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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (Z)-5-(hexylthio)pent-4-en-1-ol 1424273-49-3 C11H22OS
    (Z)-5-(hexylthio)pent-4-en-1-ol
    —— 8-(3-methoxyphenylsulfanyl)-9H-purin-6-ylamine 696574-58-0 C12H11N5OS
    8-(3-methoxyphenylsulfanyl)-9H-purin-6-ylamine
    —— 8-(3-Methoxy-phenylsulfanyl)-9-pent-4-ynyl-9H-purin-6-ylamine 852030-31-0 C17H17N5OS
    8-(3-Methoxy-phenylsulfanyl)-9-pent-4-ynyl-9H-purin-6-ylamine
    —— {[5-(Pyrazin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetic acid 104820-41-9 C8H6N4O3S
    {[5-(Pyrazin-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetic acid
    —— bis(phenylthiomethyl)phenylphosphine 110139-86-1 C20H19PS2
    bis(phenylthiomethyl)phenylphosphine
    —— (E)-2-phenylthio-1-ethenyl acetyl selenide 107750-13-0 C10H10OSSe
    (E)-2-phenylthio-1-ethenyl acetyl selenide
    —— 1-Phenylthio-2-methyl-1,3-butadien 16061-69-1 C11H12S
    1-Phenylthio-2-methyl-1,3-butadien
    —— (E)-2-phenylthio-1-ethenyl diselenide 107750-19-6 C16H14S2Se2
    (E)-2-phenylthio-1-ethenyl diselenide
    —— N-[2,6-Diethyl-4-(phenylsulfanyl)phenyl]-1,1,1-trifluoromethanesulfonamide 62677-04-7 C17H18F3NO2S2
    N-[2,6-Diethyl-4-(phenylsulfanyl)phenyl]-1,1,1-trifluoromethanesulfonamide
    —— (E)-5-(phenylthio)pent-4-en-1-ol 144482-35-9 C11H14OS
    (E)-5-(phenylthio)pent-4-en-1-ol
    —— 4,4-Bis(phenylsulfanyl)butoxy-tert-butyl-dimethylsilane 1048993-02-7 C22H32OS2Si
    4,4-Bis(phenylsulfanyl)butoxy-tert-butyl-dimethylsilane
    —— Tetradecane-7-thiol 95596-42-2 C14H30S
    Tetradecane-7-thiol
    —— 1-((4-Fluorophenyl)thio)propan-2-amine hydrochloride 104864-02-0 C9H12FNS*ClH
    1-((4-Fluorophenyl)thio)propan-2-amine hydrochloride
    —— 2-methyl-1-phenylsulfanylnaphthalene 93322-81-7 C17H14S
    2-methyl-1-phenylsulfanylnaphthalene
    —— 1,1,1-Trifluoro-N-[4-fluoro-2-(phenylsulfanyl)phenyl]methanesulfonamide 62677-00-3 C13H9F4NO2S2
    1,1,1-Trifluoro-N-[4-fluoro-2-(phenylsulfanyl)phenyl]methanesulfonamide
    —— 3-Allylmercapto-2,4-dimethyl-pent-2-en 59104-36-8 C10H18S
    3-Allylmercapto-2,4-dimethyl-pent-2-en
    —— Methyl-o-(phenylthio)phenylcarbinol 52252-63-8 C14H14OS
    Methyl-o-(phenylthio)phenylcarbinol
    —— 1-(3-chlorophenyl)sulfanylpropan-2-amine;hydrochloride 104863-98-1 C9H12ClNS*ClH
    1-(3-chlorophenyl)sulfanylpropan-2-amine;hydrochloride
    —— (2,6-Dimethyl-phenyl)-[5-(2,6-dimethyl-phenyl)-6-phenylsulfanyl-4-thioxo-4,5-dihydro-[1,3,5]triazin-2-yl]-dithiocarbamic acid phenyl ester 104157-55-3 C32H28N4S4
    (2,6-Dimethyl-phenyl)-[5-(2,6-dimethyl-phenyl)-6-phenylsulfanyl-4-thioxo-4,5-dihydro-[1,3,5]triazin-2-yl]-dithiocarbamic acid phenyl ester
    —— 1.2.3.4-Tetrafluor-5-phenylmercaptobenzol 21913-58-6 C12H6F4S
    1.2.3.4-Tetrafluor-5-phenylmercaptobenzol
    —— N-[4-Chloro-3-(phenylsulfanyl)phenyl]-4-methoxypyrimidin-2-amine 915774-27-5 C17H14ClN3OS
    N-[4-Chloro-3-(phenylsulfanyl)phenyl]-4-methoxypyrimidin-2-amine
    —— 5-<(ethoxycarbonyl)(phenylthio)methyl>-6-formyl-4-methoxy-2H-pyran-2-one 116054-35-4 C17H16O6S
    5-<(ethoxycarbonyl)(phenylthio)methyl>-6-formyl-4-methoxy-2H-pyran-2-one
    —— N-[4-Bromo-2-(phenylsulfanyl)phenyl]-1,1,1-trifluoromethanesulfonamide 62676-99-7 C13H9BrF3NO2S2
    N-[4-Bromo-2-(phenylsulfanyl)phenyl]-1,1,1-trifluoromethanesulfonamide
    —— 1,1,1-Trifluoro-N-[2-fluoro-4-(phenylsulfanyl)phenyl]methanesulfonamide 62676-90-8 C13H9F4NO2S2
    1,1,1-Trifluoro-N-[2-fluoro-4-(phenylsulfanyl)phenyl]methanesulfonamide
    —— N,N'-[Disulfanediyldi(ethane-2,1-diyl)]bis[2-(methanesulfonyl)-N-methylethan-1-amine] 99371-81-0 C12H28N2O4S4
    N,N'-[Disulfanediyldi(ethane-2,1-diyl)]bis[2-(methanesulfonyl)-N-methylethan-1-amine]
    —— (S)-1-{2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-propyl]-[1,3]dithian-2-yl}-hexan-1-ol 148316-31-8 C19H40O3S2Si
    (S)-1-{2-[(S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-hydroxy-propyl]-[1,3]dithian-2-yl}-hexan-1-ol
    —— tert-Butyl-dimethyl-((1S,3R)-1-pentyl-2-oxa-6,10-dithia-spiro[4.5]dec-3-ylmethoxy)-silane 155976-04-8 C19H38O2S2Si
    tert-Butyl-dimethyl-((1S,3R)-1-pentyl-2-oxa-6,10-dithia-spiro[4.5]dec-3-ylmethoxy)-silane
    —— 4-hydroxy-3-methoxy-5-phenylthiobenzaldehyde 936112-12-8 C14H12O3S
    4-hydroxy-3-methoxy-5-phenylthiobenzaldehyde
    —— 5-(furan-2-yl)-3-(methylthio)isoxazole 120803-23-8 C8H7NO2S
    5-(furan-2-yl)-3-(methylthio)isoxazole
    —— 5-<(ethoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-(3-oxo-1-octenyl)-2-pyrone 126759-80-6 C24H28O6S
    5-<(ethoxycarbonyl)(phenylthio)methyl>-4-methoxy-6-(3-oxo-1-octenyl)-2-pyrone
    —— 3-Ethylmercapto-trans-buten-(2)-saeurenitril 21014-07-3 C6H9NS
    3-Ethylmercapto-trans-buten-(2)-saeurenitril
    —— 4-chloro-1-nitro-3-(phenylthio)benzene 851049-56-4 C12H8ClNO2S
    4-chloro-1-nitro-3-(phenylthio)benzene
    —— 2-(1-Methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine 96592-23-3 C9H10N4S
    2-(1-Methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine
    —— 2-(3-Dimethylamino-propylthio)-anilin 1134-77-6 C11H18N2S
    2-(3-Dimethylamino-propylthio)-anilin
    —— [Pt(Me)<sub>2</sub>(dimethyl sulfoxide)<sub>2</sub>] 70423-98-2 C6H18O2PtS2
    [Pt(Me)<sub>2</sub>(dimethyl sulfoxide)<sub>2</sub>]
    —— 3-Phenylmercapto-cis-buten-(2)-saeure-nitril 21014-10-8 C10H9NS
    3-Phenylmercapto-cis-buten-(2)-saeure-nitril
    —— (S,E)-1-(1-adamantylmethylsulfonyl)-5-methylhex-1-en-3-Boc-amine 1228083-08-6 C23H39NO4S
    (S,E)-1-(1-adamantylmethylsulfonyl)-5-methylhex-1-en-3-Boc-amine
    —— (3S,E)-3-(tert-butoxycarbonylamino)-5-methyl-1-methylsulfonyl-1-hexene 193482-43-8 C13H25NO4S
    (3S,E)-3-(tert-butoxycarbonylamino)-5-methyl-1-methylsulfonyl-1-hexene
    —— 3-Ethylmercapto-cis-buten-(2)-saeurenitril 21014-08-4 C6H9NS
    3-Ethylmercapto-cis-buten-(2)-saeurenitril
    —— Butylsulfanylmethylsulfanyl-benzene 110203-49-1 C11H16S2
    Butylsulfanylmethylsulfanyl-benzene
    —— 1-phenyl-3,3-bis(phenylthio)butan-2-ol 109328-54-3 C22H22OS2
    1-phenyl-3,3-bis(phenylthio)butan-2-ol
    —— 1-Methyl-3-thioacetyl-thiourea 79009-27-1 C4H8N2S2
    1-Methyl-3-thioacetyl-thiourea
    —— (S)-3-methyl-1-(4H-[1,2,4]triazol-3-ylsulfanylmethyl)-butylamine hydrochloride 1586791-25-4 C8H16N4S*ClH
    (S)-3-methyl-1-(4H-[1,2,4]triazol-3-ylsulfanylmethyl)-butylamine hydrochloride
    —— ethyl 2-propenyl-2-phenylthiopent-4-enoate 109542-06-5 C15H18O2S
    ethyl 2-propenyl-2-phenylthiopent-4-enoate
    —— 2-benzyl-5-(methylthio)-1,3,4-oxadiazole 23269-52-5 C10H10N2OS
    2-benzyl-5-(methylthio)-1,3,4-oxadiazole
    —— [(S)-3-methyl-1-(4H-[1,2,4]triazol-3-ylsulfanylmethyl)-butyl]-carbamic acid tert-butyl ester 1586791-24-3 C13H24N4O2S
    [(S)-3-methyl-1-(4H-[1,2,4]triazol-3-ylsulfanylmethyl)-butyl]-carbamic acid tert-butyl ester
    —— methyl 2-cyclopent-1-enyl-2-phenylthioacetate 66716-77-6 C14H16O2S
    methyl 2-cyclopent-1-enyl-2-phenylthioacetate
    —— (S)-2-amino-1-(ethylsulfanyl)-4-methylpentane 302800-25-5 C8H19NS
    (S)-2-amino-1-(ethylsulfanyl)-4-methylpentane
    —— 4-(1,3-Benzodithiol-2-ylidene)-2,6-ditert-butylpyran 104825-09-4 C20H24OS2
    4-(1,3-Benzodithiol-2-ylidene)-2,6-ditert-butylpyran
    —— (E)-methyl 3-(phenylthio)-4-(3-oxo-3-methylcyclohexyl)but-2-enoate 105090-08-2 C18H22O3S
    (E)-methyl 3-(phenylthio)-4-(3-oxo-3-methylcyclohexyl)but-2-enoate