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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(2-methoxyphenyl)thio]pyrimidine 646511-12-8 C11H10N2OS
    2-[(2-methoxyphenyl)thio]pyrimidine
    —— o-methoxyphenyl mesityl sulfide 23075-76-5 C16H18OS
    o-methoxyphenyl mesityl sulfide
    —— 3-((2-methoxyphenyl)thio)quinoline 1299398-47-2 C16H13NOS
    3-((2-methoxyphenyl)thio)quinoline
    —— Dibutyl(methyl)sulfanium 62312-65-6 C9H21S+
    Dibutyl(methyl)sulfanium
    —— 6-(2-Methoxyphenyl)sulfanylpyrido[3,2-d]pyrimidine-2,4-diamine 216167-06-5 C14H13N5OS
    6-(2-Methoxyphenyl)sulfanylpyrido[3,2-d]pyrimidine-2,4-diamine
    —— 2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecylsulfonyl)ethyl carbonochloridate 643032-89-7 C13H8ClF17O4S
    2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecylsulfonyl)ethyl carbonochloridate
    —— 4-(2-methoxyphenylthio)-2,3-dimethylbenzaldehyde 381229-80-7 C16H16O2S
    4-(2-methoxyphenylthio)-2,3-dimethylbenzaldehyde
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(2-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-57-9 C16H19N3O6S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(2-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— 6-[(2-methoxyphenyl)thio]purine 646510-04-5 C12H10N4OS
    6-[(2-methoxyphenyl)thio]purine
    —— 2-[(Thiazol-2-yl)thio]phenol 163298-85-9 C9H7NOS2
    2-[(Thiazol-2-yl)thio]phenol
    —— 4-(2-methoxyphenylthio)-3-methoxybenzaldehyde 381229-81-8 C15H14O3S
    4-(2-methoxyphenylthio)-3-methoxybenzaldehyde
    —— 4-(2-methoxyphenylhio)-3-chlorobenzaldehyde 381229-77-2 C14H11ClO2S
    4-(2-methoxyphenylhio)-3-chlorobenzaldehyde
    —— (2-methoxyphenyl)(3-nitrophenyl)sulfane 353235-58-2 C13H11NO3S
    (2-methoxyphenyl)(3-nitrophenyl)sulfane
    —— {5-[4-amino-6-(2-methoxy-phenylsulfanyl)-[1,3,5]triazin-2-yl]-2,4-dichlorophenoxy}-acetonitrile 959763-07-6 C18H13Cl2N5O2S
    {5-[4-amino-6-(2-methoxy-phenylsulfanyl)-[1,3,5]triazin-2-yl]-2,4-dichlorophenoxy}-acetonitrile
    —— 2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide 381229-50-1 C14H14N2O3S
    2-methoxyphenyl-4-amino-2-nitro-5-methylphenyl sulfide
    —— 2-(2-Methoxyphenyl)sulfanyl-6-nitrobenzonitrile 168910-90-5 C14H10N2O3S
    2-(2-Methoxyphenyl)sulfanyl-6-nitrobenzonitrile
    —— 2-[(2-methoxyphenyl)sulfanyl]benzaldehyde 83193-30-0 C14H12O2S
    2-[(2-methoxyphenyl)sulfanyl]benzaldehyde
    —— 4-(2-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline 1336930-70-1 C16H11Cl3N2OS
    4-(2-Methoxyphenyl)sulfanyl-2-(trichloromethyl)quinazoline
    —— 4-Chloro-3-(2-methoxylphenylthio)-9H-thioxanthen-9-one 1372152-32-3 C20H13ClO2S2
    4-Chloro-3-(2-methoxylphenylthio)-9H-thioxanthen-9-one
    —— (2-methoxylphenyl)-(2-nitrophenyl)thioether 20912-14-5 C13H11NO3S
    (2-methoxylphenyl)-(2-nitrophenyl)thioether
    —— 5-(chloromethyl)-N-isopropyl-2-(methylthio)pyrimidin-4-amine 1011463-91-4 C9H14ClN3S
    5-(chloromethyl)-N-isopropyl-2-(methylthio)pyrimidin-4-amine
    —— 2-(2-((2-methoxyphenyl)thio)phenyl)acetic acid 58722-12-6 C15H14O3S
    2-(2-((2-methoxyphenyl)thio)phenyl)acetic acid
    —— 3-cyano-N-(2,4-dimethoxybenzyl)-4-[(2-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide 1354917-64-8 C25H22N4O5S3
    3-cyano-N-(2,4-dimethoxybenzyl)-4-[(2-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide
    —— 2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-decane-1-sulfonyl)-ethanol 34360-24-2 C12H9F17O3S
    2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-decane-1-sulfonyl)-ethanol
    —— 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol 36879-93-3 C12H9F17S
    5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol
    —— 2-(phenylthio)-1-(trimethylsilyl)butan-3-one 61829-54-7 C13H20OSSi
    2-(phenylthio)-1-(trimethylsilyl)butan-3-one
    —— 6-Methyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one 53633-35-5 C17H10O2S2
    6-Methyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one
    —— (1E,3Z)-4-phenylthio-1-trimethylsilyl-1,3-butadiene 120764-58-1 C13H18SSi
    (1E,3Z)-4-phenylthio-1-trimethylsilyl-1,3-butadiene
    —— 4,7-Dimethyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one 68516-80-3 C18H12O2S2
    4,7-Dimethyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one
    —— (1E,3E)-4-phenylthio-1-trimethylsilyl-1,3-butadiene 120764-59-2 C13H18SSi
    (1E,3E)-4-phenylthio-1-trimethylsilyl-1,3-butadiene
    —— 4-(4-Chloroanilino)-2-methylsulfanylpyrimidine-5-carbaldehyde 1082600-08-5 C12H10ClN3OS
    4-(4-Chloroanilino)-2-methylsulfanylpyrimidine-5-carbaldehyde
    —— 3-(4-bromophenylthio)butanoic acid 226259-83-2 C10H11BrO2S
    3-(4-bromophenylthio)butanoic acid
    —— 3-bromo-4-(methylsulfanyl)pyridine 82257-12-3 C6H6BrNS
    3-bromo-4-(methylsulfanyl)pyridine
    —— 2-Ethenyl-5-phenylsulfanylpentanoic acid 884598-69-0 C13H16O2S
    2-Ethenyl-5-phenylsulfanylpentanoic acid
    —— (3R)-3-(2-chlorothiazol-5-yl)-2,3,7,8-tetrahydro-8-methyl-7-oxo-6-phenyl-[1,3]thiazolo[3,2-a]pyrimidin-4-io-5-olate 2413390-32-4 C16H12ClN3O2S2
    (3R)-3-(2-chlorothiazol-5-yl)-2,3,7,8-tetrahydro-8-methyl-7-oxo-6-phenyl-[1,3]thiazolo[3,2-a]pyrimidin-4-io-5-olate
    —— 6-Ethyl-4-isobutylimino-5-hydroxy-2,2-dimethyl-3,4-dihydro-2H-thiopyrano<2,3-b>pyridin-5,7-diol 82843-15-0 C16H24N2O2S
    6-Ethyl-4-isobutylimino-5-hydroxy-2,2-dimethyl-3,4-dihydro-2H-thiopyrano<2,3-b>pyridin-5,7-diol
    —— 6-Ethyl-5,7-dihydroxy-2,2-dimethyl-2H-thiopyrano<2,3-b>pyridin-4(3H)-on 88518-16-5 C12H15NO3S
    6-Ethyl-5,7-dihydroxy-2,2-dimethyl-2H-thiopyrano<2,3-b>pyridin-4(3H)-on
    —— 6-ethyl-2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione 69395-58-0 C9H11N3O2S2
    6-ethyl-2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione
    —— glyoxalbis(2-mercaptoanil) 19668-99-6 C16H16N2S2
    glyoxalbis(2-mercaptoanil)
    —— (2S,5S)-2-(tert-butyl)-5-ethyl-5-methyl-4-[4-(methylthio) phenyl]-1,3-dioxolan-4-ol 224304-40-9 C17H26O3S
    (2S,5S)-2-(tert-butyl)-5-ethyl-5-methyl-4-[4-(methylthio) phenyl]-1,3-dioxolan-4-ol
    —— 4-(4-(methylthio)phenyl)but-3-yn-2-ol 387866-26-4 C11H12OS
    4-(4-(methylthio)phenyl)but-3-yn-2-ol
    —— (1R,2R)-N,N'-bis(2-(isopropylthio)benzylidene)-1,2-cyclohexanediamine 1383610-96-5 C26H34N2S2
    (1R,2R)-N,N'-bis(2-(isopropylthio)benzylidene)-1,2-cyclohexanediamine
    —— (1R,2R)-N,N'-bis(2-(cyclohexylthio)benzylidene)-1,2-cyclohexanediamine 1383611-02-6 C32H42N2S2
    (1R,2R)-N,N'-bis(2-(cyclohexylthio)benzylidene)-1,2-cyclohexanediamine
    —— (1R,2R)-N,N'-bis(2-(tert-butylthio)benzylidene)-1,2-cyclohexanediamine 1383611-07-1 C28H38N2S2
    (1R,2R)-N,N'-bis(2-(tert-butylthio)benzylidene)-1,2-cyclohexanediamine
    —— Adamantane-1-carbothioic acid hydrazide 109684-20-0 C11H18N2S
    Adamantane-1-carbothioic acid hydrazide
    —— (2,2-Bis-phenylsulfanyl-vinyl)-methyl-amine 1026582-21-7 C15H15NS2
    (2,2-Bis-phenylsulfanyl-vinyl)-methyl-amine
    —— 1,4,7-trithiacyclononane 1-oxide 188631-39-2 C6H12OS3
    1,4,7-trithiacyclononane 1-oxide
    —— N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]propanamide 332143-50-7 C24H22BrNOS2
    N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]propanamide
    —— ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate 332143-57-4 C24H22BrNO2S2
    ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate
    —— 4-hydroxy-thiobutyramide 936850-78-1 C4H9NOS
    4-hydroxy-thiobutyramide