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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-methyl 3-(phenylthio)-4-(3-(trimethylsilyloxy)-2-methyl-2-cyclohexenyl)but-2-enoate 105090-20-8 C21H30O3SSi
    (E)-methyl 3-(phenylthio)-4-(3-(trimethylsilyloxy)-2-methyl-2-cyclohexenyl)but-2-enoate
    —— 3-(pyridyl-2-thio)-1-cyclohexene 112157-69-4 C11H13NS
    3-(pyridyl-2-thio)-1-cyclohexene
    —— 1-(5,5-Dimethyl-3-phenylsulfanyl-4,5-dihydro-[1,2,4]triazol-1-yl)-ethanone 118807-17-3 C12H15N3OS
    1-(5,5-Dimethyl-3-phenylsulfanyl-4,5-dihydro-[1,2,4]triazol-1-yl)-ethanone
    —— 6-Methyl-1-methylsulfanyl-heptane 112173-29-2 C9H20S
    6-Methyl-1-methylsulfanyl-heptane
    —— (S)-(-)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone 127911-56-2 C16H22OSSi
    (S)-(-)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone
    —— 4-Isothiazolecarbonitrile, 3-((cyanomethyl)thio)-5-(methylthio)- 24306-38-5 C7H5N3S3
    4-Isothiazolecarbonitrile, 3-((cyanomethyl)thio)-5-(methylthio)-
    —— ethyl <(4-cyano-5-methylthioisothiazol-3-yl)thio>acetate 24134-89-2 C9H10N2O2S3
    ethyl <(4-cyano-5-methylthioisothiazol-3-yl)thio>acetate
    —— (4-amino-3-pyridyl) N,N-diisopropylcarbamodithioate 116990-43-3 C12H19N3S2
    (4-amino-3-pyridyl) N,N-diisopropylcarbamodithioate
    —— 2-benzyl-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile 96823-96-0 C13H11N3OS
    2-benzyl-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile
    —— (2-Methylsulfanyl-ethyl)-cyclohexane 112173-30-5 C9H18S
    (2-Methylsulfanyl-ethyl)-cyclohexane
    —— ethyl <(4-cyano-3-methylthio-5-isothiazolyl)thio>acetate 74598-21-3 C9H10N2O2S3
    ethyl <(4-cyano-3-methylthio-5-isothiazolyl)thio>acetate
    —— 1,4-diacetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole 118807-34-4 C18H17N3O2S
    1,4-diacetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole
    —— 5-bromo-4-(1-methylhydrazineyl)-2-(methylthio)pyrimidine 691864-63-8 C6H9BrN4S
    5-bromo-4-(1-methylhydrazineyl)-2-(methylthio)pyrimidine
    —— 1-acetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole 118807-13-9 C16H15N3OS
    1-acetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole
    —— 2-benzylsulfanyl-3-chloro-aniline 107254-82-0 C13H12ClNS
    2-benzylsulfanyl-3-chloro-aniline
    —— 4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide 182943-73-3 C20H16N2O2S2
    4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide
    —— (2-chloro-6-nitrophenyl)(p-tolyl)sulfane 860241-04-9 C13H10ClNO2S
    (2-chloro-6-nitrophenyl)(p-tolyl)sulfane
    —— (bromomethyl)(4-chlorophenyl)sulfane 83767-73-1 C7H6BrClS
    (bromomethyl)(4-chlorophenyl)sulfane
    —— 8-nitro-4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide 182943-84-6 C20H15N3O4S2
    8-nitro-4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide
    —— 6-methylthio-5-phenyl-2H-thiopyran-2-one 61149-37-9 C12H10OS2
    6-methylthio-5-phenyl-2H-thiopyran-2-one
    —— α-chloro-α-p-chlorophenylthioacetonitrile 110123-87-0 C8H5Cl2NS
    α-chloro-α-p-chlorophenylthioacetonitrile
    —— 2-(bis(methylthio)methylene)-4-chloro-1,3-benzodithiole 129104-75-2 C10H9ClS4
    2-(bis(methylthio)methylene)-4-chloro-1,3-benzodithiole
    —— 3-Phenylsulfanylthiophene-2-carboxylic acid 81028-81-1 C11H8O2S2
    3-Phenylsulfanylthiophene-2-carboxylic acid
    —— 2-imino-6-methylthio-5-phenyl-2H-thiopyran-3-carbonitrile 90059-00-0 C13H10N2S2
    2-imino-6-methylthio-5-phenyl-2H-thiopyran-3-carbonitrile
    —— 2-<(4-chlorophenyl)thio>ethanimidic acid, ethyl ester 104856-94-2 C10H12ClNOS
    2-<(4-chlorophenyl)thio>ethanimidic acid, ethyl ester
    —— 4-[3-(4-Chlorophenyl)sulfanylbenzo[b][1,8]naphthyridin-2-yl]morpholine 112181-59-6 C22H18ClN3OS
    4-[3-(4-Chlorophenyl)sulfanylbenzo[b][1,8]naphthyridin-2-yl]morpholine
    —— 2-(4-bromophenylthio)acetamidoxime 50837-18-8 C8H9BrN2OS
    2-(4-bromophenylthio)acetamidoxime
    —— 3-<<(4-chlorophenyl)thio>methyl>-5-<(phenylmethyl)thio>pyrimido<5,4-e>-1,2,4-triazin-7-amine 104856-95-3 C19H15ClN6S2
    3-<<(4-chlorophenyl)thio>methyl>-5-<(phenylmethyl)thio>pyrimido<5,4-e>-1,2,4-triazin-7-amine
    —— 3-(4-Chlorophenyl)sulfanyl-2-piperidin-1-ylbenzo[b][1,8]naphthyridine 112181-58-5 C23H20ClN3S
    3-(4-Chlorophenyl)sulfanyl-2-piperidin-1-ylbenzo[b][1,8]naphthyridine
    —— 3-<<(4-chlorophenyl)thio>methyl>pyrimido<5,4-e>-1,2,4-triazine-5,7-diamine 104856-96-4 C12H10ClN7S
    3-<<(4-chlorophenyl)thio>methyl>pyrimido<5,4-e>-1,2,4-triazine-5,7-diamine
    —— N-{2-[(2-Chloro-6-nitrophenyl)sulfanyl]-4-methoxyphenyl}formamide 488085-90-1 C14H11ClN2O4S
    N-{2-[(2-Chloro-6-nitrophenyl)sulfanyl]-4-methoxyphenyl}formamide
    —— 1-Chlor-2,3-bis(methylthio)benzol 65516-83-8 C8H9ClS2
    1-Chlor-2,3-bis(methylthio)benzol
    —— 2-(4-chlorophenyl)sulfanyl-N'-hydroxyethanimidamide 58818-93-2 C8H9ClN2OS
    2-(4-chlorophenyl)sulfanyl-N'-hydroxyethanimidamide
    —— 2-<i>p</i>-tolylsulfanyl-thioacetamide 59865-83-7 C9H11NS2
    2-<i>p</i>-tolylsulfanyl-thioacetamide
    —— 2,2'-thiobis(4,5-dimethylphenol) 170962-07-9 C16H18O2S
    2,2'-thiobis(4,5-dimethylphenol)
    —— 2-[(2-Chloro-6-nitrophenyl)thio]-1-methyl-1H-imidazole 133303-62-5 C10H8ClN3O2S
    2-[(2-Chloro-6-nitrophenyl)thio]-1-methyl-1H-imidazole
    —— 1-cyano-1-(p-tolylthio)cyclobutane 85901-31-1 C12H13NS
    1-cyano-1-(p-tolylthio)cyclobutane
    —— (4S,5S)-2-<(4-Methylphenyl)sulfanylmethyl>-5-phenyl-4-(triisopropylsiloxymethyl)-4,5-dihydro-1,3-oxazole 175477-30-2 C27H39NO2SSi
    (4S,5S)-2-<(4-Methylphenyl)sulfanylmethyl>-5-phenyl-4-(triisopropylsiloxymethyl)-4,5-dihydro-1,3-oxazole
    —— 2-(p-tolylthio)cyclopentanone 84613-02-5 C12H14OS
    2-(p-tolylthio)cyclopentanone
    —— (4S,5S)-4-Hydroxymethyl-2-<(4-methylphenyl)sulfanylmethyl>-5-phenyl-4,5-dihydro-1,3-oxazole 175477-29-9 C18H19NO2S
    (4S,5S)-4-Hydroxymethyl-2-<(4-methylphenyl)sulfanylmethyl>-5-phenyl-4,5-dihydro-1,3-oxazole
    —— 2-Methyl-1-(4-methylphenyl)sulfanylcyclobutane-1-carbonitrile 85891-69-6 C13H15NS
    2-Methyl-1-(4-methylphenyl)sulfanylcyclobutane-1-carbonitrile
    —— 3-(2-Amino-6-chlorophenyl)sulfanylthiophene-2-carboxylic acid 104636-64-8 C11H8ClNO2S2
    3-(2-Amino-6-chlorophenyl)sulfanylthiophene-2-carboxylic acid
    —— N'-hydroxy-2-(4-methylphenyl)sulfanylethanimidamide 74955-69-4 C9H12N2OS
    N'-hydroxy-2-(4-methylphenyl)sulfanylethanimidamide
    —— 3-chloro-2-(2,4-dichlorophenylthio)-nitrobenzene 210823-44-2 C12H6Cl3NO2S
    3-chloro-2-(2,4-dichlorophenylthio)-nitrobenzene
    —— 3-(2-Chloro-6-nitrophenyl)sulfanylthiophene-2-carboxylic acid 104636-60-4 C11H6ClNO4S2
    3-(2-Chloro-6-nitrophenyl)sulfanylthiophene-2-carboxylic acid
    —— 2-(2-chloro-6-nitrophenylthio)imidazole 683276-68-8 C9H6ClN3O2S
    2-(2-chloro-6-nitrophenylthio)imidazole
    —— (2S)-1-[2-[[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl]-1,3-dithian-2-yl]-3-[(4S,6R)-6-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-2,2-dimethyl-1,3-dioxan-4-yl]propan-2-ol 281670-36-8 C30H56O7S2Si
    (2S)-1-[2-[[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl]-1,3-dithian-2-yl]-3-[(4S,6R)-6-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-2,2-dimethyl-1,3-dioxan-4-yl]propan-2-ol
    —— (2S)-1-[2-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-1,3-dithian-2-yl]-3-[(2S)-oxiran-2-yl]propan-2-ol 281670-29-9 C18H36O3S2Si
    (2S)-1-[2-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-1,3-dithian-2-yl]-3-[(2S)-oxiran-2-yl]propan-2-ol
    —— (2S,3R,5R,7S)-7-methoxy-2-methyl-8-[2-[(2S,4R)-2,4,5-trihydroxypentyl]-1,3-dithian-2-yl]octane-1,3,5-triol 281670-37-9 C19H38O7S2
    (2S,3R,5R,7S)-7-methoxy-2-methyl-8-[2-[(2S,4R)-2,4,5-trihydroxypentyl]-1,3-dithian-2-yl]octane-1,3,5-triol
    —— 4-(N,N'-bis(4-chlorophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione 116088-24-5 C17H16Cl2N6S2
    4-(N,N'-bis(4-chlorophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione