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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(o-tolylthio)quinoline 1299398-40-5 C16H13NS
    3-(o-tolylthio)quinoline
    —— 2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-38-4 C21H27N5O3S
    2-(6-methoxybenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 1-(4-Ethylsulfanyl-2-furan-2-yl-6-methyl-pyrimidin-5-yl)-ethanone 120996-86-3 C13H14N2O2S
    1-(4-Ethylsulfanyl-2-furan-2-yl-6-methyl-pyrimidin-5-yl)-ethanone
    —— 2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-22-6 C21H27N5O2S
    2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— (3-chloro-4-cyclopropylsulfanyl-phenyl)-acetic acid 936362-88-8 C11H11ClO2S
    (3-chloro-4-cyclopropylsulfanyl-phenyl)-acetic acid
    —— 3-Methyl-5,6-dihydrothiazolo<2,3-b>thiazolium 17385-73-8 Br*C6H8NS2
    3-Methyl-5,6-dihydrothiazolo<2,3-b>thiazolium
    —— (3-methyl-4-methylsulfanyl-phenyl)-acetic acid 710322-93-3 C10H12O2S
    (3-methyl-4-methylsulfanyl-phenyl)-acetic acid
    —— 2-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061317-18-7 C20H24BrN5O2S
    2-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 1-(2-Aminoethyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-27-1 C16H17N5O2S
    1-(2-Aminoethyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 1-(2-aminoethyl)-2-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061317-20-1 C15H14BrN5O2S
    1-(2-aminoethyl)-2-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 3-Phenyl-5,6-dihydrothiazolo<2,3-b>thiazolium 6094-68-4 Br*C11H10NS2
    3-Phenyl-5,6-dihydrothiazolo<2,3-b>thiazolium
    —— 5,6-Dihydro-thiazolo<2.3-b>thiazolium-bromid 17822-11-6 Br*C5H6NS2
    5,6-Dihydro-thiazolo<2.3-b>thiazolium-bromid
    —— 3,3'-diquinolinyl sulfide 74575-21-6 C18H12N2S
    3,3'-diquinolinyl sulfide
    —— 2-(6-chlorobenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-18-0 C20H24ClN5O2S
    2-(6-chlorobenzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 1-(2-Aminoethyl)-2-(6-chlorobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-21-5 C15H14ClN5O2S
    1-(2-Aminoethyl)-2-(6-chlorobenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2-methyl-2-(methylsulfonyl)propionaldehyde O-(methylcarbamoyl)oxime 1646-88-4 C7H14N2O4S
    2-methyl-2-(methylsulfonyl)propionaldehyde O-(methylcarbamoyl)oxime
    —— 4-Diamantanethiol 131376-34-6 C14H20S
    4-Diamantanethiol
    —— amino-dimethylthiocarbamoyl-sulfane 54564-21-5 C3H8N2S2
    amino-dimethylthiocarbamoyl-sulfane
    —— 2-(6-(methylthio)benzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-29-3 C21H27N5O2S2
    2-(6-(methylthio)benzo[d][1,3]dioxol-5-ylthio)-1-(2-(neopentylamino)ethyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 5-(N,N-Dimethylthiocarbamoyl)thio-4-methyl-2-phenyl-4-isothiazolin-3-one 79660-27-8 C13H14N2OS3
    5-(N,N-Dimethylthiocarbamoyl)thio-4-methyl-2-phenyl-4-isothiazolin-3-one
    —— 2-(Acetonylmercapto)-thiazol 13056-52-5 C6H7NOS2
    2-(Acetonylmercapto)-thiazol
    —— (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-thiazolylthio)ethyl>oxazolidine 143122-27-4 C22H36N2O3S2
    (4S,5S)-3-(tert-butoxycarbonyl)-4-(cyclohexylmethyl)-2,2-dimethyl-5-<2-(2-thiazolylthio)ethyl>oxazolidine
    —— S-(2,2-Dimethylpropyl) 2,2-dimethylpropanesulfonothioate 75142-07-3 C10H22O2S2
    S-(2,2-Dimethylpropyl) 2,2-dimethylpropanesulfonothioate
    —— (5-Acetyl-2-furan-2-yl-6-methyl-pyrimidin-4-ylsulfanyl)-acetic acid 120996-88-5 C13H12N2O4S
    (5-Acetyl-2-furan-2-yl-6-methyl-pyrimidin-4-ylsulfanyl)-acetic acid
    —— diethylthiocarbamic acid S-hexyl ester 534572-39-9 C11H23NOS
    diethylthiocarbamic acid S-hexyl ester
    —— 2-[2-(R)-tert-butyloxycarbonylamino-1-propylthio]thiazole 162684-66-4 C11H18N2O2S2
    2-[2-(R)-tert-butyloxycarbonylamino-1-propylthio]thiazole
    —— 1-tert-butyl-3-methoxythiourea 1160943-89-4 C6H14N2OS
    1-tert-butyl-3-methoxythiourea
    —— Methyl-methylsulfonylformiat 60279-09-6 C3H6O4S
    Methyl-methylsulfonylformiat
    —— 6,7-dimethoxy-4-(thiazol-2-ylthio)quinazoline 1225451-85-3 C13H11N3O2S2
    6,7-dimethoxy-4-(thiazol-2-ylthio)quinazoline
    —— 1-tert-butyl-3-ethoxythiourea 1160943-90-7 C7H16N2OS
    1-tert-butyl-3-ethoxythiourea
    —— {1-[(1,3-thiazol-2-ylthio)methyl]cyclobutyl}methanol 787604-44-8 C9H13NOS2
    {1-[(1,3-thiazol-2-ylthio)methyl]cyclobutyl}methanol
    —— 5-Nitro-6-(2thiazolylthio)-1-indanone ethylene acetal 158877-88-4 C14H12N2O4S2
    5-Nitro-6-(2thiazolylthio)-1-indanone ethylene acetal
    —— 1,2-bis(methylsulphonyl)ethane 6330-26-3 C4H10O4S2
    1,2-bis(methylsulphonyl)ethane
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiazol-2-ylthiomethyl)pyridin-2(1H)-one 1185190-06-0 C18H17IN2OS3
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiazol-2-ylthiomethyl)pyridin-2(1H)-one
    —— 3-chloro-4-(1,3-thiazol-2-ylsulfanyl)aniline 263171-66-0 C9H7ClN2S2
    3-chloro-4-(1,3-thiazol-2-ylsulfanyl)aniline
    —— 2[[2-(Trifluoromethyl)phenyl]thio]thiazole hydrochloride 133303-98-7 C10H6F3NS2*ClH
    2[[2-(Trifluoromethyl)phenyl]thio]thiazole hydrochloride
    —— 6-methanesulfonyl-hexan-1-ol 631910-44-6 C7H16O3S
    6-methanesulfonyl-hexan-1-ol
    —— 4-ethylamino-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one 54660-27-4 C8H10N4OS
    4-ethylamino-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one
    —— 2-((2-bromoethyl)thio)thiazole 333782-39-1 C5H6BrNS2
    2-((2-bromoethyl)thio)thiazole
    —— 2-(2-chloro-4-nitrophenylsulfanyl)thiazole 179687-74-2 C9H5ClN2O2S2
    2-(2-chloro-4-nitrophenylsulfanyl)thiazole
    —— 2-((3,4,4-trifluorobut-3-en-1-yl)thio)thiazole 109993-23-9 C7H6F3NS2
    2-((3,4,4-trifluorobut-3-en-1-yl)thio)thiazole
    —— 2-(4-chloro-4,4-difluorobutylthio)thiazole 215125-03-4 C7H8ClF2NS2
    2-(4-chloro-4,4-difluorobutylthio)thiazole
    —— 2-((6,7-bis(2-methoxyethoxy)quinazolin-4-yl)thio)thiazole 1234579-19-1 C17H19N3O4S2
    2-((6,7-bis(2-methoxyethoxy)quinazolin-4-yl)thio)thiazole
    —— 1-chloro-5-methylsulfonylpentane 128147-29-5 C6H13ClO2S
    1-chloro-5-methylsulfonylpentane
    —— Diethyl 2-hydroxy-2-(2-hydroxy-5-methylsulfanylphenyl)propanedioate 89666-34-2 C14H18O6S
    Diethyl 2-hydroxy-2-(2-hydroxy-5-methylsulfanylphenyl)propanedioate
    —— Ethyl 2-hydroxy-2-(2-hydroxy-5-methylsulfanylphenyl)propanoate 89666-22-8 C12H16O4S
    Ethyl 2-hydroxy-2-(2-hydroxy-5-methylsulfanylphenyl)propanoate
    —— 4-methyl-3-(phenylthio)-1H-indole 1448801-49-7 C15H13NS
    4-methyl-3-(phenylthio)-1H-indole
    —— S-(4-(methylthio)phenyl) N,N-dimethylcarbamothioate 69734-16-3 C10H13NOS2
    S-(4-(methylthio)phenyl) N,N-dimethylcarbamothioate
    —— 4-Methylmersaptophenol-Natriumalz 24676-71-9 C7H7OS*Na
    4-Methylmersaptophenol-Natriumalz
    —— Bis<2-imidazolin-2-yl>disulfid 37137-23-8 C6H10N4S2
    Bis<2-imidazolin-2-yl>disulfid