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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methoxy-6-(phenylsulfanyl)pyridine 122734-12-7 C12H11NOS
    2-methoxy-6-(phenylsulfanyl)pyridine
    —— hexanedithioic acid ethyl ester 13831-10-2 C8H16S2
    hexanedithioic acid ethyl ester
    —— N-Ethyl-thiocapronsaeureamid 18282-87-6 C8H17NS
    N-Ethyl-thiocapronsaeureamid
    —— 3,3',4,4'-tetraaminodiphenyl sulfide 13107-57-8 C12H14N4S
    3,3',4,4'-tetraaminodiphenyl sulfide
    —— 3-(2-chloro-6-methylphenyl)-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione 1229432-57-8 C14H11ClN4O2S
    3-(2-chloro-6-methylphenyl)-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— <4,4-(1,2-Benzenediyldithio)but-3-enyl>benzene 87543-10-0 C16H14S2
    <4,4-(1,2-Benzenediyldithio)but-3-enyl>benzene
    —— 1-<(2-hydroxyethoxy)methyl>-6-<(3-nitrophenyl)thio>thymine 125056-67-9 C14H15N3O6S
    1-<(2-hydroxyethoxy)methyl>-6-<(3-nitrophenyl)thio>thymine
    —— 1,2-diamino-4-(3-chloropropylthio)benzene 57925-52-7 C9H13ClN2S
    1,2-diamino-4-(3-chloropropylthio)benzene
    —— 4-Cyanmethylmercapto-pyridin 89795-78-8 C7H6N2S
    4-Cyanmethylmercapto-pyridin
    —— 2,3,5,6-tetrafluoro-4-(propylthio)pyridine 67644-47-7 C8H7F4NS
    2,3,5,6-tetrafluoro-4-(propylthio)pyridine
    —— N-Isopropylthioformhydroxamsaeure-methylester 32117-74-1 C5H11NOS
    N-Isopropylthioformhydroxamsaeure-methylester
    —— N-Methylthioformohydroxamsaeuremethylester 32117-71-8 C3H7NOS
    N-Methylthioformohydroxamsaeuremethylester
    —— 4-(3-nitrophenylsulfanyl)imidazole-1-sulfonic acid dimethylamide 725233-26-1 C11H12N4O4S2
    4-(3-nitrophenylsulfanyl)imidazole-1-sulfonic acid dimethylamide
    —— (E)-3-Butylsulfanyl-prop-2-en-1-ol 134797-33-4 C7H14OS
    (E)-3-Butylsulfanyl-prop-2-en-1-ol
    —— 3-butylthio-2-propen-1-ol 86254-65-1 C7H14OS
    3-butylthio-2-propen-1-ol
    —— <i>N</i>,<i>N</i>-dimethyl-4-(3-nitro-phenylsulfanyl)-aniline 27332-26-9 C14H14N2O2S
    <i>N</i>,<i>N</i>-dimethyl-4-(3-nitro-phenylsulfanyl)-aniline
    —— ethyl 3-(4-amino-2-(methylthio)pyrimidin-5-yl)acrylate 211244-80-3 C10H13N3O2S
    ethyl 3-(4-amino-2-(methylthio)pyrimidin-5-yl)acrylate
    —— 3-(2,4-dichloropyridin-3-yl)-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione 1229432-59-0 C12H7Cl2N5O2S
    3-(2,4-dichloropyridin-3-yl)-7-(methylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— 4-Hydrazino-2-methyl-6-methylthiopyrimidine 99469-78-0 C6H10N4S
    4-Hydrazino-2-methyl-6-methylthiopyrimidine
    —— Methyl-β-cyanovinyl-sulfid 10004-53-2 C4H5NS
    Methyl-β-cyanovinyl-sulfid
    —— (3-nitrophenyl)(2,4,6-trimethoxyphenyl)sulfane 1242673-98-8 C15H15NO5S
    (3-nitrophenyl)(2,4,6-trimethoxyphenyl)sulfane
    —— 3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-5-[(3-nitrophenyl)thio]thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione 216685-52-8 C28H25N3O4S2
    3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-5-[(3-nitrophenyl)thio]thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione
    —— 5-methoxymethyl-2-methylsulfanyl-pyrimidin-4-ylamine 98432-25-8 C7H11N3OS
    5-methoxymethyl-2-methylsulfanyl-pyrimidin-4-ylamine
    —— 4,7-Dimethylbenzothiophene-3(2H)-one 104247-65-6 C10H10OS
    4,7-Dimethylbenzothiophene-3(2H)-one
    —— Phosphoroxy-isothiocyanat 24389-20-6 CNOPS
    Phosphoroxy-isothiocyanat
    —— 4-Pyridylthiolacetat 36875-66-8 C7H7NOS
    4-Pyridylthiolacetat
    —— Dithiocarbonic acid O-((2R,3R,8S)-2-ethyl-8-hexyl-oxocan-3-yl) ester S-methyl ester 799265-99-9 C17H32O2S2
    Dithiocarbonic acid O-((2R,3R,8S)-2-ethyl-8-hexyl-oxocan-3-yl) ester S-methyl ester
    —— 1-Ethyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine 97751-20-7 C12H18N4S
    1-Ethyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 4-methylthiobenzylidenemethylamine N-oxide 107379-09-9 C9H11NOS
    4-methylthiobenzylidenemethylamine N-oxide
    —— 1-hydroxymethyl-3-methoxy-4-phenylthiobenzene 117411-53-7 C14H14O2S
    1-hydroxymethyl-3-methoxy-4-phenylthiobenzene
    —— 1-cyanomethyl-3-methoxy-4-phenylthiobenzene 117411-41-3 C15H13NOS
    1-cyanomethyl-3-methoxy-4-phenylthiobenzene
    —— 3-Methoxy-4-(phenylthio)benzaldehyde 122415-03-6 C14H12O2S
    3-Methoxy-4-(phenylthio)benzaldehyde
    —— 1-chloromethyl-3-methoxy-4-phenylthiobenzene 117411-40-2 C14H13ClOS
    1-chloromethyl-3-methoxy-4-phenylthiobenzene
    —— 1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one 208513-26-2 C11H16N2O3S
    1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one
    —— thiacyclooctan-3-one 1,1-dioxide 62827-50-3 C7H12O3S
    thiacyclooctan-3-one 1,1-dioxide
    —— 1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-5-methyl-2-methylsulfanylpyrimidin-4-one 208513-29-5 C12H18N2O3S
    1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-5-methyl-2-methylsulfanylpyrimidin-4-one
    —— 5-bromo-1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one 208513-27-3 C11H15BrN2O3S
    5-bromo-1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one
    —— 1,6,8-Trimethyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-27-4 C9H12N4S
    1,6,8-Trimethyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 5-phenylsulfanyl-1,3-benzothiazol-2-amine 106695-49-2 C13H10N2S2
    5-phenylsulfanyl-1,3-benzothiazol-2-amine
    —— S-phenyl N-(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)carbamothioate 106695-58-3 C13H9N3O2S2
    S-phenyl N-(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)carbamothioate
    —— 2-Methyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one 105246-07-9 C8H8N2OS
    2-Methyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one
    —— 4-Allylsulfanyl-6-methoxymethyl-imidazo[1,5-d][1,2,4]triazine 97751-06-9 C10H12N4OS
    4-Allylsulfanyl-6-methoxymethyl-imidazo[1,5-d][1,2,4]triazine
    —— 3-Methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one 105246-02-4 C7H6N2OS
    3-Methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one
    —— 6-methoxymethyl-4-methylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine 69195-48-8 C8H10N4OS
    6-methoxymethyl-4-methylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine
    —— 1-Isopropyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine 97751-18-3 C13H20N4S
    1-Isopropyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 6-chloro-3-(phenylsulfanylmethylidene)hexan-2-one 89118-10-5 C13H15ClOS
    6-chloro-3-(phenylsulfanylmethylidene)hexan-2-one
    —— 6-Chloro-3-phenylsulfanylmethyl-hexan-2-one 89118-11-6 C13H17ClOS
    6-Chloro-3-phenylsulfanylmethyl-hexan-2-one
    —— 6-Ethyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine 97751-24-1 C15H16N4S
    6-Ethyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine
    —— 6-Ethyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-23-0 C9H12N4S
    6-Ethyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 2-Imino-4-oxothiolane-3-carbonitrile 90312-18-8 C5H4N2OS
    2-Imino-4-oxothiolane-3-carbonitrile