15H18S
    2-(5-Phenylthiocyclopent-1-enyl)but-2-en
    —— 6,6-Dimethyl-3-methylthio-1-(pyrid-2-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 207306-63-6 C16H17NOS2
    6,6-Dimethyl-3-methylthio-1-(pyrid-2-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— N-(1,1-Dimethyl-3-oxobutyl)-2-oxocyclohexan-1-carbothioamid 62242-24-4 C13H21NO2S
    N-(1,1-Dimethyl-3-oxobutyl)-2-oxocyclohexan-1-carbothioamid
    —— 1-bromo-6,6-dimethyl-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 207307-46-8 C11H13BrOS2
    1-bromo-6,6-dimethyl-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— trimethyl-[(E)-1-phenylsulfanyloct-2-enyl]silane 88410-24-6 C17H28SSi
    trimethyl-[(E)-1-phenylsulfanyloct-2-enyl]silane
    —— 5-(3-bromo-4-fluorophenyl)-3-methylsulfanyl-[1,2,4]triazine 765916-95-8 C10H7BrFN3S
    5-(3-bromo-4-fluorophenyl)-3-methylsulfanyl-[1,2,4]triazine
    —— ethyl 2-[(6-chloro-5-nitropyridin-2-yl)sulfanyl]acetate 1379575-25-3 C9H9ClN2O4S
    ethyl 2-[(6-chloro-5-nitropyridin-2-yl)sulfanyl]acetate
    —— 4-(3-cyanopropylthio)pyridine-3-carbonitrile 346717-58-6 C10H9N3S
    4-(3-cyanopropylthio)pyridine-3-carbonitrile
    —— 2,6-Dimethylphenylmercaptoessigsaeure 32133-94-1 C10H12O2S
    2,6-Dimethylphenylmercaptoessigsaeure
    —— 2-methylamino-3-nitro-6-phenylsulfanylpyridine 172648-61-2 C12H11N3O2S
    2-methylamino-3-nitro-6-phenylsulfanylpyridine
    —— (E)-3-diphenylphosphinoyl-1-phenylthiobut-2-ene 113108-15-9 C22H21OPS
    (E)-3-diphenylphosphinoyl-1-phenylthiobut-2-ene
    —— ethyl 2-[(6-chloro-3-nitropyridin-2-yl)sulfanyl]acetate 100638-01-5 C9H9ClN2O4S
    ethyl 2-[(6-chloro-3-nitropyridin-2-yl)sulfanyl]acetate
    —— 2-(4-methylsulfanylphenylamino)-6-chloro-3-nitropyridine 1094399-95-7 C12H10ClN3O2S
    2-(4-methylsulfanylphenylamino)-6-chloro-3-nitropyridine
    —— 9-[3-[1-[2-[2-[2-[2-[2-[2-[4-[3-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]propyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine 1243536-43-7 C46H52Br2N16O9S2
    9-[3-[1-[2-[2-[2-[2-[2-[2-[4-[3-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]propyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]propyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine
    —— 9-[4-[1-[2-[2-[2-[2-[2-[2-[4-[4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]butyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine 1243536-44-8 C48H56Br2N16O9S2
    9-[4-[1-[2-[2-[2-[2-[2-[2-[4-[4-[6-Amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]butyl]triazol-1-yl]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethyl]triazol-4-yl]butyl]-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]purin-6-amine
    —— ethyl 2-[({[2-(methylsulfanyl)anilino]carbothioyl}amino) oxy]acetate 548797-01-9 C12H16N2O3S2
    ethyl 2-[({[2-(methylsulfanyl)anilino]carbothioyl}amino) oxy]acetate
    —— S-ethyl N-(chloromethyl)-N-methylcarbamothioate 39073-81-9 C5H10ClNOS
    S-ethyl N-(chloromethyl)-N-methylcarbamothioate
    —— S-Ethyl-N-hydroxymethyl-N-methylthiocarbamat 64332-59-8 C5H11NO2S
    S-Ethyl-N-hydroxymethyl-N-methylthiocarbamat
    —— 4-fluoro-2-(4-isopropylphenylthio)benzyl chloride 88848-16-2 C16H16ClFS
    4-fluoro-2-(4-isopropylphenylthio)benzyl chloride
    —— dimercaptoethyl ether 58458-71-2 C2H6OS2
    dimercaptoethyl ether
    —— 2-(1-hydroxyethyl)-2-butyl-1,3-dithiane 68578-40-5 C10H20OS2
    2-(1-hydroxyethyl)-2-butyl-1,3-dithiane
    —— ethyl 2-(1,3-dimethyl-5-benzylthiopyrazol-4-yl)carbonylaminooxypropanoate 868681-21-4 C18H23N3O4S
    ethyl 2-(1,3-dimethyl-5-benzylthiopyrazol-4-yl)carbonylaminooxypropanoate
    —— 2-p-Tolylsulfanylmethyl-thiophene 69639-49-2 C12H12S2
    2-p-Tolylsulfanylmethyl-thiophene